土壤监测质量保证与质量控制

土壤监测质量保证和质量控制是确保获取具有代表性、准确性、精密性、可比性和完整性的监测数据的重要措施,是土壤环境监测体系的核心内容之一。土壤监测质量保证和质量控制涉及采样点布设质量保证、样品采集质量保证、样品制备质量保证、实验室内部和外部质量控制。     

高分子重金属絮凝剂MAC除Cu2+、去浊性能

以壳聚糖、巯基乙酸等为原料合成了一种新型高分子重金属絮凝剂巯基乙酰壳聚糖(MAC),研究了其除Cu2 与去浊的机理,并对几个因素做了考察.实验结果表明:①MAC具有除铜与去浊的性能,当MAC与HPAM复配时,效果优于单独使用MAC,Cu2 去除率可达98%以上;②用MAC处理Cu2 和浊度共存的体系时,废水中的重金属离子和致浊物质可以起到相互促进去除的作用,出水中[Cu2 ]＜0.5mg·L-1,浊度＜3NTU;原水浊度越大,越有利于Cu2 的去除;③Cu2 的去除率随原水pH值的增大而提高,浊度的去除率则反之.     

QA/QC措施在中哈有机氯农药联合监测工作中的应用

为了说清伊犁河出、入境断面六六六、DDT等4种有机氯农药的检出问题,中国与哈萨克斯坦双方分别在中方的三道河子断面和哈方的杜本断面进行了联合研究性监测。中方采取现场采集平行样并加带全程序空白样品,实验室采用溶剂空白、实验室空白、全程序空白、平行双样以及加标回收分析等质控措施,使哈方专家认可中方监测数据的准确性和有效性,保证了双方的监测结果被中哈环保合作委员会接受和采用。研究以中哈跨界河流实际监测的典型实例,论证了质量保证与质量控制措施（QA/QC）在跨国界河流联合监测工作中的重要作用。     

A new procedure combining GC-MS with accelerated solvent extraction for the analysis of phthalic acid esters in contaminated soils

An optimized procedure based on gas chromatography-mass spectrometry (GC-MS) combined with accelerated solvent extraction (ASE) is developed for the analysis of six phthalic acid esters (PAEs), which are priority soil pollutants nominated by United States Environmental Protection Agency (USEPA). Quantification of PAEs in soil employs ultrasonic extraction (UE) (USEPA 3550) and ASE (USEPA 3545), followed by clean up procedures involving three different chromatography columns and two combined elution methods. GC-MS conditions under selected ion monitoring (SIM) mode are described and quality assurance and quality control (QA/QC) criteria with high accuracy and sensitivity for target analytes were achieved. Method reliability is assured with the use of an isotopically labeled PAE, di-n-butyl phthalate-d4 (DnBP-D4), as a surrogate, and benzyl benzoate (BB) as an internal standard, and with the analysis of certified reference materials (CRM). QA/QC for the developed procedure was tested in four PAE-spiked soils and one PAE-contaminated soil. The four spiked soils were originated from typical Chinese agricultural fields and the contaminated soil was obtained from an electronic waste dismantling area. Instrument detection limits (IDLs) for the six PAEs ranged 0.10–0.31 μg·L^-1 and method detection limits (MDLs) of the four spiked soils varied from a range of 20–70 μg·kg^-1 to a range of 90– 290 μg·kg^-1. Linearity of response between 20 μg·L^-1 and 2 mg·L^-1 was also established and the correlation coefficients (R) were all>0.998. Spiked soil matrix showed relative recovery rates between 75 and 120% for the six target compounds and about 93% for the surrogate substance. The developed procedure is anticipated to be highly applicable for field surveys of soil PAE pollution in China.     

