生化防护材料的探讨

本文详述了生化防护材料的种类、性能特点,与防护服配件的协调、使用耐久性能以及成本等问题,得出了生化防护材料选用及设计的一般性结论。     

几种化学药剂对淡水单孔蚓虫卵及幼虫的杀灭效果研究

为寻求有效杀死"红虫"虫卵的药剂及杀灭幼虫的最小药剂用量,在20℃条件下,使用氯胺、高锰酸钾及过氧化氢溶液对虫卵及幼虫进行杀灭实验。结果表明:氯胺溶液对"红虫"虫卵的杀灭效果并不理想;在虫卵杀灭处理中,使用高锰酸钾溶液是不可行的;过氧化氢对"红虫"虫卵具有极强的杀灭效果,0.05%的过氧化氢在30 min内即可将虫卵有效杀死;低浓度氯胺溶液对"红虫"幼虫具有较好的杀灭效果,起始余氯值为1.3 mg/L的氯胺溶液即可在1 d内将"红虫"幼虫全部杀死。     

Simulation and application of a disaster spread model in Chemical Disaster Network

In the research field of chemical safety, the computer-aided simulation for occurrence and process of disasters has become a major trend in current research, in which the establishment of evolution system for chemical multi disasters is the key point. In the paper, the study lays emphasis on the simulation and application of a spread model for chemical multi disasters. After establishing a disaster network, we defined microcosmic elements of spread model specifically. Combined with guideline of chemical disaster (e.g. guideline of heat flux for damages or injure, guideline of evaluation for buildings based explosion and overpressure, and guideline of evaluation for human exposure to toxic gases), the weight of impact can be computed using new comprehensive algorithms. Simultaneously, the paper also uses an approach on simulating multiple failure events to describe random factors of triggering disasters. At last, the experimental case of alkyl aluminum leakage in a polypropylene plant shows the result of simulation with table of 5 major series of disasters and distribution diagram of nodes (disasters) in disaster network. This proves the validity and practicability of the simulation system in the establishment and feedback of contingency plan of large-scale petrochemical enterprises.     

Effect of iron addition on the performance of anoxic-oxic membrane process and biological phosphorus removal北大核心CSCD

In order to solve the problem of poor treatment of phosphorus in membrane bioreactor (MBR) with long sludge retention time (SRT), a ferric salt was added to enhance phosphorus removal; FeCl36H2O (Fe/P = 2.0) was added to the reactor. The removal efficiency of nitrogen, organic matters, and phosphorus in the MBR was investigated systematically. Moreover, this study focused on the membrane performance, the change of active sludge flora, and the effect of adding a ferric salt on membrane fouling before and after the addition. It was seen that adding the ferric salt could not affect the removal of COD and NH4 +-N and the removal rate of COD and NH4 +-N reached over 90%. However, the average removal rate of phosphorus was 52%, while the removal rate increased by nearly 40% after adding the ferric salt. The effects of adding ferric salts on the dominant bacteria and biological phosphorus removal of activated sludge were further studied. The results showed that the addition of ferric salt (Fe/P = 2.0) decreased the diversity of active sludge flora and relative abundance of some phosphorusaccumulating organisms and had a negative effect on biological phosphorus removal. The analysis of transmembrane pressure difference (TMP) recording revealed that the concentration of iron salts did not exacerbate membrane fouling. The results showed that the concentration of iron salts entering the membrane bioreactor would reduce the relative abundance and phosphorus removal efficiency of the activated sludge in the system to a certain extent, but it had no obvious effect on membrane fouling. It allowed the effluent to attain acceptable standards, especially with respect to phosphorus removal efficiency. © 2018 Science Press. All rights reserved.     

Security Risk Assessment Methodology for the petroleum and petrochemical industries

The American National Standards Institute (ANSI)/American Petroleum Institute (API) Standard 780 Security Risk Assessment (SRA) Methodology was published in June 2013 as a U. S. standard for security risk assessments on petroleum and petrochemical facilities. The standard represents a model standard for evaluating all security risks of petroleum and petrochemical infrastructure and operations and assists industries in more thoroughly and consistently conducting SRAs. The 2013 Standard is an update from the previous API/NPRA SRA Methodology (2004) and focuses on expanding functional utility without changing the basic methodology.The methodology can be applied to a wide range of assets even beyond the typical operating facilities of the industry. This includes refining and petrochemical manufacturing operations, pipelines, and transportation operations including truck, marine, and rail, as well as worker and executive security, housing compounds, and remote operational sites. The new standard describes the most efficient and thorough approach for assessing security risks widely applicable to the types of facilities operated by the industry and the security issues they face. It is voluntary but has been adopted by the Kingdom of Saudi Arabia Ministry of Interior High Commission for Industrial Security as the mandatory security risk assessment methodology for industrial facilities.This paper examines the key elements of the ANSI/API SRA process and discusses how forward thinking organizations may use risk-based performance metrics to systematically analyze facility security postures and identify appropriately scaled and fiscally responsible countermeasures based on current and projected threats. The AcuTech Consulting Group developed the methodology under contract to the API, and the author was the project manager for the project.     

