糠醛废渣制备活性炭对糠醛废水的脱色研究

以水蒸气为活化剂,用热解糠醛废渣制备活性炭,着重研究了所制备的活性炭对糠醛废水的脱色性能. 结果表明:糠醛废渣制备的活性炭对糠醛废水脱色的最佳温度为50 ℃,并且在很短的时间内即可完成,该活性炭与糠醛废水混合搅拌15 min后,脱色率几乎不再变化. 由于采用糠醛废渣制备活性炭的成本较低,可以适当增加活性炭的投加量以提高糠醛废水的脱色率. 当活性炭投加量为10 g/L时,50 ℃条件下搅拌10 min,糠醛废水脱色率可达到86.65%. 经活性炭脱色后的糠醛废水无色、透明,以去离子水为参比溶液测定其吸光度,与自来水相当.      

科尔沁沙地和浑善达克沙地流动沙丘中土壤微生物学特征比较

通过对科尔沁沙地和浑善达克沙地流动沙丘中0～10 cm和>10～20 cm层土壤中微生物数量和生物量碳的比较表明:土壤微生物三大类群(细菌、放线菌和真菌)数量和微生物生物量碳均表现为浑善达克沙地 > 科尔沁沙地,其中两大沙地真菌数量差异显著,细菌和放线菌数量差异不显著,微生物生物量碳差异显著;两大沙地土壤微生物数量和生物量碳在不同土壤层次均表现为>10～20 cm 层高于 0～10 cm层,其中微生物三大类群数量差异均不显著,微生物生物量碳差异显著. 土壤性质的差异导致两大沙地流动沙丘中微生物数量和生物量碳略有不同. 细菌和真菌数量与土壤有机碳和土壤全氮呈显著正相关,与土壤水分含量和pH呈显著负相关,微生物生物量碳与土壤有机碳和土壤全氮呈显著正相关. 两大沙地土壤微生物与土壤养分的层化比率均小于1,科尔沁沙地中微生物数量、生物量碳和土壤养分的层化比率均大于浑善达克沙地,可以推断两大沙地的流动沙丘处于退化状态,而且浑善达克沙地退化速度更快.      

低碳城市发展路径思考

为应对全球气候变化,人类开始寻求低碳发展方式。城市作为人类经济、社会活动的集中地,是低碳发展理念的实践主体。阐述了低碳城市的概念,分析了低碳城市发展的技术路径,介绍了国际上低碳城市的实践途径,提出了我国低碳城市的发展路径和对策思考。     

依靠科技进步 发展低碳农业

在全球携手应对气候变暖、减少温室气体排放的背景下,发展低碳经济是解决气候变化与经济发展矛盾的有效途径。通过描述气候变化、固碳减排对粮食安全、土壤碳汇、森林固碳、资源循环利用等影响和促进作用,深入分析发展低碳经济与可持续发展的关系,探讨如何在农业领域内开发高效循环生产体系,从而实现农业生产过程的固碳减排目的。由此,提出发展低碳农业是实现低碳经济的目标之一,它是一个复合技术体系,涉及了绿色农业、循环农业、生态文明、可持续发展理念。必须通过科学技术的突破,改造、提升低碳农业技术,改变农业现有的＂高能耗、高污染＂的生产状况,实现低碳生产、生活方式的转变。最后提出发展现代的低碳农业产业经济的对策和思考。     

活性炭辅助微波热解污泥反应条件的试验研究

针对微波不能直接实现原污水污泥高温热解的问题,采用活性炭作为微波能吸收物质辅助污泥热解。对影响污泥热解效能的3个主要因素：污泥样品量、活性炭掺杂量和微波辐射功率,各做了3个水平的考察,得到了试验条件下的最优方案：污泥样品量30g、活性炭掺杂量6g、微波辐射功率1200W。结果表明：在最优试验方案下,污泥能在7min内升至920℃的高温,实现污泥快速、高效热解。通过分析3个因素对污泥热解效能的影响,进一步对最优试验方案下的固体产物吸收微波的性能及用其作为掺杂物辅助微波热解污水污泥的可行性进行了研究,结果表明：固体残渣吸收微波性能良好,可以代替活性炭作为更经济、高效的污泥微波热解辅助材料。     

稻草还田方式对双季稻田耕层土壤有机碳积累的影响

选择南方典型双季稻田,研究不同的稻草还田方式对土壤不同层次有机碳的积累、表土碳密度、C/N比值及水稻产量的影响。结果表明,不同的稻草还田和耕作处理对水稻产量无显著影响;不同稻草还田处理的土壤有机碳和C/N均随土层加深而减小;3个稻草还田处理0-5 cm土层土壤有机碳质量分数显著高于不还田对照,其中,以高桩免耕处理最高,比无草翻耕处理提高13.8%（P〈0.01）;5-10 cm土层表现为高桩翻耕处理显著高于其他处理,增加幅度为1.39-1.66 g kg-1;10-15 cm为翻耕处理（包括稻草不还田和还田）显著高于各免耕处理;稻草翻耕处理（0-15 cm）的耕层有机碳密度显著高于其他处理。因此,南方双季稻田采取稻草翻耕还田方式有利于增加土壤有机碳汇。     

