Introductory remarks on mercury pollution in China

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PREDICTING CHANGE IN NON-LINEAR SYSTEMS

Complex systems are characterizedby surprising switches to new behaviours. Evaluating and predicting these changes demands anunderstanding of the behaviour of the whole system. The combined ecosystem-climate system shows chaoticor pseudorandom behaviour, stochastic or trulyrandom behaviour, as well as simple bifurcation andsemi-stability. Semistability involves the suddenchange from a destabilized attractor to a newstable attractor which may occur after an apparentlyunpredictable time delay. We present some recentresults for analyzing time series data and for usingsimulations of non-linear models to predict these changes.     

New approach for habitat characterization based on species lists of aquatic and semiaquatic bugs

A new approach is proposed for the environmental impact assessment of fresh waters. New indices and the cenological values of aquatic and semiaquatic bug (Hemiptera) species have been obtained through multivariate analysis based on the species list of 157 localities in Hungary. The 45 species involved in this study can be characterized by their preference for habitat types on a linear scale ranging from small, shallow waters to large, deep waters. The habitats themselves can be characterized by the added cenological values of the species found.     

A new market instrument for sustainable economic and environmental development

The regenerative capacity of ecosystems provides a regulatory basis for sustainable economic growth and development. A natural valuation of an ecosystem's services will arise in a market for developmental rights in the ecosystem using a unit of tradable 'right': E-Scrip. The amount of e-scrip needed for a development may be set by Environmental Assessment. The capacity of the ecosystem to regenerate with developmental pressure may be represented by an independent trader or Factor Proxy for the Environment who provides e-scrip to the market.     

Preliminary investigation of submerged aquatic vegetation mapping using hyperspectral remote sensing

The use of airborne hyperspectral remote sensing imagery for automated mapping of submerged aquatic vegetation (SAV) in the tidal Potomac River was investigated for near to real-time resource assessment and monitoring. Airborne hyperspectral imagery and field spectrometer measurements were obtained in October of 2000. A spectral library database containing selected ground-based and airborne sensor spectra was developed for use in image processing. The spectral library is used to automate the processing of hyperspectral imagery for potential real-time material identification and mapping. Field based spectra were compared to the airborne imagery using the database to identify and map two species of SAV (Myriophyllum spicatum and Vallisneria americana). Overall accuracy of the vegetation maps derived from hyperspectral imagery was determined by comparison to a product that combined aerial photography and field based sampling at the end of the SAV growing season. The algorithms and databases developed in this study will be useful with the current and forthcoming space-based hyperspectral remote sensing systems.     

Of Small Streams and Great Lakes: Integrating Tributaries to Understand the Ecology and Biogeochemistry of Lake Superior

Lake Superior receives inputs from approximately 2,800 tributaries that provide nutrients and dissolved organic matter (DOM) to the nearshore zone of this oligotrophic lake. Here, we review the magnitude and timing of tributary export and plume formation in Lake Superior, how these patterns and interactions may shift with global change, and how emerging technologies can be used to better characterize tributary–lake linkages. Peak tributary export occurs during snowmelt‐driven spring freshets, with additional pulses during rain‐driven storms. Instream processing and transformation of nitrogen, phosphorus, and dissolved organic carbon (DOC) can be rapid but varies seasonally in magnitude. Tributary plumes with elevated DOC concentration, higher turbidity, and distinct DOM character can be detected in the nearshore during times of high runoff, but plumes can be quickly transported and diluted by in‐lake currents and mixing. Understanding the variability in size and load of these tributary plumes, how they are transported within the lake, and how long they persist may be best addressed with environmental sensors and remote sensing using autonomous and unmanned vehicles. The connections between Lake Superior and its tributaries are vulnerable to climate change, and understanding and predicting future changes to these valuable freshwater resources will require a nuanced and detailed consideration of tributary inputs and interactions in time and space.     