新冠疫情下的保险业及保险连接证券市场

2019年底爆发的新型冠状病毒疫情已经给全世界造成了深远的影响,沉重打击了各国经济,人类生产、生活方式都发生重大变化.即使已经过去半年,目前的情况仍不明朗,每天仍有大量人员被确诊,全球经济前景充满不确定性.通过观察疫情对保险业的影响,认为在政策推动和需求增加的情况下,保险业未来的业务范围会向大流行病扩展.计算保险连接证...     

基于支持向量机(SVM)的民用飞机重着陆智能诊断研究

针对国内航空公司对于重着陆的判断方法存在的不足,提出采用支持向量机(SVM)建立重着陆的智能诊断模型;分析对重着陆产生影响的相关因素,在力学基础上揭示了重着陆的产生原理;利用快速存取记录器中记录的多个飞行参数的信息,采用B737机型的实际样本数据进行训练和验证。结果表明:该方法能有效判断出是否发生重着陆,其准确率高达92.86%,证明该重着陆智能诊断方法具有较强实际应用价值,为后续研究奠定了基础。     

Association patterns among wild chimpanzees (<Emphasis Type="Italic">Pan troglodytes schweinfurthii</Emphasis>) reflect sex differences in cooperation

Theory predicts that frequent dyadic association should promote cooperation through kin selection or social tolerance. Here we test the hypothesis that sex differences in the strength and stability of association preferences among free-ranging chimpanzees conform to sex differences in cooperative behavior. Using long-term data from the Kanyawara chimpanzee (Pan troglodytes schweinfurthii) community (Kibale National Park, Uganda), we calculated indices of intra-sexual dyadic association over a 10-year period. We found that (1) male–male dyads had significantly stronger association indices than female–female dyads, (2) the pattern of association preferences in both sexes changed little over the entire study period, and (3) when comparing periods with different alpha males, changes in association strength were more frequent among males. These results demonstrate that both the strength and stability of association patterns are important components of social relationships. Male chimpanzees, which are characterized by frequent cooperation, had association preferences that were both strong and stable, suggesting that forming long-term bonds is an important dominance strategy. However, the fact that male association patterns were sensitive to upheaval in the male dominance hierarchy suggests that males also take advantage of a changing social climate when choosing association partners. By contrast, the overall strength of female associations was relatively weak. Female association preferences were equally stable as males’; however, this reflected a dyad’s tendency to be found in the same party rather than to associate closely within that party. Therefore, in this community, female association patterns appear to be more a consequence of individual ranging behavior rather than a correlate of cooperation.     

Reliability data acquisition and evaluation in process plants

Based on the practical experience of assessing reliability data in two plants of the explosives industry, the organization and scope of the data collection, the component delimitation, the procedures of quality assurance and the data evaluation for their final use in PSA studies are presented. An example is given for the type of detection and repair, etc. The mathematical background for evaluating observed component lifetimes is discussed. Both frequentist and Bayesian methods are addressed. The resulting failure rate distributions and their approximations by log-normal distributions for several key components are presented. They were obtained using a Bayesian approach with a non-informative prior. Remarks on uncertainty, their treatment and a proposal for transferring data to plants other than the ones investigated conclude the presentation.     

山西省庞泉沟大气环境背景监测站建设经验探讨

建设国家级大气环境背景监测站是系统掌握区域性大气环境质量,是大气环境管理重要的基础性工作。本研究以山西省庞泉沟大气环境背景监测站建设为例,基于站点选址原则、选取方法说明的基础上,介绍了庞泉沟大气环境背景监测站点位确定的考量因素,以及该站点基建内容、监测项目和质量控制体系等建设、运行情况,并梳理了该站建设、运行过程中的仍存在问题及改进建议,期望对中国同类型大气环境背景监测站建设、运行提供借鉴与参考。     

空气自动监测网络数据审核自动化实现的创新与实践

阐述了在城市空气质量自动监测网络的质量保证管理中,使用计算机数据审核系统对监测数据进行自动审核的设计思想及其采取的创新手段;详细介绍了该系统在山东省的使用情况。