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51.
Pan X Tang J Chen Y Li J Zhang G 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3515-3521
PCN congeners were analyzed in marine and riverine sediments of the Laizhou Bay area, North China. Concentrations of PCNs ranged from 0.12 to 5.1 ng g−1 dry weight (dw) with a mean value of 1.1 ng g−1 dw. The levels of PCNs varied largely, with industrial group approximately ten folds higher than those of the rural in riverine sediment. A strong impact by direct discharge from local factories was suggested. Similar compositional profiles were found within groups. High resemblance of compositional profiles between industrial samples and Halowax 1014 was observed. It was indicated that PCNs in riverine sediments were mainly from release of industrial usage, with additional contributions from industrial thermal process at certain sites. In marine sediments, it was suggested that PCNs along the coast of Laizhou Bay were mainly controlled by riverine input. While in the central bay, PCN distributions were possibly impacted by combined multiple factors. 相似文献
52.
Opel O Palm WU Steffen D Ruck WK 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):924-931
Comparability of sediment analyses for semivolatile organic substances is still low. Neither screening of the sediments nor organic-carbon based normalization is sufficient to obtain comparable results. We are showing the interdependency of grain-size effects with inside-sediment organic-matter distribution for PAH, PCB and organochlorine compounds. Surface sediment samples collected by Van-Veen grab were sieved and analyzed for 16 PAH, 6 PCB and 18 organochlorine pesticides (OCP) as well as organic-matter content. Since bulk concentrations are influenced by grain-size effects themselves, we used a novel normalization method based on the sum of concentrations in the separate grain-size fractions of the sediments. By calculating relative normalized concentrations, it was possible to clearly show underlying mechanisms throughout a heterogeneous set of samples. Furthermore, we were able to show that, for comparability, screening at <125 μm is best suited and can be further improved by additional organic-carbon normalization. 相似文献
53.
Partitioning behaviour of perfluorinated alkyl contaminants between water, sediment and fish in the Orge River (nearby Paris, France) 总被引:3,自引:0,他引:3
This paper reports on the partitioning behaviour of 15 perfluorinated compounds (PFCs), including C4-C10 sulfonates and C5-C14 carboxylic acids, between water, sediment and fish (European chub, Leuciscus cephalus) in the Orge River (nearby Paris). Total PFC levels were 73.0 ± 3.0 ng L−1 in water and 8.4 ± 0.5 ng g−1 in sediment. They were in the range 43.1-4997.2 ng g−1 in fish, in which PFC tissue distribution followed the order plasma > liver > gills > gonads > muscle. Sediment-water distribution coefficients (log Kd) and bioaccumulation factors (log BAF) were in the range 0.8-4.3 and 0.9-6.7, respectively. Both distribution coefficients positively correlated with perfluoroalkyl chain length. Field-based biota-sediment accumulation factors (BSAFs) are also reported, for the first time for PFCs other than perfluorooctane sulfonate. log BSAF ranged between −1.3 and 1.5 and was negatively correlated with the perfluoroalkyl chain length in the case of carboxylic acids. 相似文献
54.
S.M. Pan S.G. TimsX.Y. Liu L.K. Fifield 《Journal of environmental radioactivity》2011,102(10):930-936
A sediment core collected from the sub-aqueous delta of the Yangtze River estuary was subjected to analyses of 137Cs and plutonium (Pu) isotopes. The 137Cs was measured using γ-spectrometry at the laboratories at the Nanjing University and Pu isotopes were determined with Accelerator Mass Spectrometry (AMS), measurements made at the Australian National University. The results show considerable structure in the depth concentration profiles of the 137Cs and 239+240Pu. The shape of the vertical 137Cs distribution in the sediment core was similar to that of the Pu. The maximum 137Cs and 239+240Pu concentrations were 16.21 ± 0.95 mBq/g and 0.716 ± 0.030 mBq/g, respectively, and appear at same depth. The average 240Pu/239Pu atom ratio was 0.238 ± 0.007 in the sediment core, slightly higher than the average global fallout value. The changes in the 240Pu/239Pu atom ratios in the sediment core indicate the presence of at least two different Pu sources, i.e., global fallout and another source, most likely close-in fallout from the Pacific Proving Grounds (PPG) in the Marshall Islands, and suggest the possibility that Pu isotopes are useful as a geochronological tool for coastal sediment studies. The 137Cs and 239+240Pu inventories were estimated to be 7100 ± 1200 Bq/m2 and 407 ± 27 Bq/m2, respectively. Approximately 40% of the 239+240Pu inventory originated from the PPG close-in fallout and about 50% has derived from land-origin global fallout transported to the estuary by the river. This study confirms that AMS is a useful tool to measure 240Pu/239Pu atom ratio and can provide valuable information on sedimentary processes in the coastal environment. 相似文献
55.
