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91.
Nugraha E. Suyatma Alain Copinet Lan Tighzert Veronique Coma 《Journal of Polymers and the Environment》2004,12(1):1-6
Biodegradable film blends of chitosan with poly(lactic acid) (PLA) were prepared by solution mixing and film casting. The main goal of these blends is to improve the water vapor barrier of chitosan by blending it with a hydrophobic biodegradable polymer from renewable resources. Mechanical properties of obtained films were assessed by tensile test. Thermal properties, water barrier properties, and water sensitivity were studied by differential scanning calorimeter analysis, water vapor permeability measurements, and surface-angle contact tests, respectively. The incorporation of PLA to chitosan improved the water barrier properties and decreased the water sensitivity of chitosan film. However, the tensile strength and elastic modulus of chitosan decreased with the addition of PLA. Mechanical and thermal properties revealed that chitosan and PLA blends are incompatible, consistent with the results of Fourier transform infrared (FTIR) analysis that showed the absence of specific interaction between chitosan and PLA. 相似文献
92.
Gregory M. Glenn Artur K. Klamczynski Bor-Sen Chiou Delilah Wood William J. Orts Syed H. Imam 《Journal of Polymers and the Environment》2004,12(3):189-196
Starch aquagel-based lightweight concrete has properties similar to those of other lightweight concrete products. However, starch aquagels are unstable in the strongly alkaline conditions typical of Portland Cement-based concrete and may interfere with the setting process. The effect of alkali treatments on the physical, mechanical, and functional properties of starch aquagels and aquagels from starch/polymer blends was investigated. Starch was blended at 100–115°C in a twin-screw extruder with five different polymers to determine whether the blends improved alkaline resistance. Polymer blends containing 5%, 15%, and 30% of the polymer hydrated and formed aquagels when equilibrated in water for 24 h. However, equilibrium moisture content was lower for the blends compared to the starch control. Aquagels equilibrated in 0.15 N NaOH swelled, lost compressive strength and had greater than 90% moisture. The blend of starch and 30% PVOH absorbed less moisture and was more resistant to alkaline dissolution in 1 N NaOH than the other blends tested making it a more suitable material for aquagel-based concrete. The moisture content of starch-based aquagels and mixing time were critical factors in determining setting times. The size of aquagel blends had a minor effect on density and compressive strength. 相似文献
93.
94.
Magdalena Svanstrm Morgan Frling Michael Modell William A. Peters Jefferson Tester 《Resources, Conservation and Recycling》2004,41(4):573
Environmental aspects of using supercritical water oxidation (SCWO) to treat sewage sludge were studied using a life cycle assessment (LCA) methodology. The system studied is the first commercial scale SCWO plant for sewage sludge in the world, treating sludge from the municipal wastewater treatment facility in Harlingen, TX, USA. The environmental impacts were evaluated using three specific environmental attributes: global warming potential (GWP), photo-oxidant creation potential (POCP) and resource depletion; as well as two single point indicators: EPS2000 and EcoIndicator99. The LCA results show that for the described process, gas-fired preheating of the sludge is the major contributor to environmental impacts, and emissions from generating electricity for pumping and for oxygen production are also important. Overall, SCWO processing of undigested sewage sludge is an environmentally attractive technology, particularly when heat is recovered from the process. Energy-conserving measures and recovery of excess oxygen from the SCWO process should be considered for improving the sustainability potential. 相似文献
95.
Brent J. Dalzell Prasanna H. Gowda David J. Mulla 《Journal of the American Water Resources Association》2004,40(2):533-543
ABSTRACT: This paper studies the effectiveness of alternative farm management strategies at improving water quality to meet Total Maximum Daily Loads (TMDLs) in agricultural watersheds. A spatial process model was calibrated using monthly flow, sediment, and phosphorus (P) losses (1994 to 1996) from Sand Creek watershed in south‐central Minnesota. Statistical evaluation of predicted and observed data gave r2 coefficients of 0.75, 0.69, and 0.49 for flow (average 4.1 m3/s), sediment load (average 0.44 ton/ha), and phosphorus load (average 0.97 kg/ha), respectively. The calibrated model was used to evaluate the effects of conservation tillage, conversion of crop land to pasture, and changes in phosphorus fertilizer application rate on pollutant loads. TMDLs were developed for sediment and P losses based on existing water quality standards and guidelines. Observed annual sediment and P losses exceeded these TMDLs by 59 percent and 83 percent, respectively. A combination of increased conservation tillage, reduced application rates of phosphorus fertilizer, and conversion of crop land to pasture could reduce sediment and phosphorus loads by 23 percent and 20 percent of existing loads, respectively. These reductions are much less than needed to meet TMDLs, suggesting that control of sediment using buffer strips and control of point sources of phosphorus are needed for the remaining reductions. 相似文献
96.