炼焦过程排放挥发性有机物的排放特征和组成分布研究

为控制炼焦排放以及为预防城市大气污染提供可靠的污染源数据支持,利用不锈钢采样罐和全自动预浓缩/GC/MS系统,研究了58-Ⅱ型和JN43-80型焦炉在装煤时刻和炼焦过程(包括装煤时刻)中挥发有机物(VOCs)的排放特征及其组成分布,分析了焦化行业排放VOCs的反应活性。研究发现,在装煤时刻和炼焦过程中,58-Ⅱ型焦炉产生的总挥发性有机物(TVOCs)浓度分别为7022μg/m~3和6266μg/m~3;JN43-80型焦炉产生的TVOCs浓度分别为4185μg/m~3和3298μg/m~3。装煤时刻产生的TVOCs浓度明显高于炼焦过程产生的。炼焦过程无组织排放的VOCs包含烯烃、烷烃、芳香烃、卤代烃以及少量的醛和酮,其中乙烯、乙烷、丙烯、苯、甲苯等为主要成分。这些产生的VOCs反应活性各不相同,活性最大的是烯烃类物质,其活性占TVOCs反应活性比重为(86.2±2.1)%;其次是芳香烃类物质,其活性比重为(9.2±3.1)%;反应活性最大的5个物种分别是丙烯、乙烯、1,3-丁二烯、1-丁烯以及苯乙烯。     

废水中氨氮的去除与利用

化学沉淀剂可去除废水中的氨氮，并得到有用复合肥ＭｇＮＨ４ＰＯ４。探讨了诸反应对氨氮去除率的影响。     

化工园区地下水环境状况调查监测布点研究

借鉴环境风险源目标管理的理念,按照“分区、分类、分级”监测的原则,建立了化工园区地下水环境状况调查监测布点方法体系,并以某化工园区为示例展开应用研究。结果显示,该方法能对化工园区不同区域、不同类型、不同级别的地下水污染源构建差异化监测网络,解决化工园区地下水污染多元化监测布点问题,可为化工园区地下水环境状况调查监测布点方案的拟定或优化调整提供工作参考。     

Pheromone-based female mate choice and its effect on reproductive investment in a spitting spider

Numerous studies have focused on whether organisms can signal or perceive pheromones and use chemical signals in species and mate recognition. Recently, there have been an increasing number of studies investigating whether pheromones are used in mate choice. Yet, little attention has been paid in exploring the effects of pheromone-based mate choice on reproductive investment. We first tested this hypothesis by providing virgin Scytodes sp. females with a choice between two virgin males in the presence of chemical signals alone and found strong evidence of an odor-based mate preference. We then examined the consequences of the odor-based mate choice by allowing female Scytodes sp. that had previously made an odor-only mate choice to mate with preferred and non-preferred males, respectively. We measured the success of copulation, mortality of male, pre-oviposition interval, egg-sac weight, egg weight, fecundity, fertility, embryonic period, and size of offspring at hatching. Females that mated with the preferred males produced significantly heavier egg sacs that contained more and larger eggs with a greater fertility. Significantly more non-preferred males than preferred males were killed by spitting. However, pre-oviposition interval, embryonic period, and hatchling size were not affected by female mate choice. This study is the first to demonstrate that female spiders are able to regulate their highly valuable reproductive investment based solely on chemical signals.     

(Z)-Dodec-3-en-1-ol, a common major component of the trail-following pheromone in the termites Kalotermitidae

(Z)-Dodec-3-en-1-ol has been identified as the major component of the trail-following pheromone of nine species of Kalotermitidae belonging to six different genera, suggesting that this compound represents a common signal in this family of termites. The homogeneous nature of trail-following pheromones of Kalotermitidae well agrees with the monophyly of this family. It also supports the postulated position of this family as a sister group of the Rhinotermitidae and Termitidae, which also secrete C12-alcohols as trail-following pheromones. The significance of a trail pheromone in termites of the ‘one-piece’ life type, which spend their whole life within the same piece of wood, is discussed.