Expanding marine protected areas to include degraded coral reefs

Marine protected areas (MPAs) are a commonly applied solution to coral reef degradation, yet coral reefs continue to decline worldwide. We argue that expanding the range of MPAs to include degraded reefs (DR‐MPA) could help reverse this trend. This approach requires new ecological criteria for MPA design, siting, and management. Rather than focusing solely on preserving healthy reefs, our approach focuses on the potential for biodiversity recovery and renewal of ecosystem services. The new criteria would help identify sites with the highest potential for recovery and the greatest resistance to future threats (e.g., increased temperature and acidification) and sites that contribute to MPA connectivity. The DR‐MPA approach is a compliment rather than a substitute for traditional MPA design approaches. We believe that the DR‐MPA approach can enhance the natural, or restoration‐assisted, recovery of DRs and their ecosystem services; increase total reef area available for protection; promote more resilient and better‐connected MPA networks; and improve conditions for human communities dependent on MPA ecosystem services.     

Limitations of Gravity Models in Predicting the Spread of Eurasian Watermilfoil

Abstract: The effects of non‐native invasive species are costly and environmentally damaging, and resources to slow their spread and reduce their effects are scarce. Models that accurately predict where new invasions will occur could guide the efficient allocation of resources to slow colonization. We assessed the accuracy of a model that predicts the probability of colonization of lakes in Wisconsin by Eurasian watermilfoil (Myriophyllum spicatum). We based this predictive model on 9 years (1990–1999) of sequence data of milfoil colonization of lakes larger than 25 ha (n =1803). We used milfoil colonization sequence data from 2000 to 2006 to test whether the model accurately predicted the number of lakes that actually were colonized from among the 200 lakes identified as being most likely to be colonized. We found that a lake's predicted probability of colonization was not correlated with whether a lake actually was colonized. Given the low predictability of colonization of specific lakes, we compared the efficacy of preventing milfoil from leaving occupied sites, which does not require predicting colonization probability, with protecting vacant sites from being colonized, which does require predicting colonization probability. Preventing organisms from leaving colonized sites reduced the likelihood of spread more than protecting vacant sites. Although we focused on the spread of a single species in a particular region, our results show the shortcomings of gravity models in predicting the spread of numerous non‐native species to a variety of locations via a wide range of vectors.     

Enantioselectivity in toxicity and degradation of dichlorprop-methyl in algal cultures

Enantioselectivity in the toxicity and degradation of the herbicide dichlorprop-methyl (2,4-DCPPM) in algal cultures was studied. Enantioselectivity was clearly observed in the toxicity of racemic 2,4-DCPPM and its two enantiomers. R-2,4-DCPPM showed low toxicity to Chlorella pyrenoidosa and Chlorella vulgaris, but higher toxicity to Scenedesmus obliquus. The observed toxicity was ranked: R-2,4-DCPPM > S-2,4-DCPPM ? Rac-2,4-DCPPM; the toxicity of R-2,4-DCPPM was about 8-fold higher than that of Rac-2,4-DCPPM. Additionally, 2,4-DCPPM was quickly degraded, in the initial 12 h, and different algae cultures had different enantioselectivity for the 2,4-DCPPM enantiomers. There was no significant enantioselectivity for 2,4-DCPPM in Chlorella vulgaris in the initial 7 h. However, racemic 2,4-DCPPM was degraded by Scenedesmus obliquus quickly, in the initial 4 h, much quicker, in fact, than the S- or R-enantiomers (racemate > R- > S-), indicating that the herbicide 2,4-DCPPM was absorbed enantioselectively by Scenedesmus obliquus. The rapid formation of 2,4-DCPP suggested that 2,4-DCPPM adsorbed by algal cells was catalytically hydrolyzed to the free acid, a toxic metabolite. The production rates of 2,4-DCPP were as follows: Scenedesmus obliquus > Chlorella pyrenoidosa > Chlorella vulgaris, consistent with the degradability of 2,4-DCPPM. Scenedesmus obliquus had quick, but different, degradative and uptake abilities for R-, S-, and Rac-2,4-DCPPM. The R- and S- enantiomers were not hydrolyzed in the first 12 h, while both enantiomers were hydrolyzed slowly after that. These results indicate that some physical and chemical properties of compounds are of importance in determining their enantioselective toxicity and degradation. The ester and its metabolite likely played an important role in enantioselective toxicity to the three algae.     

我国水生生态系统优先控制有机污染物的研究现状

介绍了我国对水生生态系统各相中各类环境优先控制有机污染物的分布、迁移转化规律及其归宿等方面的研究成果,着重论述了多环芳烃、多氯联苯和有机氯农药等在沉积物中的分布特征及污染来源判别的研究状况,同时指出了我国目前对于环境优先控制有机污染物研究的薄弱环节和今后努力的方向.