高效液相色谱在水环境监测中的应用分析

现阶段,随着我国城市化建设的不断推进,一些大型工程的施工以及工业的发展,都成为了对于水资源造成污染和破坏的主要因素,因此对于水资源的保护迫在眉睫。为了能够进一步保护水资源,通过高效液相色谱来开展水环境监测工作,能够更加全面和高效地监测水资源的污染情况,进而为之后的水环境治理工作提供有力支持。本文主要阐述了高效液相色谱的系统构成,并分析了该技术在水环境监测工作中的具体应用。     

工业园区水污染源精细化管控系统的应用

针对工业园区污水排放监管问题,以北京某园区为例,提出了水污染源精细化管控方案。按照多级防控的思路,在企业级、管网级、园区级建成在线监测系统和精细化管控平台,实现园区水环境监管的全覆盖,有效监控企业排污动态,实时掌握园区污水排放状况,为企业、园区管理部门和环保管理部门提供决策支持。     

聚氨酯泡塑预富集-石墨炉原子吸收法测定水中铊

水样经硝酸和过氧化氢消解,Tl~+被氧化为Tl~(3+),在王水和Fe~(3+)介质中,TlCl~-_4被聚氨酯泡塑吸附富集,沸水脱附后用石墨炉原子吸收光谱法测定。用硝酸钯-抗坏血酸基体改进剂提高测定灵敏度,方法在0μg/L～25.0μg/L范围内线性良好,方法检出限为0.01μg/L。实际样品加标后6次测定结果的RSD为3.0%～11.0%,平均加标回收率为95.0%～99.8%。有证标准物质的测定结果在标准值范围内,相对误差为-4.8%。     

Water security: Old concepts,new package,what value?

“Water security” has come to infiltrate prominent discourse in the international water and development community, and achieving it is often viewed as a new water sector target. Despite the elevated status that the concept has increasingly acquired, understandings of the term are murky and quantification is rare. To promote a more tangible understanding of the concept, this paper develops an index for evaluating water security at a country level. The index is comprised of indicators in five components considered to be critical to the concept: (i) basic needs; (ii) agricultural production; (iii) the environment; (iv) risk management; and (v) independence. Achieving water security in these components can be considered necessary but insufficient criteria to measure the achievement of security in related areas such as health, livelihoods, and industry. After populating indicators with data from Asia‐Pacific countries, results are interpreted and the viability of methods is discussed. This effort comprises an important first step for quantifying and assessing water security across countries, which should spur more concrete understanding of the term and discussion of its added value.     

Contrasting cesium dynamics in neighboring deep and shallow warm-water reservoirs

To measure the long term retention and seasonal dynamics of an initial 4 kg addition of ¹³³Cs into an 11.4-ha, 157,000 m³ reservoir (Pond 4, near Aiken, South Carolina, USA), the concentrations and inventories of ¹³³Cs in the water column were measured at periodical intervals for 522 days following the 1 August, 1999 release. After rapid declines in concentrations and inventories during the first 90 days, the ¹³³Cs concentrations in the water column declined at an average proportional rate of 0.004 d⁻¹. However, there were periods of less rapid and more rapid rates of declines, and these were correlated with periods of increasing and decreasing K concentrations in the water column. The decline rates were less and the K concentrations greater in the winter than in the summer. In the deeper, neighboring monomictic reservoirs of Par Pond and Pond B, a yearly cycle of increasing and decreasing ¹³⁷Cs concentrations in the water column is driven by anoxic remobilization of Cs from the sediments into a persistent summer hypolimnion. In Pond 4, whose mean depth of 1.6 m is too shallow to support a persistent anoxic hypolimnion, the pattern of yearly dynamics for K and Cs appear to be related to the accumulation and release of these elements from the extensive, seasonal macrophyte communities. The contrasting results between Pond 4 and Pond B suggest that a full appreciation of the relative importance of 1) anoxic remobilization and 2) accumulation and release by macrophytes in these systems remains to be established.     

Moving Beyond Strawmen and Artificial Dichotomies: Adaptive Management When an Endangered Species Uses an Invasive One

Evans et al. (Journal of Agricultural and Environmental Ethics, 2008) have attempted to enmesh me in their dispute with the Florida Bureau of Invasive Plant Management about a specific system, Kings Bay/Crystal River. In so doing, they repeatedly mischaracterize my positions in order to depict, incorrectly, invasion biology as monolithic and me as a representative of one extreme of a false dichotomy about management of introduced species. In addition, they introduce an issue irrelevant in this case (extinctions) and cite incorrect data. Proposing to manage people, manatees, introduced plants, and cyanobacteria in Kings Bay by participative adaptive management, they ignore the fact that living organisms can both disperse autonomously and hitchhike. Finally, they present few details on any aspect of their management proposal and do not address the myriad problems that have beset previous attempts at scientific adaptive management, especially at large scales. Until such a management approach is fleshed out and implemented, it is impossible to assess its validity for Kings Bay, and it is very premature to suggest it as a general model for dealing with invasive species disputes.     