Oikawa S Watabe T Inatomi N Isoyama N Misonoo J Suzuki C Nakahara M Nakamura R Morizono S Fujii S Hara T Kido K 《Journal of environmental radioactivity》2011,102(3):302-310
A radioactivity survey was launched in 1991 to determine the background levels of 239+240Pu in the marine environment off a commercial spent nuclear fuel reprocessing plant before full operation of the facility. Particular attention was focused on the 240Pu/239Pu atom ratio in seawater and bottom sediment to identify the origins of Pu isotopes. The concentration of 239+240Pu was almost uniform in surface water, decreasing slowly over time. Conversely, the 239+240Pu concentration varied markedly in the bottom water and was dependent upon the sampling point, with higher concentrations of 239+240Pu observed in the bottom water sample at sampling points having greater depth. The 240Pu/239Pu atom ratio in the seawater and sediment samples was higher than that of global fallout Pu, and comparable with the data in the other sea area around Japan which has likely been affected by close-in fallout Pu originating from the Pacific Proving Grounds. The 240Pu/239Pu atom ratio in bottom sediment samples decreased with sea depth. The land-originated Pu is not considered as the reason of the increasing 239+240Pu concentration and also decreasing the 240Pu/239Pu atom ratio with sea depth, and further study is required to clarify it. 相似文献
56.
Wakefield R Tyler AN McDonald P Atkin PA Gleizon P Gilvear D 《Journal of environmental radioactivity》2011,102(3):252-261
High spatial and temporal resolution airborne imagery were acquired for the Ribble Estuary, North West England in 1997 and 2003, to assess the application of time-series airborne remote sensing to quantify total suspended sediment and radionuclide fluxes during a flood and ebb tide sequence. Concomitant measurements of suspended particulate matter (SPM) and water column turbidity were obtained during the time-series image acquisition for the flood and ebb tide sequence on the 17th July 2003 to verify the assumption of a vertically well mixed estuary and thus justifying the vertical extrapolation of spatially integrated estimate of surface SPM. The 137Cs activity concentrations were calculated from a relatively stable relationship between SPM and 137Cs for the Ribble Estuary. Total estuary wide budgets of sediment and 137Cs were obtained by combining the image-derived estimates of surface SPM and 137Cs with estimates of water volume from a two-dimensional hydrodynamic model (VERSE) developed for the Ribble Estuary. These indicate that around 10,000 tonnes of sediment and 2.72 GBq of 137Cs were deposited over the tidal sequence monitored in July 2003. This compared favourably with bed height elevation change estimated from field work. An uncertainty analysis on the total sediment and 137Cs flux yielded a total budget of the order of 40% on the final estimate. The results represent a novel approach to providing a spatially integrated estimate of the total net sediment and radionuclide flux in an intertidal environment over a flood and ebb tide sequence. 相似文献
57.
M. Noble P. C. Oloffs R. So J. Yee F. Yuen 《Journal of environmental science and health. Part. B》2013,48(5):359-373
Abstract A tubular device has been developed making it possible to obtain layered samples of loosely aggregated, flocculent material from bogs or eutrophic lakes. The samples are up to 50 cm long and 15 cm in diameter. The sampler is free from protuberances and intact, layered samples can be taken. The tubular part of the sampler is about 85 em long, the walls of the lower 25‐cm portion harbouring a pneumatic closing mechanism which is controlled from above the water surface. An extendible handle for manipulating the sampler and for guiding it into place, is fastened to the upper end of the sampling tube. The performance and the operation of the sampler in the field are described. 相似文献
58.
Jiri Marsalek 《Journal of the American Water Resources Association》1991,27(2):283-291
ABSTRACT: A review of methods for planning-level estimates of pollutant loads in urban stormwater focuses on transfer of charac. teristic runoff quality data to unmonitored sites, runoff monitoring, and simulation models. Load estimation by transfer of runoff quality data is the least expensive, but the accuracy of estimates is unknown. Runoff monitoring methods provide best estimates of existing loads, but cannot be used to predict load changes resulting from runoff controls, or other changes of the urban system. Simulation models require extensive calibration for reliable application. Models with optional formulations of pollutant build up, washoff, and transport can be better calibrated and the selection of options should be based on a statistical analysis of calibration data. Calibrated simulation models can be used for evaluation of control alternatives. 相似文献
59.
The Neebing-McIntyre floodway in Thunder Bay, Ontario, Canada, has been constructed with a relatively straight and uniform trapezoidal channel, compared with the prechannelized sinuous reaches of the Neebing and the McIntyre rivers. The flow regime of the floodway also contrasts significantly with the prechannelized regime, because of the combination of discharges from these rivers into a new channel and the regulation of flows by a diversion structure. The maximum channel capacity of the floodway is about 284 m3 s–1 (175-year regional flood), compared with about 40 m3 s–1 and 60 m3 s–1, respectively, for the Neebing and the McIntyre. According to regime theories, the construction of a straight and trapezoidal channel has upset the equilibrium of the stream system and therefore should lead to some accelerated erosion and sedimentation processes in the new channel immediately after construction. Erosion potential is particularly high during higher discharge events, when flow velocities are expected to be greater than the prechannelized velocities of the Neebing and the McIntyre. The overall sediment yield of the watershed is low (71t km–2 yr–1), compared with other documented watersheds of North America, but the rates of deposition in the floodway are relatively high, mainly due to the backwater effect of Lake Superior. Unless maintained by constant channel work, the floodway will tend to fill up with sediment, until a postconstructional equilibrium is reestablished. 相似文献
60.