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571.
Bouo FX Kouamé JK Tchétché Y Kré RN Moussé ML Assamoi P Cautenet S Cautenet G 《Chemosphere》2011,84(11):1617-1629
The purpose of this paper is to study the redistribution of chemical species (OH, HO2, H2O2, HNO3 and H2SO4) over West Africa, where the cloud cover is ubiquitously present, and where deep convection often develops. In this area, because of these cloud systems, chemical species are redistributed by the ascending and descending flow, or leached if they are soluble. So, we carry out a mesoscale study using the Regional Atmospheric Modelling System (RAMS) coupled to a code of gas and aqueous chemistry (RAMS_Chemistry). It takes into account all processes under mesh. We examine several cases following the period (November and July), with inputs emissions (anthropogenic, biogenic and biomass burning). The radicals OH and HO2 are an indicator of possibilities for chemical activity. They characterize the oxidizing power of the atmosphere and are very strong oxidants. The acids HNO3 and H2SO4 are interesting in their transformation into nitrates and sulfates in precipitation. In November, when photochemistry is active during an event of biomass burning, concentrations of chemical species are higher than those of November in the absence of biomass burning. The concentrations of nitric acid double and sulfuric acid increases 70 times. In addition, the concentrations are even lower in July if there is a deep convection. Compared to measures of the African Monsoon Multidisciplinary Analysis (AMMA), the results and observations of radicals OH and HO2 are the same order of magnitude. Emissions from biomass burning increase the concentrations of acid and peroxide, and a deep convection cloud allows the solubility and the washing out of species, reducing their concentration. Rainfalls play a major role in solubility and washing out acids, peroxides and radicals in this region. 相似文献
572.
Sorption of pyrene on black carbons (BCs) obtained by heating sawdust at two temperatures (400 and 700 °C, denoted as 400BC and 700BC, respectively), as well as on modified BCs (via oxidation, oximation, and hydrolysis) was studied to investigate the role of BC structural characteristics in sorption of hydrophobic organic compounds. Pyrene was bound strongly by 700BC and 400BC, with organic carbon normalized distribution coefficients (Koc) of 105.04-105.86 and 104.65-105.16, respectively, at equilibrium pyrene concentrations of 10-100 μg L−1. Both chemical composition and pore distribution of the two BCs changed after modifications, which led to changes in their sorption characteristics for pyrene. After modifications, the linearity of pyrene sorption isotherm increased for 700BC but decreased for 400BC. For 700BC, both oxidation and oximation reduced pyrene sorption, with Koc decreasing by 69.1-73.7% and 18.7-33.9%, respectively, whereas hydrolysis did not exert a significant influence. For 400BC, oxidation and hydrolysis reduced Koc by 2.28-25.9% and 29.2-33.9%, respectively, while oximation increased Koc. In most cases, the change in sorption capacity could be explained by the changes in C content and type, polarity, surface area, and micropore volume of the BCs; however, the role of conformation (the accessibility to sorption sites) could not be ignored. 相似文献
573.
在给水曝气生物滤池内置粉末活性炭,对比分析其对各工艺单元水质净化效果的影响,确定给水曝气生物滤池内置粉末活性炭的作用与最佳投加量,研究表明,给水曝气生物滤池将活性炭截留在滤池内,大幅度提高了粉末活性炭利用率,部分未饱和粉末活性炭通过反冲洗排入后续常规处理系统,作为生物载体仍能够进一步发挥生物强化作用。当粉末活性炭的投加量为8 mg/L时,砂滤出水氨氮、CODMn、浊度和色度均值分别为:0.02 mg/L,1.82 mg/L0,.46 NTU和6度,去除率分别达到99.6%、71.2%、99.1%和80.6%,出水指标达到《生活饮用水卫生标准(》GB5749-2006)和《饮用净水水质标准(》CJ94-2005)规定的标准。与常规工艺相比,投加量降低了20%~60%。 相似文献
574.
575.
宁波市大气可吸入颗粒物PM1o和PM2.5的源解析研究 总被引:2,自引:0,他引:2
在宁波市布设4个代表性点位,于2010年春季、夏季和冬季进行大气PM10和PM2.s的采样,同时采集了多种颗粒物源样品,建立了PM10、PM2.5和源样品的化学成分谱.采用化学质量平衡模型(CMB)对宁波市PM10、PM2.5进行源解析.结果表明,城市扬尘、煤烟尘、机动车尾气尘是宁波市PM10、PM2.5的3大污染源,... 相似文献
576.
J.M. Santos I. Mavroidis N.C. Reis Jr. E.C. Pagel 《Atmospheric environment (Oxford, England : 1994)》2011,45(36):6534-6545
Tracer gas was released upwind of a two-compartment complex shaped building under unstable atmospheric conditions. The mean wind direction was normal to or at 45° to the long face of the building. The general patterns of concentration distribution on the building external walls and inside the building were analysed and the influence of natural and mechanical ventilation on indoor concentration distributions was discussed. Mean concentration levels, as well as the concentration fluctuation intensity, were higher on the windward walls of the building, although concentration levels varied along each wall. Concentration fluctuations measured inside the building were lower than those measured outside. Inside the two compartments of the building, the time series of concentrations had a similar general behaviour; however, gas concentrations took approximately 1.5 times longer to reach the mean maximum concentration value at the downwind compartment 02 while they also decreased more rapidly in the upwind compartment 01 after the source was turned off. The highest indoor concentration and concentration fluctuation values were observed at the detectors located close to the windward walls, especially when the building windows were open. Experiments with and without natural ventilation suggested that infiltration and exfiltration of contaminants is much faster when the building windows are open, resulting to higher indoor concentration levels. Furthermore, mechanical ventilation tends to homogenize concentrations and suppress concentration fluctuations, leading to lower maximum concentration values. 相似文献
577.
578.
活性炭纤维(ACF)有比普通活性炭吸附量大、吸附和脱附速度快等优点,因此应用于有机废气的回收和净化,具有良好的经济、环境和社会效益。文中介绍了ACF的微观结构、表面化学以及吸附性能,并综述了近年来ACF在有机废气回收和治理方面的国内概况。 相似文献
579.
放射源管理系统是一种基于环境地理信息系统平台的资源管理系统,是GIS技术与环境监测技术、环境管理技术、数据库技术等各种环境信息分析和处理技术的集成。系统为环保部门提供了一个功能强大的空间信息服务和管理工具,可以直观、方便地获取放射源的监控、管理等数据信息,为环境管理部门的决策提供依据。 相似文献
580.