羟基铝蒙脱石去除染料弱酸性深蓝GR的研究

在[OH^-]/[A1³⁺]=2.4的反应条件下,利用A1³⁺与碱液反应制备出Keggin离子,并由此制备出羟基铝蒙脱石.XRD-衍射数据表明:羟基铝蒙脱石的层间距由原来的12.58A(d₀₀₁)增加到18.63A.研究了染料弱酸性深蓝GR在7种改性蒙脱石上的吸附.结果表明:酸性条件下,羟基铝蒙脱石处理有机污染物的去除率高,用0.0200g处理25ml弱酸性深蓝GR溶液,去除率可高达95%以上.由等温吸附线可知:弱酸性深蓝GR在不同改性蒙脱石上的吸附机理主要为表面吸附、离子交换和分配作用.     

The bioeffects of extremely weak power-frequency alternating magnetic fields

We report the results of a study of the influence of extremely-weak alternating magnetic fields (EW AMF) directed co-linearly to the static Earth’s magnetic field on the rate of regeneration in planarians and also on the rate of gravitropic response in the stem segments of flax. In particular we obtained the data on the dependence of the value of bioeffects on the amplitude (at fixed 60 Hz—frequency) and on the frequency (at fixed 1.6 μT—amplitude) of the alternating component. Our data show unambiguously that EW AMF substantially affect the properties of the biosystems. The experimental data may be approximated by the theoretical expression following directly from a general formula, derived in the theory of magnetic parametric resonance. Our data indicate that the nuclear spins of hydrogen atoms serve as the primary targets for the action of the EW AMF on the biosystems. The values of bioeffects of combined magnetic fields with extremely weak alternating component are completely determined by the parameter , where γ = 42.578 Hz/μT—gyromagnetic ratio of the nuclear spins of hydrogen atoms, and and f correspond to magnetic induction and frequency of the alternating magnetic component. The dependence of bioeffect’s value on —parameter is polyextremal: well expressed maxima are observed at and minor maxima at . The bioeffects are absent at , 3.8, 5.3, 6.7. At the values of the bioeffect changes its sign—activation of planarian’s regeneration starts to be replaced by its inhibition. The inhibition takes place for the range of the amplitudes from 10 to 140 μT. The observed change in the sign of the effect may result to the prevalence of the effects caused by the induction of the alternating currents in the test-system at relatively high —amplitudes. These results provide the basis for planning of the epidemiological studies and interpretation of the corresponding results.     

基于弱HSDI与强HSDI的区域可持续性评价——以中国环渤海地区为例

可持续性评价是可持续性科学研究的重要内容。在HDI和HSDI的基础上,构建对环境重视程度不同的弱HSDI与强HSDI评价指数,以中国环渤海地区为例,揭示区域2000-2015年可持续性基本状态与变化过程。结果表明：从基本状态来看,环渤海地区各市可持续性水平等级结构失衡,弱HSDI与强HSDI水平均呈两头小、中间大的纺锤形等级结构,但弱HSDI的等级结构失衡比强HSDI更严重,且弱、强HSDI空间格局差异较大;从变化过程来看,环渤海地区各市可持续发展步调不一致,弱HSDI与强HSDI均以显著增长趋势为主,但弱HSDI主要呈中高速增长,强HSDI主要呈中低速增长。结合评价结果,划分可持续性状态与过程矩阵,提出具有针对性的多元化策略,可为促进区域可持续发展提供决策参考。     

On the indicator of weak sustainability

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某型滑油温度传感器的可靠性强化试验

针对诱发滑油温度传感器故障模式的主要环境因素进行了分析,确定了影响滑油温度传感器可靠性的敏感环境应力。根据滑油温度传感器结构间的逻辑关系和可靠性框图,建立其故障树,找出了潜在薄弱环节作为可靠性强化试验的主要关注点。依据可靠性强化试验理论设计了试验方案,并制定了试验剖面。     

燃烧管中烟煤粉粉尘云传播参数的试验研究

利用自行设计的长29.6 m,内径199 mm,配有特殊扬尘装置的大犁卧式燃烧爆炸管道试验系统,对弱点火条件下烟煤粉与空气两相悬浮流中的爆炸过程进行了试验研究,用压电传感器测量了管内各测点的压力信号,观测到快速爆燃的状态稳定,分析了爆燃波稳定传播机理.结果表明:在煤粉浓度为300g/m~3及弱点火条件下,悬浮烟煤粉粉尘云中爆燃波能够稳定传播,且稳态传播距离持续20 m以上,峰值超压和波速平均值分别约为70 kPa和430m/s.     