Marji J. Patz Katta J. Ready Quentin D. Skinner 《Journal of the American Water Resources Association》2004,40(5):1247-1255
ABSTRACT: The objective of this study was to examine the chemistry of Coalbed Methane (CBM) discharge water reacting with semi‐arid ephemeral stream channels in the Powder River Basin, Wyoming. The study area consisted of two ephemeral streams: Burger Draw and Sue Draw. These streams are tributaries to the perennial Powder River. Samples were collected bimonthly from three CBM discharge points and seven channel locations in Burger Draw and Sue Draw. Samples were also collected bimonthly from the Powder River above and below the confluence of Burger Draw. Before sample collection, the pH and electrical conductivity (EC) were measured in the field. Samples were transported to the laboratory and analyzed for alkalinity, major cations, and anions. From the measurement of sodium (Na), calcium (Ca), and magnesium (Mg), practical sodium adsorption ratio (SARp) and true sodium adsorption ratio (SARt) were calculated. Results suggest pH and EC of CBM discharge water was 7.1 and 4.3 dS/m, respectively. The CBM discharge water consisted of higher concentrations of sodium and alkalinity compared to other components. The pH of CBM discharge water increased significantly (p = 0.000) in the downstream channel of Burger Draw from 7.1 to 8.84 before it joined with the Powder River. Dissolved calcium concentration of CBM discharge water decreased significantly (p = 0.000) in the downstream channel water. Subsequently, SARp increased approximately from 24 to 29. The SARt also increased significantly (p = 0.001) in the downstream channel water. For instance, SARt of CBM discharge water increased from 32.93 to 45.5 downstream channels after the confluence of Sue Draw with the Burger Draw. The only significant difference in water chemistry above and below the confluence of Burger Draw with the Powder River was pH, which increased from 8.36 to 8.52. The significant increase in SAR values of CBM discharge water in Burger Draw and Sue Draw tributaries suggest a careful monitoring of salinity and sodicity is needed if CBM discharge water is used for irrigation in semi‐arid environments. Results discussed in this study will be useful to downstream water users who depend on water for irrigation. 相似文献
97.
基于CAN总线的分布式安全报警系统 总被引:4,自引:5,他引:4
CAN总线是一种多主站局部网络 ,支持分布式控制系统或实时控制系统的通信功能 ,具有检错功能强 ,抗干扰 ,传输速率高等优点 ,广泛应用于工业控制领域。笔者以CAN总线技术为基础 ,用单片机和个人计算机组成分布式安全报警系统 ,该系统具有开放性、全分散体系结构、安装维护简单等特点。笔者介绍了该系统的总体构成及其软件和硬件设计。试验结果表明 ,该系统实现了事故现场、住户与住宅小区三者联系的安全报警功能。系统稳定性好 ,实时性强 ,报警准确。 相似文献
98.
基于ArcIMS的旅游安全管理系统 总被引:3,自引:0,他引:3
结合旅游业的特点,即综合性、敏感性、涉外性或国际性,提出旅游安全管理系统应该包括:灾前的防范系统、灾时的抗灾系统以及灾后的评估善后系统3大部分的设计思路。将相应的旅游重大危险源监控系统的功能定为:以行政监察、社会监督、行业自律和应急救援体系为主的宏观管理系统。阐述了Web GIS的优点并推荐了一种构建Web GIS的新技术———ArcIMS,利用ArcIMS的系统构建的旅游安全管理系统具有功能健全、管理方便、系统成熟和安全可靠的诸多优点;同时整个系统的构建相对于其他Web GIS系统的开发而言,技术难度比较低、开发速度比较快,而且系统运行相对稳定,减轻了系统维护的负担。最后,结合旅游安全信息流的特点,具体阐述了运用ArcIMS作为旅游安全管理系统的平台的合理性和可行性。 相似文献
99.
100.