Risk assessment and binding mechanisms of potentially toxic metals in sediments from different water levels in a coastal wetland

The excessive accumulation of potentially toxic metals (Pb and Cd) in coastal wetlands is among the main factors threatening wetland ecosystems. However, the effects of water table depth (WTD) on the risk and binding mechanisms of potentially toxic metals in sediments remain unclear. Here, sediments from different WTD obtained from a typical coastal wetland were evaluated using a newly developed strategy based on chemical extraction methods coupled with high-resolution spectroscopy. Our findings indicated that the WTD of the coastal wetland fluctuates frequently and the average enrichment factor for Pb was categorized as minor, whereas Cd enrichment was categorized as moderate. High-resolution spectroscopy techniques also demonstrated that organic functional groups and partly inorganic compounds (e.g., Fe-O/Si-O) played a vital role in the binding of Pb and Cd to surface sediments. Additionally, mineral components rather than organic groups were mainly bound to these metals in the bottom sediments. Collectively, our findings provide key insights into the potential health effects and binding characteristics of potentially toxic metals in sediments, as well as their dynamic behavior under varying sediment depths at a microscale.     

Risk factors for driving into flooded roads

Motor vehicle-related deaths account for more than half of all flood fatalities in the United States, but to date, very little is known about the risk factors associated with why people drive into flooded roads. Using data from survey questionnaires administered in Denver, CO, and Austin, TX, this paper suggests that people who do not take warnings seriously are more likely to drive through flooded roads, as are people aged 18–35, and those that do not know that motor vehicles are involved in more than half of all flood fatalities. In Denver, people who have not experienced a flood previously and those who do not know they live in flood-prone areas are also more likely to drive into flooded roads.     

Mapping social vulnerability to natural hazards in Italy: A suitable tool for risk mitigation strategies

Italy is one of the European countries that are most heavily exposed to a wide range of natural hazards, which might cause large economic losses. In this context, the assessment of social vulnerability has an important role for evaluating the capacity of a community to prepare for, respond to and recover from disasters. However there are currently no published studies analysing social vulnerability and its spatial distribution in Italy. Within this framework, this paper aims to apply a proven method for assessing social vulnerability at the national scale, while considering the contribution of the socioeconomic and demographic factors that affect the Italian population. The proposed methodology is based on the Hazard-of-Place Model approach, and uses free and open source software applications (FOSS). Specifically, we selected significant components through Principal Component Analysis and derived their spatial distribution. Using component scores, we derived a social vulnerability index, evaluated its geographic distribution, and performed a cluster analysis on its spatial variation. The analysis identified different spatial patterns across Italy, providing useful information for identifying the communities most likely to experience negative natural disaster impacts due to their socioeconomic and demographic characteristics. This research represents an important contribution to improve the potentiality of risk mitigation strategies and in designing risk custom-made policies.     

Reducing the risk level for pipelines transporting carbon dioxide and hydrogen by means of optimal safety valves spacing

In many countries where electricity generation is based on their natural resources of fossil fuels a need arises to implement new power engineering technologies that allow carbon dioxide capture. Simultaneously, efforts are made to find new energy carriers which, if fired, do not involve carbon dioxide emissions. Hydrogen is one of such fuels with this future potential which is now becoming increasingly popular. Obviously, this means that the two gases mentioned above – carbon dioxide and hydrogen – will be produced in large quantities in future, which in many cases will necessitate their transport over considerable distances. If a pipeline failure occurs, the transport of the gases may pose a serious hazard to people in the immediate vicinity of the leakage site. This paper presents an analysis of the possibility of reducing the level of risk related to pipelines transporting CO₂ and H₂ by means of safety valves. It is shown that for a 50 km long and a 0.4 m diameter pipeline transporting gas with the pressure of 15 MPa the individual risk level can be reduced from 1·10⁻⁴ to 6.5·10⁻⁷ for CO₂ and from 1·10⁻⁶ to 6·10⁻¹⁰ for H₂. The social risk can be diminished in similar proportions.     

Database for accidents and incidents in the fuel ethanol industry

The purpose of the present research is to collect information about accidents and incidents that have occurred at fuel ethanol facilities from 1998 to October 2014, and to keep complete unified records of them in a database. The developed database contains general information about the accident or incident, its sequence, mitigation measures, its causes and consequences for humans, environment and for the plant. Until now, this information is not available. The work consisted in gathering information from different documental sources and subsequent organization in a database. It complements the previous work made for biodiesel industry and fills the existing gap in the field of ethanol. Knowledge about this information enables us to manage plant risks, since the accidents that are more likely to occur and the main sources of risk can be easily identified. Also, it makes it possible to exchange information with interested third parties. Statistical analysis shows that accident frequency has an oscillatory behavior, rising in the last year. Fire is the most common type of accident, while equipment mechanical failure is the main cause of accident. Partial material loss has been identified as the most common consequence. Finally, some conclusions are obtained concerning to the importance of having an updated and complete accident and incident database.     

