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791.
海水中石油类国标分析方法存在的问题及改进建议 总被引:1,自引:0,他引:1
当前海水石油类分析三种国标方法存在代表性和适用性不足的问题,不同方法的数据间缺乏可比性,给政府和民众控制水体污染、评价水质状况带来偏差和不便。建议国家相关部门修订海水石油类分析方法,将水质石油类分析国标方法统一为红外分光光度法。通过海水样品加标实验验证了该方法的可行性,实际操作简便、准确。 相似文献
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为了研究受弯构件的抗火性能,及对国内外目前的受弯构件抗火设计方法有一个系统的了解,介绍了中国、美国、欧洲、英国和澳大利亚的钢结构抗火设计规范关于受弯构件的计算方法,并对它们的区别和联系进行了分析。设计了一个算例,分别采用不同的规范计算了其临界温度和耐火极限。经对比分析表明:各国规范的计算结果差别较大,相同条件下,澳大利亚规范计算得出的临界温度较低;无防火保护层时,英国规范计算得出的耐火极限较高,而有保护层时,美国规范计算得出的耐火极限较低。 相似文献
795.
Since conventional water treatment is not affordable in developing countries,looking for locally available and alternative treatment options is mandatory.Removal of fluoride and phosphate can be achieved by designing appropriate filtration media from different materials such as sand,calcined clay,pumice,scoria and bone char.This study was designed to determine the removal efficiency of these locally available filter media with respect to detention time and pH.The filtration apparatuses(tank)were filled separately with stone,gravel with grain size 0.6-4.75 mm and 40 cm deep,sand(ES=0.15-0.35 mm and UC=1.5-3),calcined clay,pumice,scoria and bone char with grain size 0.25-0.5 inch.Water samples were prepared using glass bottles with fluoride concentrations of 6 and 8 mg/l and phosphate concentration of 4 mg/1.Laboratory analysis was carried out before and after filtration to determine the removal efficiency of each medium.It was found that the highest removal of fluoride was achieved by bone char(89.65%),followed by pumice(82.4%).However,bone char has rather increased the concentration of phosphate by 63.8%.Sand was the most efficient media to remove phosphate,managing to remove by 70%.Therefore,it is an attractive option to use these locally available,environmental friendly and appropriate technologies for efficient removal of both fluorine and phosphate at the household or community water treatment level. 相似文献
796.
Susana Santos Nuno Lapa Andreia Alves João Morais Benilde Mendes 《Journal of environmental science and health. Part. B》2013,48(5):364-375
The objective of this work is to quantify As, Hg, Cd, Ni and Pb in Portuguese red wines. First, the methods for the quantification of trace elements in red wines were validated. Several pre-treatments were compared, namely a pre-digestion process with HNO3, a pre-oxidation step with H2O2, and a spiking step of wine samples with a known concentration of the trace elements analyzed. Except for As, it was determined that the quantification of the trace elements does not require a pre-digestion process with HNO3. For all of the trace elements analyzed, a pre-oxidation step with H2O2 may enable an accurate quantification. The techniques chosen for the quantification of trace elements were hydride generation atomic absorption spectrometry (HGAAS) for As and Hg, electrothermal atomic absorption spectrometry (ETAAS) for Cd, and flame atomic absorption spectrometry (FAAS) for Ni and Pb. In the second stage of this work, 25 Portuguese red wines spanning all of the red wine-producing regions were analyzed for all of the five trace elements referred to above. Only Cd and Pb have shown concentrations above the limit values defined by the “Organization Internationale de la Vigne et du Vin.” The Target Hazard Quotient (THQ) equation was used to determine in which wine-producing regions that wine consumption can be a problem for public health in terms of the concentrations of the five trace elements analyzed. THQ values have indicated that for the universe of the 25 red wines analyzed no region produces wines that can pose problems for public health, when the Portuguese red wine standard consumption is considered. 相似文献
797.
Tessa Artruc Desiree Tullos Ben Leshchinsky 《Journal of the American Water Resources Association》2023,59(1):86-106
The drawdown of reservoirs behind dams is an important management strategy (e.g., for removal of aging infrastructure, flushing of sediment), and an opportunity to study erosional processes. A numerical model was developed to examine retrogressive bank erosion across reservoir drawdown scenarios and to evaluate factors controlling the rate, volume, and mechanisms of lateral erosion. Modeled processes included dynamic drawdown of groundwater, sequential slope failures via limit equilibrium analysis, and retrogression considering stress interaction between failing blocks. Field measurements were coupled with Staged, Slow, and Rapid drawdown scenarios. Results highlight the importance of including retrogression as an avenue for lateral erosion, as sequential block failures were found to occur in all scenarios except Slow drawdown. This result indicates that bank stability models without some means of characterizing the evolution of slope failure during drawdown are likely underestimating bank failure rates and volumes. In contrast, dynamic groundwater was not found to be a dominant control for any drawdown scenario. Model results also demonstrate that the drawdown increment is a first-order control on slope instability via the development of drained or undrained conditions. A majority of failures occurred under undrained conditions. To maximize slope stability, using slow drawdown to activate internal friction under drained conditions is essential. The design of the drawdown rate created a tradeoff between the amount of impact created and when the impact is produced. The study also articulated the need for coupling models and field observations for rapidly changing systems. 相似文献
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799.
VOCs快速检测在某化工企业搬迁遗留污染场地调查中的应用 总被引:1,自引:0,他引:1
以天津市某化工企业搬迁遗留污染场地为例,采用VOCs快速检测法辅助现场钻孔取样,以初步判断土壤污染深度,同时将现场样品送实验室检测。试验表明,VOCs快速检测法与实验室检测法结果基本一致。将452个样品测定结果做比对,结果表明实验室检测数据VOCs加和值与快速检测法现场检测数据存在显著相关,R2为0.803 7。污染物主要集中于场地5 m~9 m的粉土层中。其中,13种VOCs检出,4种VOCs超过《场地土壤环境风险评价筛选值》(DB11/T 811—2011)商业用地筛选值。 相似文献
800.