Impact of Watershed Subdivision and Soil Data Resolution on SWAT Model Calibration and Parameter Uncertainty1

Abstract: Impact of watershed subdivision and soil data resolution on Soil Water Assessment Tool (SWAT) model calibration and parameter uncertainty is investigated by creating 24 different watershed model configurations for two study areas in northern Indiana. SWAT autocalibration tool is used to calibrate 14 parameters for simulating seven years of daily streamflow records. Calibrated parameter sets are found to be different for all 24 watershed configurations, however in terms of calibrated model output, their effect is minimal. In some cases, autocalibration is followed by manual calibration to correct for low flows, which were underestimated during autocalibration. In addition to normal validation using four years of streamflow data for each calibrated parameter set, cross‐validation (using a calibrated parameter set from one model configuration to validate observations using another configuration) is performed to investigate the effect of different model configurations on streamflow prediction. Results show that streamflow output during cross‐validation is not affected, thus highlighting the non‐unique nature of calibrated parameters in hydrologic modeling. Finally, parameter uncertainty is investigated by extracting good parameter sets during the autocalibration process. Parameter uncertainty analysis suggests that significant parameters show very narrow range of uncertainty across different watershed configurations compared with nonsignificant parameters. Results from recalibration of some configurations using only six significant parameters were comparable to that from calibration using 14 parameters, suggesting that including fewer significant parameters could reduce the uncertainty arising from model parameters, and also expedite the calibration process.     

Beneath the Straw: In Defense of Participatory Adaptive Management

Our recent paper advocating adaptive management of invasive nonnative species (INS) in Kings Bay, Florida received detailed responses from both Daniel Simberloff, a prominent invasion biologist, and Mark Sagoff, a prominent critic of invasion biology. Simberloff offers several significant lines of criticism that compel detailed rebuttals, and, as such, most of this reply is dedicated to this purpose. Ultimately, we find it quite significant that Simberloff, despite his other stated objections to our paper, apparently agrees with our argument that proposals for alternative management of established INS (i.e., alternatives to minimization/eradication) should not be rejected on an a␣priori basis. We argue that more specific development and application of adaptive approaches toward INS management, whether in Kings Bay or other appropriate case studies, would be facilitated if ecosystem managers and invasion biologists follow Simberloff’s lead on this key point. While Sagoff largely shares (and, indeed, served as a primary source for developing) our general arguments that challenge common moral and scientific assumptions associated with invasion biology, he does question our suggestion that participatory adaptive management provides an appropriate framework for approaching environmental problems in which science and politics are inherently entangled. We attempt to answer this criticism through a brief sketch of what participatory adaptive management might look like for Kings Bay and how such an approach would differ from past management approaches.     

Fate and transport of fragrance materials in principal environmental sinks

Fragrance materials are widely present in the environment, such as air, water, and soil. Concerns have been raised due to the increasing utilization and suspected impact on human health. The bioaccumulating property is considered as one of the causes of the toxicity to human beings. The removal of fragrance materials from environmental sinks has not been paid enough attention due to the lack of regulation and research on their toxicity. This paper provides systematic information on how fragrance materials are transferred to the environment, how do they affect human lives, and what is their fate in water, wastewater, wastewater sludge, and soil.     

Effects of estrone on the early life stages and expression of vitellogenin and estrogen receptor genes of Japanese medaka (Oryzias latipes)

The fertilized eggs of Japanese medaka (Oryzias latipes) were exposed to estrone (E1) at 5–5000 ng L⁻¹ for 15 d, and the hatched fry were exposed continuously to the same concentrations for the additional 15 d. Adverse effects on hatchability, time to hatching, and gross abnormalities occurred at 50 ng L⁻¹ or above. Then the fry were divided into a continual exposure group, and a water recovery group. When the fry were exposed to E1 for another 60 d, there was a decrease in the hepatosomatic index (HSI) of males and the influence disappeared in the water recovery group. The gonadosonatic index (GSI) of females at 500 ng L⁻¹ decreased significantly in another 60 d exposure. While the fry were maintained in dechlorinated tap water for 60 d, a significant decrease in female GSI was observed at 50 ng L⁻¹ or above. An increased GSI was found in males in both continual exposure and water recovery groups at all E1 treatments. Quantitative RT-PCR showed that vitellogenin-I (Vtg-I) gene expressions in the female liver were significantly down-regulated at 50 ng L⁻¹ in the continual exposure group, and at 500 ng L⁻¹ in the water recovery group, while male Vtg-I genes were significantly up-regulated for all E1 treatments. In addition, all E1 treatments caused sex reversal of males. These results suggest that E1 at 5 ng L⁻¹ or above have unrecoverable impacts on the gonadal growth and development of medaka, even if only early life stages were exposed to E1.