Silver recovery as Ag0 nanoparticles from ion-exchange regenerant solution using electrolysis

Many silver(Ag)containing consumer-products(e.g.textiles)release Ag into the environment,posing ecotoxicological risks.Ag recovery mitigates environmental hazards,recycles Ag,and leads to sustainability.In the present work,Ag has been recovered as Ag~0nanoparticles from the spent solution(thiourea(TU)～0.5 mol/L pH～1.1–1.2,and Ag～550 mg/L)obtained from the regeneration of an Ag-loaded resin using a simple undivided electrolytic cell.The reclaimed regenerant solution has been recycled and reused in a closed-loop scheme over multiple cycles.The process parameters,i.e.,current(0.05 A)and stirring speed(600 r/min),have been optimized for Ag recovery of～94%and TU loss of～2%.The reclaimed regenerant solution has been shown to regenerate Ag-loaded resin samples with90%regeneration efficiency over 4 cycles of consecutive extraction and regeneration.The recovered Ag~0nanoparticles are monodisperse,consistently spherical in shape,and have a mean diameter of～6 nm with standard deviation of the Gaussian fit as～2.66 nm.     

Use of polymeric sub-micron ion-exchange resins for removal of lead, copper, zinc, and nickel from natural waters

This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel.     

Towards real-time detection of wastewater in surface waters using fluorescence spectroscopy

The presence of municipal wastewater at the intake of a major drinking water treatment facility located on Lake Ontario was examined using fluorescence data collected during a period of continuous monitoring. In addition, controlled mixing of lake water and wastewater sampled from a local treatment facility were conducted using a bench-scale fluorescence system to quantify observed changes in natural organic matter. Multivariate linear regression was applied to components derived from parallel factors analysis. The resulting mean absolute error for predicted wastewater level was 0.22% (V/V, wastewater/lake water), indicating that wastewater detection at below 1.0% (V/V) was possible. Analyses of sucralose, a wastewater indicator, were conducted for treated wastewater as well as surface water collected at two intake locations on Lake Ontario. Results suggested minimal wastewater contribution at the drinking water intake. A wastewater detection model using a moving baseline was developed and applied to continuous fluorescence data collected at one of the drinking water intakes, which agreed well with sucralose results. Furthermore, the simulated addition of 1.0% (V/V) of wastewater/wastewater was detectable in 89% of samples analyzed, demonstrating the utility of fluorescence-based wastewater monitoring.     

Molecular characterization of transformation and halogenation of natural organic matter during the UV/chlorine AOP using FT-ICR mass spectrometry

UV/chlorine process, as an emerging advanced oxidation process (AOP), was effective for removing micro-pollutants via various reactive radicals, but it also led to the changes of natural organic matter (NOM) and formation of disinfection byproducts (DBPs). By using negative ion electrospray ionization coupled with Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS), the transformation of Suwannee River NOM (SRNOM) and the formation of chlorinated DBPs (Cl-DBPs) in the UV/chlorine AOP and subsequent post-chlorination were tracked and compared with dark chlorination. In comparison to dark chlorination, the involvement of ClO^?, Cl^?, and HO^? in the UV/chlorine AOP promoted the transformation of NOM by removing the compounds owning higher aromaticity (AI_mod) value and DBE (double-bond equivalence)/C ratio and causing the decrease in the proportion of aromatic compounds. Meanwhile, more compounds which contained only C, H, O, N atoms (CHON) were observed after the UV/chlorine AOP compared with dark chlorination via photolysis of organic chloramines or radical reactions. A total of 833 compounds contained C, H, O, Cl atoms (CHOCl) were observed after the UV/chlorine AOP, higher than 789 CHOCl compounds in dark chlorination, and one-chlorine-containing components were the dominant species. The different products from chlorine substitution reactions (SR) and addition reactions (AR) suggested that SR often occurred in the precursors owning higher H/C ratio and AR often occurred in the precursors owning higher aromaticity. Post-chlorination further caused the cleavages of NOM structures into small molecular weight compounds, removed CHON compounds and enhanced the formation of Cl-DBPs. The results provide information about NOM transformation and Cl-DBPs formation at molecular levels in the UV/chlorine AOP.     

云南省农业自然灾害区划指标之探讨

自然灾害区划是防灾减灾和灾害科学研究的重要内容，而正确地选取区划指标是进行区划工作的关键环节。本文作为《云南省农业自然灾害区划研究》课题的一部分，在探讨各单项灾害（干旱、洪涝、低温霜冻、风雹、水土流失）区划指标的基础上，提出了综合农业自然灾害区划的基本指标－即“综合农业自然灾害指数”，并对指标进行了分级，为区划工作提供了依据。     

Assessment of physical economy through economy-wide material flow analysis in developing Uzbekistan

