聚丙烯酸-聚偏氟乙烯共混膜对Cu^2＋吸附特性的研究

应用热诱导聚合和相转移技术,制备了具有离子交换性能的聚丙烯酸-聚偏氟乙烯（PAA—PVDF）共混膜,采用XPS和SEM表征了PAA—PVDF共混膜的结构和组成,分析了PAA—PVDF共混膜对水溶液中Cu^2＋的吸附性能,研究了共混膜对Cu^2＋的吸附热力学和吸附动力学．结果表明,动力学吸附过程符合准二级动力学方程,等温吸附过程符合Langmuir模型．吸附过程的平均吸附能为8—16kJ／mol,表明该吸附过程为离子交换反应．热力学参数△G^0〈0、△H^0〉0、△S^0〉0,证实了吸附过程为自发的吸热过程。PAA—PVDF共混膜经吸附／脱附4次循环后,对废水中Cu^2＋的吸附量大于0．025mg／cm^2,脱附率超过95％。PAA—PVDF共混膜具有优良的吸附／脱附性能,良好的稳定性和潜在的应用前号。     

微囊藻属一日内垂向分布的数值模拟

将水质模型与微囊藻属浮力调节模型相结合,建立微囊藻属垂向浓度分布模型,该模型不仅保留了以往模型的优点且改进了以往模型的不足,如考虑了微囊藻群体的直径大小及微囊藻属的浮力调节能力.模型结果与荷兰的Vinkeveen湖的实际测量数据吻合良好.此外,模拟结果也表明:微囊藻属在垂向的分布受水体紊动程度影响显著.微囊藻群体的最大浓度并不在水体表面,而是在水下一定深度处.小尺寸群体微囊藻群体(20~50μm)在水深方向的分布比大尺寸群体(100~200μm)更加均匀.日落后,微囊藻属会因为密度减小上浮至水面,反之,白日里,微囊藻属密度增加向水底方向下沉,因此日出前水面的微囊藻属浓度高于日落前的水面浓度.     

某厂煤气洗涤塔煤气泄漏中毒事故分析

针对某钢铁厂煤气事故,使用定性分析的方法,对喷淋塔泄水作业的试验数据进行了分析,煤气泄漏造成人员中毒原因进行了论证,得出了一些结论,并据此分析煤气泄漏后可能导致人员死亡的范围,为今后采取控制措施提供依据。     

非均匀热环境下热舒适评价的两种方法及其关键技术

针对非均匀热环境下乘员热舒适性的评价问题,提出当量温度评价指标(EQT)和当量均匀温度评价指标(EHT);完成这两种评价指标的关键技术在于如何进行流场的三维Navier-Stokes方程与人体的生物热方程之间的耦合迭代。在进行数值计算时发现:流场计算时人体皮肤表面给温度分布(即提D irichlet问题)、人体的生物热方程求解时给热流密度分布(即提Neumann问题),采用其边界条件的提法后,使得非均匀热环境下的流场与人体生物热方程之间的大迭代容易收敛和稳定。典型算例表明:对同一种物理问题,尽管两种评价下所得到的当量温度不同,但得出的评价效果是一致的,这就从侧面显示了这两种评价方法的一致性与有效性。     

大学生应急能力评估指标体系多群组结构方程模型

为构建大学生应急能力评估指标体系,提升大学生应急能力水平,首先通过访谈和文献研究提取了大学生应急能力初始评估指标体系,并编制调查问卷,对我国大学生群体的应急能力进行调查;然后采用SPSS 24.0软件对大学生应急能力评估调查问卷数据进行项目分析、探索性因子分析和信度分析,明确了大学生应急能力评估指标体系的结构;最后采用...     

基于结构方程模型的京津冀城市用地行政边界效应分析

行政边界如何影响城市用地规模?论文以京津冀为研究案例,基于结构方程构建5个时段（1990、1995、2000、2005、2010年）的城市用地行政边界效应模型,揭示行政边界影响下城市用地的扩张机理和演化特征。研究结果表明：行政边界对城市用地规模的直接影响效应不显著;行政边界通过对经济、人口等中间要素的影响间接作用于城市用地的扩张过程;1990—2010年的5个时间节点,京津冀城市用地行政边界效应的间接影响要素中,财政支出和非农业人口的主导作用明显,社会固定资产、实际利用外资和职工平均工资也在不同阶段发挥了不可忽视的作用;在社会经济发展水平较低、市场化和区域一体化滞后的阶段,社会固定资产是行政边界影响城市用地规模的重要间接要素,而在要素流动较为频繁的时期,实际利用外资和职工平均工资成为构筑在行政边界和城市用地规模间不可忽视的中间要素。本研究可为京津冀城市用地的理性扩张和城市开发边界的划定提供理论支持和政策建议。     

