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71.
以天然粘土矿物累托石为载体、以铁盐作交联剂,利用水溶液插层方法制备了铁/累托石复合物。采用FT-IR和XRD两种表征方法对铁/累托石复合物进行了表征,分析了复合物的结构变化和层间间距变化,并探讨了复合物制备条件以及反应过程中溶液初始浓度、溶液初始pH、复合物投加量和H2O2浓度因素对催化降解活性艳蓝的影响。研究表明:铁聚合物插入到累托石的层间结构中,扩大了累托石的层间距;当Na+/Fe3+比值为0.5,Fe3+/累托石比值为10 mmol/g,p H为3左右,催化剂用量为0.5 g/L时,H2O2浓度为100 mg/L时,活性艳蓝的去除率达到90%以上。实验表明,铁柱撑累托石/UV/Fenton工艺对活性艳蓝具有良好的降解效果。 相似文献
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The elemental mercury removal abilities of three different zeolites (NaA, NaX, HZSM-5) impregnated with iron(III) chloride were studied on a lab-scale fixed-bed reactor. X-ray diffraction, nitrogen adsorption porosimetry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and temperature programmed desorption (TPD) analyses were used to investigate the physicochemical properties. Results indicated that the pore structure and active chloride species on the surface of the samples are the key factors for physisorption and oxidation of Hg0, respectively. Relatively high surface area and micropore volume are beneficial to efficient mercury adsorption. The active Cl species generated on the surface of the samples were effective oxidants able to convert elemental mercury (Hg0) into oxidized mercury (Hg2 +). The crystallization of NaCl due to the ion exchange effect during the impregnation of NaA and NaX reduced the number of active Cl species on the surface, and restricted the physisorption of Hg0. Therefore, the Hg0 removal efficiencies of the samples were inhibited. The TPD analysis revealed that the species of mercury on the surface of FeCl3–HZSM-5 was mainly in the form of mercuric chloride (HgCl2), while on FeCl3–NaX and FeCl3–NaA it was mainly mercuric oxide (HgO). 相似文献
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对劳动湖受纳周边工程排水后水质的影响变化进行了分析,并给出可行性较强的建议,为此类工程排水处理提供很好的借鉴。 相似文献
75.
强化安全管理 改进安全工作 总被引:2,自引:1,他引:1
随着我国钢铁企业生产中科技含量的不断增加,自动化程度的逐渐深化,企业的规模也相应的扩大了.然而,在钢铁企业中安全管理中存在的问题变得越来越突出.就我国钢铁企业安全生产的现状作简要论述,并对改进安全工作提出几点意见. 相似文献
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针对武钢循环冷却水系统部分钢管腐蚀,造成管管漏水,严重影响正常生产的问题.探讨了钢管产生腐蚀的原因及其对策.近2年,通过实施减缓循环冷却水钢管腐蚀的对策,取得了明显的效果. 相似文献
79.
Yuxin Wu Roelof Versteeg Lee Slater Douglas LaBrecque 《Journal of contaminant hydrology》2009,106(3-4):131-143
Calcium carbonate is a secondary mineral precipitate influencing zero valent iron (ZVI) barrier reactivity and hydraulic performance. We conducted column experiments to investigate electrical signatures resulting from concurrent CaCO3 and iron oxides precipitation under simulated field geochemical conditions. We identified CaCO3 as a major mineral phase throughout the columns, with magnetite present primarily close to the influent based on XRD analysis. Electrical measurements revealed decreases in conductivity and polarization of both columns, suggesting that electrically insulating CaCO3 dominates the electrical response despite the presence of electrically conductive iron oxides. SEM/EDX imaging suggests that the electrical signal reflects the geometrical arrangement of the mineral phases. CaCO3 forms insulating films on ZVI/magnetite surfaces, restricting charge transfer between the pore electrolyte and ZVI particles, as well as across interconnected ZVI particles. As surface reactivity also depends on the ability of the surface to engage in redox reactions via charge transfer, electrical measurements may provide a minimally invasive technology for monitoring reactivity loss due to CaCO3 precipitation. Comparison between laboratory and field data shows consistent changes in electrical signatures due to iron corrosion and secondary mineral precipitation. 相似文献
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