全文获取类型
收费全文 | 1489篇 |
免费 | 135篇 |
国内免费 | 451篇 |
专业分类
安全科学 | 112篇 |
废物处理 | 43篇 |
环保管理 | 153篇 |
综合类 | 864篇 |
基础理论 | 233篇 |
污染及防治 | 274篇 |
评价与监测 | 316篇 |
社会与环境 | 49篇 |
灾害及防治 | 31篇 |
出版年
2024年 | 20篇 |
2023年 | 31篇 |
2022年 | 74篇 |
2021年 | 59篇 |
2020年 | 73篇 |
2019年 | 60篇 |
2018年 | 62篇 |
2017年 | 87篇 |
2016年 | 98篇 |
2015年 | 95篇 |
2014年 | 102篇 |
2013年 | 176篇 |
2012年 | 128篇 |
2011年 | 153篇 |
2010年 | 92篇 |
2009年 | 116篇 |
2008年 | 76篇 |
2007年 | 101篇 |
2006年 | 72篇 |
2005年 | 64篇 |
2004年 | 35篇 |
2003年 | 38篇 |
2002年 | 35篇 |
2001年 | 31篇 |
2000年 | 30篇 |
1999年 | 16篇 |
1998年 | 29篇 |
1997年 | 19篇 |
1996年 | 15篇 |
1995年 | 19篇 |
1994年 | 8篇 |
1993年 | 14篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有2075条查询结果,搜索用时 62 毫秒
261.
Cadmium and lead were determined simultaneously in seawater by differential pulse stripping voltammetry (DPSV) preceded by
adsoptive collection of complexes with 8-hydroxyquinoline (oxine) on to a hanging mercury drop electrode (HMDE). In preliminary
experiments the optimal analytical condition for oxine concentration was found to be 2.10−5 M, at pH 7.7, the accumulation potential was −1.1 V, and the initial scannig potential was −0.8 V. The peak potentials were
found −0.652 V for Cd and −0.463 V for Pb At the 60 s accumalation time. The limit of detection (LOD) and limit of quantitatification
(LOQ) were found to be by voltammetry as 0.588 and 1.959 μg l−1 (RSD, 5.50%) for Cd and 0.931 and 3.104 μg l−1 (RSD, 4.10%) for Pb at 60 s stirred accumulation time respectively. In these conditions the most of the seawater samples
are amenable for direct voltammetric determination of cadmium and lead using a HMDE. An adsorptive stripping mechanism of
the electrode reaction was proposed. For the comparison, seawater samples were also analysed by ICP-atomic emission spectrometry
method (ICP-AES). The applied voltammetric technique was validated and good recoveries were obtained. 相似文献
262.
The activity concentrations of soil samples collected from thirty different locations of Malwa region of Punjab were determined
by using HPGe detector based on high-resolution gamma spectrometry system. The range of activity concentrations of 226Ra, 232Th and 40K in the soil from the studied areas varies from 18.37 Bq kg−1 (Sangrur) to 53.11 Bq kg−1 (Sitoguno), 57.28 Bq kg−1 (Dhanola) to 148.28 Bq kg−1 (Sitoguno) and 211.13 Bq kg−1 (Sunam) to 413.27 Bq kg−1 (Virk Khera) with overall mean values of 35 Bq kg−1, 80 Bq kg−1and 317 Bq kg−1 respectively. The absorbed dose rate calculated from activity concentration of 226Ra, 232Th and 40K ranges between 8.47 and 24.48, 35.68 and 92.38, and 8.74 and 17.11 nGy h−1, respectively. The total absorbed dose in the study area ranges from 58.08 nGy h−1 to 130.85 nGy h−1 with an average value of 79.11 nGy h−1. The calculated values of external hazard index (Hex) for the soil samples of the study area range from 0.35 to 0.79. Since these values are lower than unity, therefore, according
to the Radiation Protection 112 (European Commission. Radiation Protection 112 1999) report, soil from these regions is safe and can be used as a construction material without posing any significant radiological
threat to population. 相似文献
263.
