影响顶空-气相色谱法测定水中吡啶准确度的关键因素探讨

通过试验,讨论盐析效应、顶空的平衡温度和平衡时间、水样的p H值、色谱条件等对顶空-气相色谱法测定环境水体中吡啶准确度的影响。优化上述条件后,方法在0 mg/L~3.95 mg/L范围内线性良好,检出限可达0.016 mg/L,测定下限为0.064 mg/L。用该方法对地表水和生活污水做3个质量浓度水平的加标回收试验,测定6次结果的RSD为1.7%~5.7%,回收率为93.9%~113%。     

气相色谱/质谱法测定水中15种酞酸酯类化合物

采用固相萃取-气相色谱/质谱法测定水中15种酞酸酯类化合物,确定方法的最优条件为:依次用10 m L正己烷和丙酮混合溶剂(V/V=5∶1)、甲醇和空白试剂水活化C18固相萃取柱后,水样以5 m L/min过柱萃取,再以8 m L正己烷:丙酮(V/V=5∶1)混合溶剂洗脱后,浓缩至1 m L,进气相色谱/质谱测定。该法的检出限为0.18~0.38μg/L,在0.50~20.0 mg/L范围内线性良好,相关系数均0.996。空白水样的加标回收率为71.8%~120%,相对标准偏差为1.73%~12.7%;实际废水水样的加标回收率为64.8%~135%,相对标准偏差为2.75%~18.0%。     

太湖流域水生态监控系统平台构建研究

从太湖流域水生态监控管理需求出发,研究太湖流域水生态监控系统平台建设目标及建设内容,包括水生态监控数据管理子系统构建、水生态状况评价子系统构建、水生态模拟子系统构建和水生态辅助管理决策子系统构建。集成管理太湖流域水质监测数据、水生生物监测数据、基础地理信息数据,对各类数据进行一体化管理及深度挖掘,自动实现水生态状况评价;构建水生态模拟子系统,对水生态情景、污染物扩散、水生态功能区空间分布及变化趋势进行模拟,并提出水生态辅助决策方案及报告。     

基于STIRPAT模型的天津市水环境污染影响因素分析

基于拓展的STIRPAT模型,利用岭回归分析方法,以天津市2006—2016年COD值及其相关社会、经济、人口数据为例,分析人口、城市化水平、经济发展、技术水平、产业结构、用水结构对水环境污染的影响。研究表明:工业GDP占比的提高是导致水环境污染的最主要原因,人口、城市化率、人均GDP、排放强度和生活用水占总用水比例的提升都是引起水环境污染加重的因素,通过技术创新可以控制水污染。     

南水北调中线工程水源区蒸散发计算方法比较及影响因素分析

以南水北调中线工程水源区为研究区域,采用1961~2007年9个气象站点气象观测数据和黄家港水文站实测径流资料,以FAO彭曼蒙特斯公式和水文模拟法为标准分别对多种潜在蒸散发计算方法和实际蒸散发计算方法进行比较研究,并分析了陆面蒸散发的影响因素。研究表明：南水北调中线工程水源区存在“蒸发悖论”现象,Priestley Taylor公式计算结果偏大,但与FAO 彭曼蒙特斯公式存在良好的相关关系,在气象资料较少时可以考虑建立相关方程进行推求。傅抱璞公式与水文模拟法计算结果较为接近,相关关系最优。潜在蒸散发与平均温度、气温日较差、实际水汽压、降雨量、风速、净太阳辐射、日照时数呈正相关,而实际蒸散发与平均温度、气温日较差、实际水汽压、降雨量、净太阳辐射、日照时数呈正相关,与风速呈负相关。净太阳辐射是影响陆面蒸散发的核心因素     

Reverse phase high performance liquid chromatographic determination of Baygon in water

Abstract

A simple analytical procedure for determination of Baygon in water is described. The Baygon residues are extracted on a C₁₈ SEP‐PAK cartridge and subsequently analyzed by reverse phase high performance liquid chromatography using ultraviolet detection at 272 nm. Water samples spiked with Baygon are found to give greater than 90 percent recoveries.

Concentration levels as low as 20 ppb can be easily detected by this method.     

Model Development for Nutrient Loading Estimates from Paddy Rice Fields in Korea

Abstract

A field experiment was performed to evaluate water and nutrient balances in paddy rice culture operations during 2001–2002. The water balance analysis indicated that about half (50–60%) of the total outflow was lost by surface drainage, with the remainder occurring by evapotranspiration (490–530 mm). The surface drainage from paddy fields was mainly caused by rainfall and forced-drainage, and in particular, the runoff during early rice culture periods depends more on the forced-drainage due to fertilization practices. Most of the total phosphorus (T-P) inflow was supplied by fertilization at transplanting, while the total nitrogen (T-N) inflow was supplied by the three fertilizations, precipitation, and from the upper paddy field, which comprised 13–33% of the total inflow. Although most of the nutrient outflow was attributed to plant uptake, nutrient loss by surface drainage was substantial, comprising 20% for T-N and 10% for T-P. Water and nutrient balances indicate that reduction of surface drainage from paddy rice fields is imperative for nonpoint source pollution control. The simplified computer model, PADDIMOD, was developed to simulate water and nutrient (T-N and T-P) behavior in the paddy rice field. The model predicts daily ponded water depth, surface drainage, and nutrient concentrations. It was formulated with a few equations and simplified assumptions, but its application and a model fitness test indicated that the simulation results reasonably matched the observed data. It is a simple and convenient planning model that could be used to evaluate BMPs of paddy rice fields alone or in combination with other complex watershed models. Application of the PADDIMOD to other paddy rice fields with different agricultural environments might require further calibration and validation.     

