Effect of initial temperature on explosion characteristics of 2, 3, 3, 3–Tetrafluoropropene

The flammability of refrigerants is a major cause of refrigerant explosion incidents. Studying the explosion characteristics of refrigerants at different initial temperatures can provide significant benefits for solving the safety problems of refrigerants under actual working conditions. This paper studied the effects of the initial temperature and refrigerant concentration on the explosion characteristics of refrigerant 2, 3, 3, 3-tetrafluoropropene (R1234yf) at 0.1 MPa. The curves of explosion characteristics with different initial temperature revealed the same variation trend ranged from 25 °C to 115 °C. Specifically, as the refrigerant concentration was raised, the peak overpressure, the maximum rate of pressure rise, and laminar burning velocity increased initially and decreased afterwards, along with maximum values at the refrigerant concentration of 7.6%. When the refrigerant concentration was 7.6%, the peak overpressure declined exponentially with the initial temperature rise, while the maximum rate of pressure rise increased linearly. The laminar burning velocity calculated from the spherical expansion method indicated that the flame propagation was gradually accelerated by the increase of initial temperature, which coincided with the change of the maximum rate of pressure rise. Meanwhile, experiments and CHEMKIN simulation results demonstrated the effects of elevated temperature from 20 °C to 50 °C on the explosion limits of R1234yf. The lower explosion limit reduced and the upper explosion limit increased with rising initial temperature. In general, R1234yf exhibited moderate combustion and lower explosion risk, compared with traditional refrigerants.     

耐酸性异养菌的分离及其在制革污泥重金属生物淋滤中的作用

从制革污泥中分离出一株异养微生物,经鉴定属于红酵母菌属(Rhodotorula sp.)R30, 测定菌株R30的适宜生长pH范围为3～7,但能耐受pH 2.5至1.5的酸性环境,最适生长温度28℃.酵母R30在污泥水溶性有机物(DOM)中培养96h,水溶性有机碳(DOC)从1485mg/L降至345mg/L,菌数达4.8×10⁷mL^-1.将污泥预酸化至pH 6.5,在进行污泥的生物淋滤过程中,添加酵母处理与不添加酵母处理的对照相比,淋滤时间减少了4d,淋滤周期显著缩短,在7d的淋滤时间内,重金属Cr的溶出率提高39%.     

分光光度法测定水中铍的最佳条件选择

本文对分光光度法测定水中铍的最佳测定条件进行了研究和探讨。在方法对比实验的基础上,选择了最适宜的方法,并进行了各种条件实验,对某些实验条件进行了改进。特别是对阴离子的干扰,提出了有效的消除方法。改进后的实验方法,显色稳定,重现性好,灵敏度高,摩尔吸光系数达１．０１×１０５Ｌ／ｃｍ·ｍｏｌ。     

自然灾害发生时间序列的分形特征及R/S分析

统计了公元960年到1979年我国地震、洪涝和台风风暴潮灾害发生的时间及死亡人数,以分形几何中的Cantor集合为模型,发现我国自然灾害发生时间序列的分布呈现出明显的分形特征,并采用Smalley方法分别计算了不同灾害发生时间序列分布的分维值,它们均在0.5左右,同严格意义上的数学分形Cantor集合相比分维较小,说明我国地震等自然灾害发生发展的自组织程度还有进一步发展的趋势,其危害程度将可能进一步提高;在自然灾害发生时间序列的分形特征的基础上,通过R/S分析,得出3种自然灾害发生时间序列的H指数均在0.28左右,同日斑指数、树木年轮、湖泊水位变化等自然现象相比较小,说明自然灾害的发生具有短程相关性,其发生规律没有日斑指数等自然现象明显.该研究对于进一步认识和研究我国地震等自然灾害的发生规律和发展趋势等具有一定意义.     

混沌理论在事故分析及预测中的应用

在对江苏常州市某公司安全事故资料进行大量调查与统计的基础上,应用混沌理论分析了该公司安全事故的混沌特征,指出了事故对初始条件的敏感依赖性和事故的长期不可预测性。应用重构相空间理论对安全事故次数的时间序列进行了分析和预测。同时,还对安全事故统计资料进行了R/S分析,得出该时间序列以2 0 0 1年6月为界限,存在两个Hurst指数,H1=1.6 82 8和H2 =0 .2 936 ,表明在以3个月为时间统计尺度的条件下,事故发生次数在前一时间段整体表现为持久相关性,而在后一时间段表现为反持久相关性。预测与分析结果与实际情况符合较好,表明应用混沌理论进行事故分析与预测是可行的,反映了事故的发展趋势。     

Effects of recreational use on forested sites

Impact of recreational activities on soil and vegetation was evaluated in eight forested camping and picnic areas in southern Rhode Island. Forest vegetation consists of mixed-oak and white pine stands. Soils are of granitic glacial till or outwash origin and textures range from loamy sand to find sandy loam. Recreational use resulted in significant compaction of soils as indexed by soil penetration resistance and bulk density. Evidence indicates that compaction influences bulk densities to a depth of about 12.7 cm. Rates of water infiltration are less on recreation areas. Soil water accretion and depletion during the growing season are less rapid on recreation sites than on control sites. Differences are attributed to reduced infiltration, percolation, and rooting activity. Much of the ground surface on recreation areas is devoid of vegetation. The surface consists primarily of bare mineral soil, rock, or litter. The plants most commonly present are grasses. Native ground cover vegetation including tree seedlings, ericaceous shrubs and herbs has been eliminated or greatly reduced by trampling. Damage to tree trunks is common in recreation areas. White pine radial growth and scarlet oak height growth were significantly less on recreation sites. Scarlet oak appears intolerant to heavy recreation use.     

基于 M －MP2R 的现代安全管理方法研究

如何减少事故造成的人员伤亡和经济损失,有效预防事故及高效处置事故是现代安全管理研究的方向。基于PDCA理论的研究以及现代应急管理和现代安全管理的发展趋势,提出M －MP2R动态的现代安全管理新方法,构建M－MP2R模型与体系,模拟出M－MP2R运行流程,分析M－MP2R的特点,并指出其存在的问题,丰富了现代安全管理的研究内容。     

R/S法的土石坝施工期沉降规律及预警标准研究

为提高施工期土石坝沉降安全性,研究其具有复杂非线性特征的施工期沉降规律和相应的预警标准。基于国内某在建高土石坝的沉降数据,采用R/S法分析坝体不同高程测点、同高程测点和同测点不同时期沉降数据的Hurst指数及分形维数,提出评价坝体施工期沉降安全性的预警标准。结果表明:各测点的Hurst指数最小值为0.763,坝内各处沉降仍处于快速增长阶段;坝体下部比上部、中部比下游堆石区沉降能更快趋于稳定,且坝体下部的沉降速率已经渐趋平缓。