Chuaybamroong P Cayse K Wu CY Lundgren DA 《Environmental monitoring and assessment》2007,128(1-3):421-430
Ambient aerosols were collected during 2000–2001 in Gainesville, Florida, using a micro-orifice uniform deposit impactor (MOUDI)
to study mass size distribution and carbon composition. A bimodal mass distribution was found in every sample with major peaks
for aerosols ranging from 0.32 to 0.56 μm, and 3.2 to 5.6 μm in diameter. The two distributions represent the fine mode (<2.5 μm)
and the coarse mode (>2.5 μm) of particle size. Averaged over all sites and seasons, coarse particles consisted of 15% carbon
while fine particles consisted of 22% carbon. Considerable variation was noted between winter and summer seasons. Smoke from
fireplaces in winter appeared to be an important factor for the carbon, especially the elemental carbon contribution. In summer,
organic carbon was more abundant. The maximum secondary organic carbon was also found in this season (7.0 μg m−3), and the concentration is between those observed in urban areas (15–20 μg m−3) and in rural areas (4–5 μg m−3). However, unlike in large cities where photochemical activity of anthropogenic emissions are determinants of carbon composition,
biogenic sources were likely the key factor in Gainesville. Other critical factors that affect the distribution, shape and
concentration were precipitation, brushfire and wind. 相似文献
264.
In this work, water and sediment samples were collected from three different stations located along the Sakarya river between
May and September 2003. Lead, copper, chromium, zinc, nickel and cadmium concentrations were determined by using solvent extraction
and flame atomic absorption spectrometric method. The results show that differences based upon sampling times, regions, sediment
and water samples were observed. The mean levels of copper, nickel, chromium, lead, cadmium, zinc for sediment samples are;
4.630 μg g−1, 13.520 μg g−1, 8.780 μg g−1, 2.550 μg g−1, 9.990 μg g−1 and for water samples are; 0.851 μg g−1, 1.050 μg g−1, 0.027 μg g−1, 1.786 μg g−1, 0.236 μg g−1, 0.173 μg g−1, respectively. 相似文献
265.
After introducing soft defence techniques as an alternative to hard defence techniques, the need is emphasized to consider
the coastal area as an integral system. By recalling the main driving factors for coastal management: conflict resolution,
resilience and sustainability, we logically arrive at the concepts of ecological engineering and ecotechnology, which are
increasingly acknowledged as possible solutions to achieve sustainable use of coastal space as a resource. In this context,
we refer to the principles of self design and of ecosystem conservation.
In order to deal with real situations we are in need of fundamental ‘tools’ for the application of the soft intervention technology
approach. We therefore introduce the concept of physiographic units and develop an initial elaboration for a coastal stretch
and for coastal wetlands. The latter deserve more attention because of the already established practices of ecotechnology,
at least as far as water and soil quality are concerned, but certainly also concerning morphology, especially in the future.
We conclude by briefly discussing how activities undertaken in two research projects currently being conducted under the framework
of the Marine Science and Technology Program of the Commission of the European Communities are expected to contribute to the
concepts introduced here. 相似文献
266.
267.
建立了固相萃取-超高效液相-串联质谱法同时测定水环境中26种类固醇激素的分析方法。明确了取样体积为500 m L,Cleanert PEP为富集柱,乙酸乙酯为洗脱剂,甲醇为溶剂进行提取操作。选择了正离子模式,以0. 1%甲酸/甲醇-水为流动相,负离子模式以0. 1%氨水/乙腈-水为流动相,试样经AcquityTMUPLC BEH C18色谱柱分离后,选用质谱检测模式进行定性、定量分析。通过方法验证,26种类固醇激素的方法检出限为0. 3~1. 5 ng/L,测定下限为1. 2~6. 0 ng/L,代表性样品测定结果的相对标准偏差为2. 6%~13. 7%(n=6),加标回收率为71. 2%~121%。该方法操作便捷,灵敏度高,精密度和准确度良好,可适用于水环境中多种痕量、超痕量类固醇激素的定性定量分析。 相似文献
268.
269.
270.