Development of pretreatment protocol for DNA extraction from biofilm attached to biologic activated carbon (BAC) granules

The biologic activated carbon (BAC) process is widely used in drinking water treatments. A comprehensive molecular analysis of the microbial community structure provides very helpful data to improve the reactor performance. However, the bottleneck of deoxyribonucleic acid (DNA) extraction from BAC attached biofilm has to be solved since the conventional procedure was unsuccessful due to firm biomass attachment and adsorption capacity of the BAC granules. In this study, five pretreatments were compared, and adding skim milk followed by ultrasonic vibration was proven to be the optimal choice. This protocol was further tested using the vertical BAC samples from the full-scale biofilter of Pinghu Water Plant. The results showed the DNA yielded a range of 40 μg·g^-1 BAC (dry weight) to over 100 μg·g^-1 BAC (dry weight), which were consistent with the biomass distribution. All results suggested that the final protocol could produce qualified genomic DNA as a template from the BAC filter for downstream molecular biology researches.     

The in situ treatment of TCE and PFAS in groundwater within a silty sand aquifer

Chlorinated ethenes such as trichloroethene (TCE), cis‐1,2‐dichloroethene (cis‐1,2‐DCE), and vinyl chloride along with per‐ and polyfluoroalkyl substances (PFAS) have been identified as chemicals of concern in groundwater; with many of the compounds being confirmed as being carcinogens or suspected carcinogens. While there are a variety of demonstrated in‐situ technologies for the treatment of chlorinated ethenes, there are limited technologies available to treat PFAS in groundwater. At a former industrial site shallow groundwater was impacted with TCE, cis‐1,2‐DCE, and vinyl chloride at concentrations up to 985, 258, and 54 µg/L, respectively. The groundwater also contained maximum concentrations of the following PFAS: 12,800 ng/L of perfluoropentanoic acid, 3,240 ng/L of perfluorohexanoic acid, 795 ng/L of perfluorobutanoic acid, 950 ng/L of perfluorooctanoic acid, and 2,140 ng/L of perfluorooctanesulfonic acid. Using a combination of adsorption, biotic, and abiotic degradation in situ remedial approaches, the chemicals of concern were targeted for removal from the groundwater with adsorption being utilized for PFAS whereas adsorption, chemical reduction, and anaerobic biodegradation were used for the chlorinated ethenes. Sampling of the groundwater over a 24‐month period indicated that the detected PFAS were treated to either their detection, or below the analytical detection limit over the monitoring period. Postinjection results for TCE, cis‐1,2‐DCE, and vinyl chloride indicated that the concentrations of the three compounds decreased by an order of magnitude within 4 months of injection, with TCE decreasing to below the analytical detection limit over the 24‐month monitoring period. Cis‐1,2‐DCE, and vinyl chloride concentrations decreased by over 99% within 8 months of injections, remaining at or below these concentrations during the 24‐month monitoring period. Analyses of Dehalococcoides, ethene, and acetylene over time suggest that microbiological and reductive dechlorination were occurring in conjunction with adsorption to attenuate the chlorinated ethenes and PFAS within the aquifer. Analysis of soil cores collected pre‐ and post‐injection, indicated that the distribution of the colloidal activated carbon was influenced by small scale heterogeneities within the aquifer. However, all aquifer samples collected within the targeted injection zone contained total organic carbon at concentrations at least one order of magnitude greater than the preinjection total organic carbon concentrations.     

分子筛孔结构对CO_2吸附性能的影响

采用巨正则蒙特卡罗方法模拟了CO_2在FAU分子筛上的吸附情况,比较了不同CO_2逸度下,CO_2在分子筛模型上的吸附位、吸附量的变化,拟合了其吸附等温线。结果表明:在吸附饱和状态下,分子筛的孔结构越大,对CO_2的吸附量越大,对于比CO_2分子更小的微孔结构,吸附几乎不发生;在低逸度下,CO_2的吸附主要发生在小孔内,随着逸度的提高,CO_2的吸附量迅速上升;在高逸度下,吸附量的提高主要发生在大孔内;FAU分子筛吸附CO_2的过程符合Ⅰ型Langmuir吸附等温线,在高压下对CO_2的吸附能力远大于低压下的吸附能力。     

基于碳排放的秦皇岛市工业产业结构优化研究

根据联合国政府间气候变化专门委员会推荐的方法,计算了秦皇岛市工业行业2005-2010年的能源消费碳排放。秦皇岛市工业效益偏低,重工业比例偏大和以煤炭为主的能源结构是碳排总量和碳排放强度的主要驱动力。改造提升传统主导产业,做强装备制造业,加快工业园区建设,完善产业链,改善能源结构等是秦皇岛市工业产业结构优化的主要途径。