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Radon-222 and carbon dioxide concentrations have been measured during several years at several points in the atmosphere of an underground limestone quarry located at a depth of 18 m in Vincennes, near Paris, France. Both concentrations showed a seasonal cycle. Radon concentration varied from 1200 to 2000 Bq m−3 in summer to about 800-1400 Bq m−3 in winter, indicating winter ventilation rates varying from 0.6 to 2.5 × 10−6 s−1. Carbon dioxide concentration varied from 0.9 to 1.0% in summer, to about 0.1-0.3% in winter. Radon concentration can be corrected for natural ventilation using temperature measurements. The obtained model also accounts for the measured seasonal variation of carbon dioxide. After correction, radon concentrations still exhibit significant temporal variation, mostly associated with the variation of atmospheric pressure, with coupling coefficients varying from −7 to −26 Bq m−3 hPa−1. This variation can be accounted for using a barometric pumping model, coupled with natural ventilation in winter, and including internal mixing as well. After correction, radon concentrations exhibit residual temporal variation, poorly correlated between different points, with standard deviations varying from 3 to 6%. This study shows that temporal variation of radon concentrations in underground cavities can be understood to a satisfactory level of detail using non-linear and time-dependent modelling. It is important to understand the temporal variation of radon concentrations and the limitations in their modelling to monitor the properties of natural or artificial underground settings, and to be able to assess the existence of new processes, for example associated with the preparatory phases of volcanic eruptions or earthquakes. 相似文献
64.
A gas explosion in an underground structure may cause serious damage to the human body and ground buildings and may result in huge economic losses. The pressure of the gas explosion is an important parameter in determining its severity and designating an emergency plan. However, existing empirical and computational fluid dynamics (CFD) methods for pressure prediction are either inaccurate or inefficient when considering multiple influencing factors and their interrelationships. Therefore, for a more efficient and reliable prediction, the present study developed a multifactorial prediction model based on a beetle antennae search (BAS) algorithm improved back propagation (BP) neural network. A total of 317 sets of data which considered factors of geometry, gas, obstacle, vent, and ignition were collected from previous studies. The results showed that the established model can predict pressures accurately by low RMSE (43.4542 and 50.7176) and MAPE (3.9666% and 4.9605%) values and high R2 (0.7696 and 0.7388) values for training and testing datasets, respectively. Meanwhile, the BAS algorithm was applied to improve both the calculation efficiency and the accuracy of the proposed model by enabling a more intelligent hyperparameter tuning method. Furthermore, the permutation importance of input variables was investigated, and the length (L) and the ratio of length and diameter (L/D) of geometry were found to be the most critical factors that affect the explosion pressure level. 相似文献
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As an efficient method for ammonium (NH4+) removal, contact catalytic oxidation technology has drawn much attention recently, due to its good low temperature resistance and short start-up period. Two identical filters were employed to compare the process for ammonium removal during the start-up period for ammonium removal in groundwater (Filter-N) and surface water (Filter-S) treatment. Two types of source water (groundwater and surface water) were used as the feed waters for the filtration trials. Although the same initiating method was used, Filter-N exhibited much better ammonium removal performance than Filter-S. The differences in catalytic activity among these two filters were probed using X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and compositional analysis. XRD results indicated that different manganese oxide species were formed in Filter-N and Filter-S. Furthermore, the Mn3p XPS spectra taken on the surface of the filter films revealed that the average manganese valence of the inactive manganese oxide film collected from Filter-S (FS-MnOx) was higher than in the film collected from Filter-N (FN-MnOx). Mn(IV) was identified as the predominant oxidation state in FS-MnOx and Mn(III) was identified as the predominant oxidation state in FN-MnOx. The results of compositional analyses suggested that polyaluminum ferric chloride (PAFC) used during the surface water treatment was an important factor in the mineralogy and reactivity of MnOx. This study provides the theoretical basis for promoting the wide application of the technology and has great practical significance. 相似文献
67.
介绍了地下水环境监测的现状,特点和设计地下水环境监测系统的目的,详细阐述了地下水环境监测系统的站位布设,采样频率和时间分配,监测项目,以及地下水采样井的布设。 相似文献
68.
垃圾填埋场地下水污染对居民健康的风险评价 总被引:8,自引:2,他引:6
调查了某垃圾填埋场地下水和周边居民饮用水中的As、Hg等重金属和挥发酚等有机物的污染状况,运用美国环保局的健康风险计算模型,评估了该垃圾填埋场地下水对周边居民的潜在健康风险。结果表明,各类人群对4种有阈化合物的饮食和皮肤暴露的终身健康危险度在8.2×10^-11~1.3×10^-10之间,均低于可以接受的风险水平10^-6;对As的终身超额健康危险度在3.1×10^-7~4.9×10^-7之间,表明地下水中砷污染对居民潜在的致癌风险不明显。各类人群通过皮肤对Hg、As、Cd和挥发酚的暴露剂量比通过饮水暴露的剂量高0.7倍~14.5倍,皮肤暴露将是地下水影响人体健康并构成潜在风险的重要途径。 相似文献
69.
The environmental safety of an underground mine depends strongly on its ventilation system. An efficient ventilation system provides fresh air, removes hazardous gases and dust, and maintains the temperature and humidity at appropriate levels. One of the most important factors in removing hazardous gases and dust is the dispersion behaviour in the mine network. This factor determines the longitudinal spreading and the average air residence time of gases or particulate matter throughout the mine. This paper describes tracer gas measurement in an underground mine and the utilisation and analysis of the dispersion characteristics using numerical simulations. The concentration–time curve obtained from the measurement is simulated to evaluate the effective diffusion coefficient that reflects the general dispersion characteristic of an entire mine. The evaluated values of effective diffusion coefficient are then compared to other data from several studies. The diffusivities obtained in this study were higher than other analytical and empirical results. More research is still required to identify the main factors causing such higher diffusivities. However, the results from the present work can be an important standpoint for future work. Numerical simulation conducted in this research was confirmed to be effective in detecting several leakage paths occurring in the mine ventilation network. 相似文献
70.
对127~193采区域产生剧烈地压活动的原因进行了综合分析,并找到了它的一般规律,提出了控制措施。 相似文献