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551.
污水处理厂是抗生素的重要汇集场所,反硝化是污水处理厂生物脱氮的关键环节.为了探究抗生素在反硝化污泥体系的去除特性,选取诺氟沙星(NOR)、土霉素(OTC)、磺胺甲■唑(SMX)和甲氧苄啶(TMP),对比研究了其在不同碳源条件下的变化规律,评估了吸附和生物降解等途径对抗生素去除的贡献.结果表明,反硝化脱氮体系对NOR、 OTC和TMP具有一定的去除作用,且NOR和OTC可被用作碳源进行反硝化.反硝化污泥对NOR和OTC的去除是快速吸附和缓慢生物降解的过程,其中,吸附对NOR和OTC总去除量的贡献率分别达到83.5%和58.9%,生物降解的贡献率分别为16.5%和41.1%.在吸附过程中,胞外聚合物(EPS)吸附的贡献率达到40%以上,而在OTC的生物降解过程中,P450酶发挥重要作用,其贡献率达到20%. 相似文献
552.
Małgorzata Baćmaga Jan Kucharski 《Journal of environmental science and health. Part. B》2019,54(4):252-262
Excess fungicides can pose a serious threat to the soil environment. Fungicides can lower the microbiological and biochemical activity of soil and lead to yield declines. Soils contaminated with fungicides have to be remediated to maintain the optimal function of soil ecosystems. This study evaluates the effect of neutralizing substances on soil enzymatic activity and the yield of Triticum aestivum L. in soil contaminated with fungicides. Sandy loam (Eutric Cambisols) with pHKCl 7.0 was contaminated with an aqueous solution of Amistar 250 SC and Falcon 460 EC in the following doses: 0 (soil without fungicide – treated as a control), RD (dose recommended by the manufacturer) and 300?×?RD (dose 300-fold higher than the recommended dose). Soil was supplemented with bentonite and basalt meal at a dose of 10?g kg?1 DM of soil (dry mass of soil). The fungicide dose recommended by the manufacturer did not induce changes in soil enzymatic activity or the yield of T. aestivum L. Our findings indicate that the tested fungicides can be safely applied to protect crops against fungal pathogens. However, when applied at the dose of 300?×?RD, the tested fungicides strongly inhibited soil enzymatic activity and disrupted the growth and development of spring wheat. Soil supplementation with bentonite and basalt meal improved the yield of T. aestivum L., and bentonite was more effective in reducing fungicide stress. The analyzed substances were not highly effective in restoring biochemical homeostasis in soil. 相似文献
553.
Mengmeng Guo Guanchao Zheng Jixing Peng Di Meng Haiyan Wu 《Journal of environmental science and health. Part. B》2019,54(4):271-280
Perfluorinated alkyl substances (PFASs) are emerging persistent organic pollutants, which pose a threat to human health primarily by dietary exposure, especially through seafood. Bohai Sea (a semi-closed sea located north of China) is an important shellfish aquaculture area that is possibly highly-polluted with PFASs. In this study, we first evaluated contamination by PFASs in a total of 230 samples of marine shellfish from the Bohai Sea. Samples included five important shellfish species, collected from important aquaculture spots distributed around the Bohai Sea. Samples were analyzed by an ultra-fast liquid chromatography-tandem mass spectrometry method, which could simultaneously detect 23 PFASs in shellfish. Our research verified that PFASs have become a threat to the safety of shellfish products in this area. Furthermore, contamination by PFASs in shellfish changed depending on the components of PFASs, the species of shellfish, and the sampling sites. Many of the 23 target compounds contributed to the high detection ratio (>50%) as follows: perfluorooctanoic acid (PFOA)?>?perfluorononanoic acid?>?perfluorodecanesulfonic acid?>?perfluorooctanesulfonic acid (PFOS). Compared with other dominant components, PFOA not only had the highest detection percentage in shellfish samples (98.3%), but its detection level contributed to 87.2% of total PFASs concentrations, indicating that PFOA is the major threat to the safety of shellfish products. The highest level of PFAS was found in clams (62.5?ng?g?1 wet weight of PFOA). The concentration of total PFAS in different shellfish species showed the following trend: clams?>?mussels?>?scallops?>?whelks?>?oysters. The maximum concentration of total PFAS or PFOA was found in Shouguang. The total concentration of PFOS and its precursor were highest in Cangzhou, possibly due to local industrial activities. The results presented in this paper provide new data on the contamination of marine shellfish along the Bohai Sea coasts in China, and constitute a reference for future monitoring of contamination by emerging contaminants in Bohai coast. 相似文献
554.