In this paper, we assess the physical dimensions of Uzbekistan's economy during 1992–2011 by using the economy-wide material flow analysis (EW-MFA) method, which is an internationally recognized tool for such assessments. There have been a number of studies using methodological standardization of EW-MFA, but to the best of our knowledge, it has never been used to assess the metabolism of Central Asian economies, especially, in this case, the Republic of Uzbekistan.Our analysis strives to empirically evaluate macroscopic economic activities by considering the accounting of material flows. The material flows data-set comprises of consistent data for domestic extraction, imports, and exports, as well as other derived MFA-based indicators.The derived indicators are internationally compared for further evaluation of national economic development performance in a given period. The indicators of direct material input (DMI) and total material requirements (TMR) showed a slight increase in 1992–2011 with an average annual increase of 2.79% and 2.34%. The trends of TMR, DMI, domestic material consumption (DMC) and material efficiency, which is indicated by GDP/DMI, displayed lower values than other industrialized countries referenced in the international comparison. Although national economic performance data showed particularly remarkable success, indicators measuring material inputs and DMC reveal an insignificant increase during the period of study. During the second decade of study period, relative decoupling has occurred which indicated that the economic indicator (GDP) grows faster than DMC and other macro indicators grow.     

Allocation solutions for secondary material production and end of life recovery: Proposals for product policy initiatives

This paper aims at analysing how secondary materials production and end of life recovery processes are modelled in life cycle-based environmental assessment methods in order to discuss their suitability in product policy-support contexts, with a focus on Sustainable Consumption and Production (SCP) policies. The equations prescribed in three published, widely recognised standards are evaluated. In addition, more recent modelling approaches that have been adopted in the context of two EU product policy initiatives (the Product Environmental Footprint (PEF) and the Resource Efficiency Assessment of Products (REAPro)) are similarly analysed. All of the methods are scrutinised against eight criteria which we deem to be important in product policy-support contexts, including comprehensiveness, accommodation of open-loop and closed-loop product systems, and consideration of recyclability/recoverability rates, to name a few. Based on this analysis, it is suggested that the PEF and REAPro modelling approaches appear to be better suited for use in product policy-support contexts than do the currently widely endorsed methods that we considered.     

Real-world gaseous emission characteristics of natural gas heavy-duty sanitation trucks

As compared to conventional diesel heavy-duty vehicles, natural gas vehicles have been proved to be more eco-friendly due to their lower production of greenhouse gas and pollutant emissions, which are causing enormous adverse effects on global warming and air pollution. However, natural gas vehicles were rarely studied before, especially through on-road measurements. In this study, a portable emission measurement system (PEMS) was employed to investigate the real-world emissions of nitrogen oxides (NOx) (nitrogen monoxide (NO), nitrogen dioxide (NO₂)), total hydrocarbons (THC), carbon monoxide (CO), and carbon dioxide (CO₂) from two liquified natural gas (LNG) China V heavy-duty cleaning sanitation trucks with different weight. Associated with the more aggressive driving behaviors, the vehicle with lower weight exhibited higher CO₂ (3%) but lower NOx (48.3%) (NO₂ (78.2%) and NO (29.4%)), CO (44.8%), and THC (3.7%) emission factors. Aggressive driving behaviors were also favorable to the production of THC, especially those in the medium-speed range but significantly negative to the production of CO and NO₂, especially those in the low-speed range with high engine load. In particular, the emission rate ratio of NO₂/NO decreased with the increase of speed/scaled tractive power in different speed ranges.     

Determining heavy metals in spent compact fluorescent lamps (CFLs) and their waste management challenges: Some strategies for improving current conditions

From environmental viewpoint, the most important advantage of compact fluorescent lamps (CFLs) is reduction of green house gas emissions. But their significant disadvantage is disposal of spent lamps because of containing a few milligrams of toxic metals, especially mercury and lead. For a successful implementation of any waste management plan, availability of sufficient and accurate information on quantities and compositions of the generated waste and current management conditions is a fundamental prerequisite. In this study, CFLs were selected among 20 different brands in Iran. Content of heavy metals including mercury, lead, nickel, arsenic and chromium was determined by inductive coupled plasma (ICP). Two cities, Tehran and Tabriz, were selected for assessing the current waste management condition of CFLs. The study found that waste generation amount of CFLs in the country was about 159.80, 183.82 and 153.75 million per year in 2010, 2011 and 2012, respectively. Waste generation rate of CFLs in Iran was determined to be 2.05 per person in 2012. The average amount of mercury, lead, nickel, arsenic and chromium was 0.417, 2.33, 0.064, 0.056 and 0.012 mg per lamp, respectively. Currently, waste of CFLs is disposed by municipal waste stream in waste landfills. For improving the current conditions, we propose by considering the successful experience of extended producer responsibility (EPR) in other electronic waste management. The EPR program with advanced recycling fee (ARF) is implemented for collecting and then recycling CFLs. For encouraging consumers to take the spent CFLs back at the end of the products’ useful life, a proportion of ARF (for example, 50%) can be refunded. On the other hand, the government and Environmental Protection Agency should support and encourage recycling companies of CFLs both technically and financially in the first place.     

水资源管理模式发展趋势探析

随着工业进步和社会发展,水污染亦日趋严重,已对人类的生存安全构成重大威胁,成为人类健康、经济和社会可持续发展的重大障碍。水安全与水资源管理是全球战略问题,如何进行水资源管理和研究也是当今社会面临的难题。本文就水资源管理模式发展趋势进行阐述。