加热炉炉管穿孔事故处理及原因分析

以一起直接式原油加热炉炉管穿孔事故为例,介绍了事故处理程序,分析了炉管穿孔的原因是由于漏点腐蚀、坑点腐蚀以及炉管管卡损坏导致的,并提出了类似事故防范对策.     

A stochastic-advective transport model for NAPL dissolution and degradation in non-uniform flows in porous media

Remediation schemes for contaminated sites are often evaluated to assess their potential for source zone reduction of mass, or treatment of the contaminant between the source and a control plane (CP) to achieve regulatory limits. In this study, we utilize a stochastic stream tube model to explain the behavior of breakthrough curves (BTCs) across a CP. At the local scale, mass dissolution at the source is combined with an advection model with first-order decay for the dissolved plume. Field-scale averaging is then employed to account for spatial variation in mass within the source zone, and variation in the velocity field. Under the assumption of instantaneous mass transfer from the source to the moving liquid, semi-analytical expressions for the BTC and temporal moments are developed, followed by derivation of expressions for effective velocity, dispersion, and degradation coefficients using the method of moments. It is found that degradation strongly influences the behavior of moments and the effective parameters. While increased heterogeneity in the velocity field results in increased dispersion, degradation causes the center of mass of the plume to shift to earlier times, and reduces the dispersion of the BTC by lowering the concentrations in the tail. Modified definitions of effective parameters are presented for degrading solutes to account for the normalization constant (zeroth moment) that keeps changing with time or distance to the CP. It is shown that anomalous dispersion can result for high degradation rates combined with wide variation in velocity fluctuations. Implications of model results on estimating cleanup times and fulfillment of regulatory limits are discussed. Relating mass removal at the source to flux reductions past a control plane is confounded by many factors. Increased heterogeneity in velocity fields causes mass fluxes past a control plane to persist, however, aggressive remediation between the source and CP can reduce these fluxes.     

Contribution of anthropogenic pollutants to the increase of tropospheric ozone levels in the Oporto Metropolitan Area, Portugal since the 19th century

The main purpose of this study was to evaluate the contribution of anthropogenic pollutants to the increase of tropospheric ozone levels in the Oporto Metropolitan Area (Portugal) since the 19th century. The study was based on pre-industrial and recent data series, the results being analyzed according to the atmospheric chemistry. The treatment of ozone and meteorological data was performed by classical statistics and by time-series analysis. It was concluded that in the 19th century the ozone present in the troposphere was not of photochemical origin, being possible to consider the respective concentrations as reference values. For recent data a cycle of 8h for ozone concentrations could be related to traffic. Compared to the 19th century, the current concentrations were 147% higher (252% higher in May) due to the increased photochemical production associated with the increased anthropogenic emissions.     

模糊综合评价法在道路运输企业安全评价中的应用

我国道路运输企业交通安全形势比较严峻,推行道路运输企业安全综合评价是降低道路运输企业交通事故的有效途径之一.本文运用Delphi法和AHP法建立了道路运输企业安全层次分析模型,构建了安全综合评价指标体系.选用基于"差动"原理的赋权法--G1法计算各指标的权重,应用模糊综合评价法对其进行安全综合评价.采用平均加权法对评价因素的各项指标进行量化处理,从而得到道路运输企业安全的综合评价结果.最后,对陕西省一家道路运输企业进行了实际验证,比较真实地反映了此企业的安全状况.     

某场地边坡稳定分析方法的比较研究*

为了对边坡稳定性分析方法进行研究,以某场地高填方边坡和直立边坡为研究对象,基于Geostudio、理正软件以及ANSYS软件,采用M-P法、Bishop法和强度折减法进行边坡稳定分析。结果表明:高填方边坡安全系数为1.3,为稳定边坡;AB,BC,CD段地块间边坡边坡安全系数依次为0.479,0.410,0.381,基坑边坡安全系数为0.436,均为不稳定边坡;其中,M-P法得到的安全系数偏保守,Bishop法得到的安全系数结果较可靠,强度折减法得到的结果最为理想。研究结果可为边坡稳定性研究与治理提供借鉴。     

基于电磁辐射峰谷比值法的煤与瓦斯突出预警

为了提高电磁辐射预警煤与瓦斯突出危险的准确性,减少误报现象,在分析大量电磁辐射现场数据基础上,基于电磁辐射预警煤与瓦斯突出危险原理,提出了电磁辐射峰谷比值法,利用正态分布统计特征计算每个班次的电磁辐射瞬时强度峰值均值和谷值均值,并将其比值作为煤与瓦斯突出危险性的预警值。最后,将该方法应用于义忠煤矿11112风巷掘进工作面,研究结果表明:与临界值系数和动态变化趋势系数法相比,峰谷比值法误报较低,预警准确性高,能够很大程度上减少误报对生产的影响。     

CH_4/N_2/O_2预混气激波火焰结构数值预测

研究激波着火现象，推导激波加热点燃可燃气控制方程组。针对甲烷预混气激波火焰结构进行数值模拟，计算了激波燃烧时的压力、温度、及不同组分随时间的变化历程。其中甲烷燃烧采用美国BERKELEY大学GRI-MECH机理，该反应机理包含177个基元反应，涉及32种组分。程序采用美国SANDIA国家实验室发展的大型化学反应动力学软件包CHEMKIN III中相关的模型、子程序和热力学数据库。计算结果表明激波火焰有其自身的结构特征。     

析因试验设计在环境污染物联合毒性研究中的应用

结合当前化学污染物联合毒性评价方法及析因试验应用现状,从试验设汁方法及统计学角度,论证析因试验在研究环境化学污染物联合毒性,特别是在2种化合物联合毒性研究中应用的优势及其可行性。     

金属系无机抗菌材料研究进展

主要介绍金属系无机抗菌材料。从材料的选择和合成方面,讨论了材料的特性和抗菌功能相结合的途径,归纳出抗菌材料的制备工艺的一般规律,为开发适合我国国情的无机抗菌材料提供思路。     

非煤矿山安全评价方法探讨

介绍了非煤矿山安全评价的内容和方法,分析了目前评价方法的不足和缺陷,提出了一种新型非煤矿山安全评价方法,并结合湖北某石膏矿山安全评价的实例,阐述了这种评价方法的应用过程,最后对这种方法提出改进建议。