Preparedness of emergency evacuation for the leakage of toxic substances in chemical plants is very important in order to reduce damage. In order to implement an emergency evacuation properly, it is necessary to comprehensively and concretely determine the conditions of the leakage and atmospheric conditions and predict the consequences of the dispersed gases. Repeated training for emergencies is also essential. In order to realize effective evacuation, a prediction model of the evacuation area that anyone can use to obtain the same results both accurately and promptly is developed in the present study. The prediction model is designed such that the wind speed and atmospheric conditions are automatically set, and the leakage rate is the only input parameter, so that anyone can use the model easily. In addition, the model can also predict the atmospheric parameters for up to 3 h and can calculate the evacuation distance so that smooth evacuation can be achieved for changing atmospheric conditions. Finally, the evacuation area is defined by statistically analysed wind fluctuations, and a series of emergency evacuation measures is implemented. 相似文献
555.
556.
Laura Annika Sormunen Tommi Kaartinen Riina Rantsi 《International Journal of Sustainable Engineering》2018,11(4):261-271
In many European countries, the environmental properties of waste-derived aggregates are mostly assessed based on laboratory leaching tests such as the standardised percolation tests CEN/TS/14405, ISO/TS 21268-3, or DIN 19528. These tests are conducted under specified conditions, which are similar yet somewhat different from realistic field conditions. Therefore, this study aimed to investigate the leaching properties of ADR (Advanced Dry Recovery) recovered MSWI BA in the field in order to understand more about its environmental impacts in actual civil engineering structures. Two field scale studies (a lysimeter and a larger interim storage field study) were constructed and the leachate quality was investigated. These results were then complemented with the results of previously conducted laboratory leaching tests using a liquid to solid ratio (L kg?1) comparison. The results demonstrated that the leaching behaviours of many potentially harmful substances, such as chloride, copper and antimony, was similar despite the study scale. In addition, this study illustrated the importance of investigating the leaching properties of waste-derived aggregates on a larger scale, even though the uncertainties in such studies may not be easily controlled. 相似文献
557.
邻苯二甲酸二乙基己酯(DEHP)污染及其毒性研究进展 总被引:3,自引:0,他引:3
邻苯二甲酸二乙基己酯(DEHP)作为重要的增塑剂被广泛应用于涂料、食品包装、医疗器材、儿童玩具等产品中。研究表明DEHP在水、土壤、空气等各个环境要素以及食物、饮用水中已被普遍检出,并对环境产生潜在的危害。本文通过分析国内外DEHP的环境暴露和毒性效应的研究成果,总结了DEHP在室外大气、室内空气、土壤、地表水、地下水、食品和饮用水中的污染现状,并对DEHP的替代产品进行总结;此外,本文深入探讨了DEHP对水生生物和陆生生物的生态毒性效应,以及对生殖发育、肝脏、呼吸系统和神经系统等的健康毒性效应。最后,结合DEHP在环境暴露调查和毒性效应研究方面的不足,指出需要进一步加强我国DEHP的环境暴露调查,制定相关环境基准值与标准限值,开展慢性生态毒性效应和人体健康毒性效应等方面的研究。 相似文献
558.
559.
好氧颗粒污泥胞外聚合物的产生及其分布 总被引:15,自引:0,他引:15
考察了不同操作条件和基质条件对好氧颗粒污泥中胞外聚合物(EPS)产生的影响及其在污泥和体系上清液中的分布.结果表明:随体系操作条件和基质条件的变化,好氧颗粒污泥内部和上清液中的EPS含量呈规律性变化.相对而言,好氧颗粒污泥中EPS含量的变化幅度较小,过多的EPS则释放到上清液中.大量EPS的释放只发生在颗粒污泥解体时,而酸性条件和不适当的C/N比不利于好氧颗粒污泥的形成及形态保持.体系溶解氧为4.5 mg·l-1,pH为中性,污泥负荷小于等于0.37kgCOD·kg-1MLSS·d-1,碳氮比为20∶ 1时,好氧颗粒污泥中EPS的含量约占污泥总质量的9%-12%,与厌氧颗粒污泥(0.6%-20%)相近,但远低于絮状活性污泥(80%),此时,EPS在上清液中的含量最低或接近最低,为14-26 mg·l-1. 相似文献
560.