上海大气氮湿沉降的污染特征

为探讨上海大气氮湿沉降的污染特征,采集了2007年11月至2008年10月上海雨水样品,分析了大气氮湿沉降浓度,探讨了上海大气湿沉降氮通量及上海市区,市郊和远郊大气氮湿沉降的时空污染特征.结果表明:(1)上海市区、市郊和远郊大气氮湿沉降质量浓度平均值分别为2.96、2.31、2.21 mg/L.从上海大气湿沉降总体来看,大气氮湿沉降劣V类、V类的超标率分别达到51.09%和13.87%.推断大气氮湿沉降的主要来源是机动车辆所排放的大量氮氧化物.(2)除冬季外,其余季节上海市区大气氮湿沉降浓度均大于市郊和远郊;市区和远郊大气氮湿沉降浓度均在秋季最大,市郊大气氮湿沉降浓度在春季最大.(3)上海大气年氮湿沉降通量为78.42 kg/hm~2,同其他区域相比较,属于世界上高氮沉降区域.(4)上海大气月氮沉降通量与月平均降雨量呈显著的线性正相关(p<0.05),说明上海大气氮湿沉降通量主要受降雨量的影响.     

上海人口变化与资源环境效应分析

作为特大型城市,上海2008年常住人口总量已达1 888万,城市化水平也以87%高居全国首位.通过分析上海1978-2008年30年来人口变化特征及其资源环境效应表明,伴随着人口规模不断扩大和城市化水平快速提升,2008年上海居民生活电耗和水耗分别是1978年的17倍和5倍,占资源消费总量的比例也逐年快速攀升;生活废水排放量已取代工业废水成为最大贡献源,占废水排放总量的比例高达80%;生活废气排放总量相对稳定.针对上海实现可持续发展所面临的人口难题,从依据人口发展规律调整城市发展战略,通过产业结构调整带动经济增长方式转变,切实加大环保投入力度促进治污防污,进一步提高公众环保意识和企业环保责任等几个方面提出了破解这一难题的对策与建议.     

河口及邻近海域鱼类优先保护次序的评价模型

正确评价河口及邻近海域鱼类优先保护次序,对河口生态管理以及维持生物多样性具有重要意义,而鱼类优先保护次序评价指标体系和评价方法研究是珍稀鱼类保护的基础。在实地调查和资料收集的基础上,借助专家咨询和相关研究成果提出了由物种濒危系统、遗传价值系统和物种价值系统3个子系统及其指标集组成的鱼类优先保护评价指标体系,确定了评价等级和标准。为克服权重确定的主观随意性,基于信息熵原理确定各指标的客观权重,在此基础上,引入理想点法进行鱼类优先保护多目标决策评价,进而建立了鱼类优先保护次序的评价模型,最后以建立的模型对漳卫新河口及邻近海域鱼类优先保护次序进行评价。结果表明,计算方法简便,评价结果合理,在河口生态管理中具有一定的应用价值     

上海城市草坪CO2排放通量特征及其影响因子

草坪是城市绿地系统的重要组成部分,为量化其在城市碳平衡中的作用,采用静态箱 气相色谱法对上海结缕草草坪CO2排放通量进行了研究。结果表明：CO2排放通量具有明显的日变化和季节变化特征,日变化表现为昼高夜低的特点,最大排放通量一般出现在正午前后,最小在清晨,最大日较差为1 1877 mg/（m2·h）（7月1日）,最小892 mg/（m²·h）（1月3日）。CO₂排放通量的季节变化呈单峰型,夏季7月最大,春秋季次之,冬季1月最小,与温度的季节变化一致。观测期间年平均CO2排放通量为6194 mg/（m2·h）。对上海城市结缕草草坪观测期间,温度是CO2排放通量变化的主要影响因素。研究成果不仅可为城市草坪碳排放提供基础数据,也可为城市碳循环研究和管理提供参考.     

Polychlorinated biphenyls contamination in urban soil of Shanghai: level, compositional profiles and source identification