南海某深水高温高压气井SS-15型井口头系统薄弱点安全评价

为应对深水高温高压气井生产过程中井口系统复杂性、井口抬升等对整个井口系统完整性的破坏情况,研究环空压力、上顶力、温度、产量对井口头系统薄弱点的影响。基于数值模拟方法建立井口系统有限元力学模型,分析在不同环空压力与上顶力条件下,井口系统各部件的应力大小变化情况,为井口系统薄弱点位置的确定提供理论依据,进而提出深水高温高压井井口系统完整性的管控图版及方法。研究结果表明：环空密封本体与套管挂、锁环与限位槽的接触部位是薄弱点;同一环空压力下,上顶力越大,套管挂等效应力与锁环变形量越大;当上顶力超过700 t时,不论环空压力是否存在,均达到井口系统薄弱点屈服强度。因此,深水高温高压油气井应制定合理生产制度或管理措施,研究结果对保障井口系统完整性,降低深水高温高压井生产阶段风险具有一定参考意义。     

Occurrence and congeners specific of polychlorinated biphenyls in agricultural soils from Southern Jiangsu, China

A total of 198 agricultural soil samples were collected from Zhangjiagang and Changshu in Southern Jiangsu for analysis of 13 polychlorinated biphenyls （PCBs） in order to assess the levels of pollution, sources, area distribution, and potential risk for the environment. All methods were rigorously tested and an adequate quality control was ensured. Only one site had no PCBs residues, and the highest total PCBs concentration in the surface soils was 32.83 ng/g. The average concentration in all the soil samples was 4.13 ng/g, signaling low-level pollution. Tetra-, penta-, and hexa-chlorinated biphenyls were dominant species in soil samples, accounting for more than 75% of ∑PCBs in the soil samples. PCB118 was the most abundant congener in all the samples. The PCB118 was about 20% of ∑PCBs. The soil organic matter content showed only a weak correlation with the levels of all PCB congeners, in which a better correlation was noted for the more volatile lighter PCB congeners than for the heavier homologues. To a certain extent, the sources and land use seemed to influence the levels of PCBs.     

优化多孔蜂窝状硅镁胶的制备及其对弱酸性红的吸附性能

为了研究开发经济、高吸附量、可再生的吸附剂,以Na₂SiO₃、MgCl₂为原料,通过溶胶-凝胶法制备出一系列优化蜂窝状硅镁胶,并分析制备硅镁胶的最佳焙烧条件,采用热重分析(TG)、红外光谱(FT-IR)、X射线衍射光谱(XRD)、比表面及孔隙度分析、电镜扫描(SEM)等手段对硅镁胶进行结构表征和性质测定,研究硅镁胶对印染废水中弱酸性红的吸附行为. 结果表明:经500 ℃焙烧4 h后镁硅配比〔n(Mg2+)∶n(SO2-₃)〕为3∶1的硅镁胶对弱酸性红具有最好的吸附效果,硅镁胶对弱酸性红的吸附符合Langmuir模型,吸附过程符合伪二级动力学模型,在吸附温度为25 ℃、投加量为0.5 g/L、ρ(弱酸性红)初始值为200 mg/L时,硅镁胶对弱酸性红的饱和吸附量可达到199.51 mg/g,脱除率达到99.34%;经过5次再生之后对弱酸性红依然具有较高的吸附量,可达到192.12 mg/g,脱除率为95.60%. 研究显示,以Na₂SiO₃、MgCl₂为原料制备的优化多孔蜂窝状硅镁胶对弱酸性红具备良好的吸附性能,并且具有较好的再生能力,是一种廉价高效的吸附材料.      

软弱底板特厚煤层综放面矿压特征研究与应用

水帘洞煤矿3802工作面是彬长矿区首个采用8m小区段煤柱护巷、面临软弱底板问题的特厚煤层工作面,生产条件复杂,类似开采技术经验较少。针对此问题,采用岩石物理力学性质测试和计算机数值模拟等手段,明确软弱底板对综放面矿压影响机理;通过现场实测,对3802工作面矿压特征和覆岩移动规律等进行研究,结果表明,软弱底板条件下特厚煤层综放面较一般底板下特厚煤层综放面矿压显现特征不同,软弱底板吸收能量,将应力转移到深处,一定程度上消除了冲击地压危险,同时矿山压力显现平缓不明显,动载系数小。现场实测结果表明巷道围岩稳定,研究结果可以在类似条件下推广应用。