A History of Dry Cleaners and Sources of Solvent Releases from Dry Cleaning Equipment

Approximately 25, 000-35, 000 dry cleaning facilities currently operate in the U.S. The release of perchloroethylene and other solvents from these establishments represents a major source of soil and groundwater contamination. The manner in which dry cleaning solvents escape from dry cleaning plants is, for all practical purposes, identical for chlorinated and petroleum hydrocarbon solvents and is related to one of the following events: the catastrophic failure of a component of the dry cleaning system, the improper installation, operation or maintenance of the dry cleaning equipment or a combination of all of these causes. Acceptable customs, codes and regulations can also dictate what is authorized for operation of a dry cleaning facility in a particular community, geographic area during a particular time frame. Environmental litigation dealing with the origin of a solvent release from dry cleaners tends to focus on the design and manufacture of dry cleaning industry machines such as washers, washer extractors, tumblers, solvent filters, water separators, stills and spotting boards. A thorough analysis of the daily operations of dry cleaners often reveals that poor maintenance, failure to follow the manufacturer's instructions and the actions of the operator are the most likely causes of soil and groundwater pollution. In order to forensically evaluate the most probable origins of a solvent release and to examine issues regarding liability, a thorough understanding of the history of dry cleaning and a detailed analysis of the operation and maintenance of the dry cleaning equipment are necessary. The discovery of solvent plumes in the vicinity of dry cleaning plants may suggest that the solvent source is the dry cleaning plant; however, the presence of these plumes does not necessarily indicate that the dry cleaning equipment was defectively designed or manufactured. A thorough review of the type of equipment used over the life of the dry cleaning plant and verifiable solvent mileage records frequently indicates that operators of the plant have disposed of solvent and contaminated solids into the municipal sewer or on ground surfaces.     

What’s the Problem? River Management,Education, and Public Beliefs

This paper invokes the theory of planned behavior (TPB) as a diagnostic tool to explain an existing public education program's limited success at improving river water quality in the City of Perth, Western Australia. A reflective, client-driven research approach was used. A facilitated expert workshop defined an environmental problem (excess nutrients leaving gardens and entering waterways) and a desired behavior (residents purchasing environmentally sensitive fertilizer) to address the problem. A TPB-based belief elicitation survey captured respondents' beliefs regarding the desired behavior. The findings suggest respondents were aware of the links between purchasing environmentally sensitive fertilizer and river water quality. However, this behavior is compromised by the challenges in identifying appropriate products, product quality concerns, and cost. Viewing the content of a public education program through the lens of the TPB reveals insights into how and why the program fell short in achieving one of its key behavioral change goals.     

Phyt'Eaux Cités: application and validation of a programme to reduce surface water contamination with urban pesticides

This paper presents first results of Phyt’Eaux Cités, a program put in place by the local water supply agency, the SEDIF (Syndicat des Eaux d’Ile-de-France), in collaboration with 73 local authorities, private societies and institutional offices (365 km²). The challenges included: measurement of the previous surface water contamination, control of urban pesticide applications, prevention of pesticide hazard on users and finally a overall reduction of surface water contamination. An inquiry on urban total pesticide amount was coupled with a surface water bi-weekly monitoring to establish the impact of more than 200 molecules upon the Orge River. For 2007, at least 4400 kg and 92 type of pesticides (essentially herbicides) were quantified for all urban users in the Phyt’Eaux Cités perimeter. At the outlet of the Orge River (bi-weekly sampling in 2007), 11 molecules were always detected above 0.1 μg L⁻¹. They displayed the mainly urban origin of pesticide surface water contamination. Amitrole, AMPA (Aminomethyl Phosphonic Acid), demethyldiuron, diuron, glyphosate and atrazine were quantified with a 100% of frequency in 2007 and 2008 at the Orge River outlet. During the year, peaks of contamination were also registered for MCCP, 2,4 MCPA, 2,4 D, triclopyr, dichlorprop, diflufènican, active substances used in large amount in the urban area. However, some other urban molecules, such as isoxaben or flazasulfuron, were detected with low frequency. During late spring and summer, contamination patterns and load were dominated by glyphosate, amitrole and diuron, essentially applied by cities and urban users. Both isoproturon and chlortoluron were quantified during autumn and winter months according to upstream agricultural practices. In conclusion, 3 years after the beginning of this programme, the cities reduced the use of 68% of the total pesticide amount. An improvement on surface water quality was found from 2008 and during 2009 for all pesticides. In particular, glyphosate showed a decrease of the load above 60% in 2008, partly related to the Phyt’Eaux Cités action.