Surface soil samples taken from 55 sampling sites at the urban areas of Shanghai were collected and analyzed for the occurrence of 144 polychlorinated biphenyls (PCBs) by GC-μECD. The results showed that totally 74 PCB congeners were identified and the mean concentration of total PCBs was 3057 ng kg⁻¹ with a range of 232 to 11325 ng kg⁻¹. Compared with the related reports, the level of PCBs contamination in this study was approximately equal to the global background value in soils, but higher than Chinese background for rural and urban soils. According to the compositional profiles of PCBs homologues, a higher proportion of low chlorinated (from tri-CBs to hexa-CBs) was observed. The results indicated that PCB15 + 13, PCB18, PCB28, PCB104 + 47 and PCB153 were the most dominant congeners among the identified PCBs. Through homologues analysis, cluster analysis and principal component analysis (PCA), it was found that PCBs were stretched from mixed local sources, and appeared to be mostly originated by Aroclor 1260- and 1254-like mixtures as well as some samples influenced by Aroclor 1232 and 1242. The correlation analysis showed the relatively good correlation among the PCB homologues and soil total organic carbon (TOC), suggesting important influence of soil TOC on PCBs contamination in soil matrix in Shanghai region. The toxic equivalency (TEQ) concentrations of these six dioxin-like PCBs detected in urban soil samples range from 2.71 to 24.9 pg kg⁻¹-PCDDeq with a mean 8.18 pg kg⁻¹-PCDDeq.     

海上含聚油泥处理后泥水的回注

采用热化学法处理某海上平台含聚油泥(矿物含量(w)1.30%~3.74%,聚合物含量(w)3.37%~7.42%),研究了反应后分离出的泥水的回注性能,并进行了现场回注试验。实验结果表明:泥水经研磨细化处理后,95%(w)的细化污泥粒径不超过7.86μm,远小于注入地层的平均孔喉直径;在含聚量为1 750 mg/L的注聚液中加入500 mg/L的细化污泥,65℃(油藏温度)下,细化污泥在注聚液中具有很好的稳定性,体系黏度变化小;泥水中的污水与注聚液、采出污水、现场采出液处理系统中使用的各种药剂的配伍性好。现场试验结果表明,将泥水加入注聚液中进行回注,注入井压力保持稳定。     

海上平台冷放空系统二氧化碳灭火释放量的设计

海上固定平台在设计采用冷放空取代火炬放空时,需要考虑到冷放空口发生火情时使用二氧化碳灭火的设计用量.笔者根据有关灭火规范进行了分析计算,并结合实例提出合理的操作程序,以达到有效地减少设计用量的目的,同时指出海上平台应用冷放空系统在设计和操作上应注意的问题.     

改性核桃壳滤料对油田含油污水的过滤效果

采用亚硫酸氢镁蒸煮法对核桃壳滤料进行亲水改性,考察了改性核桃壳滤料对油田含油污水的过滤、反洗效果,探讨了改性前后核桃壳滤料的过滤过程及乳化油捕集机理。实验结果表明:在蒸煮温度为95℃、蒸煮时间为5 h、w(MgHSO_3)为5%的条件下,核桃壳滤料接触角由改性前的117.1°降至62.4°;分4批次过滤含油污水,改性核桃壳滤料的平均出水含油量为32.3 mg/L,平均油去除率为78.5%,平均浊度为7.7 NTU,平均浊度去除率为89.7%;改性核桃壳滤料的反洗效果显著改善,反洗水含油量由520 mg/L提高到840 mg/L,核桃壳滤料增重率由4.3%下降到0.2%。     

上海粮食中元素的含量及土壤的安全值

经对上海农村和粮食的多年调查研究，阐述小麦和水稻的质量状况，并作了评价。小麦和水稻籽粒中Ｃｄ，Ｐｈ，Ｎｉ，Ｃｒ，Ｈｇ的含量差不多，但Ｚｎ，Ｃｕ含量小麦〉水稻，Ｍｎ，Ａｓ含量为小麦〈水稻。局部地区小麦和水稻中镉的污染较重。在粮食含镉较高的地区，锌肥不宜喷用。公路附近粮食中含铅量较高，与汽车排放废气有关。     

Forecasting Up to Year 2000 on Shanghai's Environmental Quality

The capabilities of third world countries in dealing withenvironmental problems are often limited by available resources and the tremendous costs of environmental monitoring.This paper attempts to introduce a newmethodology that can be used to derive information aboutenvironmental quality in its spatial and temporal dimensions.This methodology, based on an inquiry-feedback network of 8,000families and iteration with controlled-feedback of expertcommunity, has been first tested in Shanghai, China andprocedurally can be divided into two steps: Base-year evaluationand forecasting. Fuzzy pattern recognition is introduced for thesubjective assessment of the citizens' feelings theirperceived environment and a four-round Delphi-Cross Impactanalysis is conducted for forecasting the environmental changesup to 2000. Results show that the base-year environmentalsituations were poor. In the foreseeable future, the conditionsfor housing, social services, public health, greenspace anddrinking water will be substantially improved. Due to the rapidgrowth of manufacturing, the city will continue its deteriorating trend of air and water quality into the next century according to the forecast.