Book reviews and notices

This study aims to examine the mediating role of the customer environmental satisfaction in the effect of environmental friendliness of products and the company on customer loyalty in using green products in Malaysia. Structural equation modeling (SEM) analysis is performed to test the proposed hypotheses among 200 full time university students with purchasing experience at least once a week green products like organic vegetables. SEM results showed that customer environmental satisfaction significantly affected customer loyalty. This pair of relationships has the highest standardized beta coefficients, signifying the most important aspect of consideration by respondents among the rest of the proposed hypotheses. Next, customer environmental satisfaction partially mediated the relationship between environmental friendliness of products and customer loyalty in using green products. The results confirmed that customers are satisfied with their decision to purchase green products as they consume the least amount of resources and energy which results in minimum environmental damage and are also easy to recycle, disassemble, decompose, and reuse. Marketers should focus on creating effective marketing strategies and green promotional activities to attract customers for their green products. Marketers should control and enhance the quality of green products, as well as emphasizing their environmental satisfaction and increasing customer loyalty levels. This empirical study advanced marketers’ and policy makers’ understanding of the identification of customer environmental satisfaction as a mediator in the relationship between environmental friendliness of products and customer loyalty has been inspected in Malaysian context.     

Measuring sustainable governance in the European Union

This paper examines the problem of measuring sustainable governance in the European Union (EU-27) through the use of duality and the Slutsky equation. The proposed methodology is based on the application of a three-dimensional optimisation model, where the arguments of the objective (sustainable social welfare) function are economic goods that contribute to sustainable economic growth; environmental goods that provide for sustainable environmental protection; and social goods through which sustainable social development is achieved. The dual problem, formulated through this three-dimensional theoretical model, is solved to find the optimal solution, indicating a certain sustainability level. We suggest that this solution can be used for calculating the value of what we define here as the sustainable governmental policy indicator, which is considered to provide quantitative measurement of government policies on sustainable development within the context of ‘good governance’. Furthermore, it is suggested that the Slutsky equation can be used as a reliable method for long-term monitoring and planning of national as well as international good governance with regard to sustainable development policies. In its empirical part, the paper applies the theoretical model in an analysis of the sustainable development indicators (as set out in the Sustainable Development Strategy (SDS) of the EU) in Bulgaria for the period 2000–2010 and compares them to those of the EU-27.     

用伴随方程研究空气污染的优化控制

从一类常见的空气污染控制问题出发，推导了三维非平坦地形下大气平流扩散方程的伴随方程，利用伴随方程和原始方程的关系，对优化控制问题进行了等价变形，大大降低了计算量．文中指出，空气污染预报问题是正问题，适合用平流扩散原始方程求解；控制问题是反问题，用伴随方程求解是很自然的途径。     

Epidemiological and biomechanical evaluation of airline baggage handling

Objectives. Musculoskeletal disorders (MSDs) are prevalent among airline baggage handlers due to manual materials handling. In this study, the Nordic musculoskeletal questionnaire (NMQ), the revised National Institute for Occupational Safety and Health (NIOSH) lifting equation, and the University of Michigan 3D Static Strength Prediction Program? (3DSSPP) were used to analyze MSDs among baggage handlers. Methods. The NMQ was filled out by 209 baggage handlers and 46 arbitrarily selected baggage handlers were evaluated using the NIOSH method and 3DSSPP. Results. The obtained results showed that the most common MSDs occurred in the lower back region. The next risky regions included knees, neck, and upper back, respectively. The NIOSH results confirmed that the subjects lifted loads heavier than the permitted limit and their lifting postures were inappropriate. The results of the 3DSSPP also indicated that compression forces exceeded the NIOSH limit in these awkward postures. Conclusions. Relying on this study, holding compulsory ergonomic lifting training courses could be proposed for workers and regulations adjusting an upper limit for maximum baggage weight must be also enacted in order to improve occupational health and prevent the prevalence of increasing MSDs.