Method to analyze the regional life loss risk by airborne chemicals released after devastating earthquakes: A simulation approach

Widespread chemical plants render human life more vulnerable to major natural disasters such as earthquakes. Recognizing the potential cascading threats initiated by a devastating earthquake, a general methodology for assessing the life loss risks introduced by airborne hazardous chemical dispersion following seismically induced chemical release (SICR) was proposed. With a 600 km × 600 km region in North China as a demonstrative study area, the dispersion of ammonia released from multiple relevant chemical plants that were supposed to be damaged by a devastating earthquake was simulated in a probabilistic manner. Using an ammonia toxicity-fatality relationship and its toxicity concentration threshold, regional life loss and spatial spread were evaluated. The life loss risk was found to be non-prominent but would be very contingent on unfavorable meteorological conditions. Non-parametric correlation analysis revealed that the respective effects of meteorological mixing parameters on the risk exhibit new features in a disaster context, that is, stronger mixing would cause elevation of risk in a region. This preliminary research implied that the risk of chemical-induced life loss after a devastating earthquake deserves attention and a thorough uncertainty evaluation in the future.     

Predicting the aquatic risk of realistic pesticide mixtures to species assemblages in Portuguese river basins

Although pesticide regulatory tools are mainly based on individual substances, aquatic ecosystems are usually exposed to multiple pesticides from their use on the variety of crops within the catchment of a river. This study estimated the impact of measured pesticide mixtures in surface waters from 2002 and 2008 within three important Portuguese river basins (‘Mondego’, ‘Sado’ and ‘Tejo’) on primary producers, arthropods and fish by toxic pressure calculation. Species sensitivity distributions (SSDs), in combination with mixture toxicity models, were applied. Considering the differences in the responses of the taxonomic groups as well as in the pesticide exposures that these organisms experience, variable acute multi-substance potentially affected fractions (msPAFs) were obtained. The median msPAF for primary producers and arthropods in surface waters of all river basins exceeded 5%, the cut-off value used in the prospective SSD approach for deriving individual environmental quality standards. A ranking procedure identified various photosystem II inhibiting herbicides, with oxadiazon having the relatively largest toxic effects on primary producers, while the organophosphorus insecticides, chlorfenvinphos and chlorpyrifos, and the organochloride endosulfan had the largest effects on arthropods and fish, respectively. These results ensure compliance with European legislation with regard to ecological risk assessment and management of pesticides in surface waters.     

Risk assessment of Giardia from a full scale MBR sewage treatment plant caused by membrane integrity failure

Membrane bioreactors (MBR) are highly efficient at intercepting particles and microbes and have become an important technology for wastewater reclamation. However, many pathogens can accumulate in activated sludge due to the long residence time usually adopted in MBR, and thus may pose health risks when membrane integrity problems occur. This study presents data from a survey on the occurrence of water-borne Giardia pathogens in reclaimed water from a full-scale wastewater treatment plant with MBR experiencing membrane integrity failure, and assessed the associated risk for green space irrigation. Due to membrane integrity failure, the MBR effluent turbidity varied between 0.23 and 1.90 NTU over a period of eight months. Though this turbidity level still met reclaimed water quality standards (≤5 NTU), Giardia were detected at concentrations of 0.3 to 95 cysts/10 L, with a close correlation between effluent turbidity and Giardia concentration. All β-giardin gene sequences of Giardia in the WWTP influents were genotyped as Assemblages A and B, both of which are known to infect humans. An exponential dose-response model was applied to assess the risk of infection by Giardia. The risk in the MBR effluent with chlorination was 9.83 × 10^-3, higher than the acceptable annual risk of 1.0 × 10^-4. This study suggested that membrane integrity is very important for keeping a low pathogen level, and multiple barriers are needed to ensure the biological safety of MBR effluent.     

关于老工业区污染场地管理的探讨

根据在某老工业区第1批28块场地环境调查的实践,对污染场地管理中存在的问题进行了分析并提出了相应改进建议：①获取准确的场地资料难度很大,建议研究制定场地全过程档案管理制度;②工业企业关闭搬迁会产生新的环境污染风险,工业企业关闭搬迁应该成为污染场地管理的重要环节,环保部门应该在工业企业搬迁前介入,严格监管整个过程中的环境污染;③大量区域由于其中污染严重、风险高的场地缺乏修复资金而难以再开发利用,建议结合规划优先启动资金投入低的污染较轻区域修复,并同时对风险较高的污染场地进行风险管控,当区域开发取得一定规模、成就和收益后,可以整合资金力量和资源开展污染较重区域的修复。     

焦化行业环境风险预测应用

以焦化行业中典型企业——徐州某焦化生产企业年产100万t捣固焦生产线项目为例,采用新的评价体系和数学模式对项目环境风险进行定量的预测评价,在环境风险定量预测方面作出了有益的尝试,对同类焦化行业环境风险预测及防范具有很好的借鉴意义.