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671.
Zhao Rongfang Ye Shufeng Xie Yusheng Chen Yunfa 《Journal of Material Cycles and Waste Management》2007,9(1):7-14
A new way to implement the simultaneous reutilization of solid waste, the desulfurization of coke oven gas (COG), and even
the desulfurization of coke by the co-coking of coking coal (CC) and waste plastic (WP) blended with a sorbent is proposed;
the evolution of H2S and the removal efficiency of H2S from COG during the co-coking process were investigated in a lab-scale cylindrical reactor. The experimental results indicated
that for the coking of CC blended with ZnO, Fe2O3, or blast furnace dust (BFD) as a sorbent, the instantaneous concentration of H2S in COG was lower than 500 mg/m3 (which meets the technical specification requirement of the Chinese Cleaner Production Standard–Coking Industry, HJ/T 126-2003)
when the molar ratio between the key component of the sorbent and the volatile S in CC or the CC/WP blend, n
Zn+Fe/n
S, was about 1.2 for ZnO and Fe2O3, but not for BFD under the same conditions, suggesting that ZnO and Fe2O3 are promising sorbents, but that BFD must be treated chemical or thermally before being used as a sorbent because of the
size and complicated nature of the influence of its phase/chemical composition on its desulfurization ability. However, for
the co-coking of CC and WP blended with ZnO as a sorbent, n
Zn+Fe/n
S must increase to 1.4 and 1.7 for 100/2 and 100/5 blends of CC/WP, respectively, to ensure a satisfactory efficiency for H2S removal from COG.
Part of this paper was presented at the International Symposium on EcoTopia Science 2005 (ISET05), Aug 8–9, 2005, Chikusa-ku,
Nagoya, Japan 相似文献
672.
以环境经济学的经济外部性理论为依据,识别采煤过程中生态环境的外部不经济因素,应用环境价值评价法,对这些不经济因素进行量化和货币化,初步建立了省域煤炭开采环境污染和生态破坏经济损失核算体系.以2003年为基准年,核算了山西省煤炭开采环境污染和生态破坏的经济损失量.结果表明:2003年山西省煤炭开采环境污染与生态破坏造成的损失约为286.746 8×108元,折合每t煤损失63.79元.其中环境污染年损失61.979 4×108元,折合每t煤损失13.78元;生态破坏损失224.767 4×108元,折合每t煤损失50.00元.依据该核算结果,1978─2003年山西省累计采煤约65×108 t,所造成的环境损失约为4 100×108元. 相似文献
673.
674.
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676.
为解决辽宁某铁矿开采后地表沉陷问题,验证自研的复合激发尾砂胶结充填体充填效果,运用FLAC3D模拟软件对铁矿二步骤充填开采和地表沉陷进行数值模拟计算研究.研究结果表明:采用3种胶结充填体分别进行二步骤充填后,盐基、碱基、水泥基胶结充填体内部的应力平均值分别为0.92,0.79,0.93 MPa,最大位移值分别为38,2... 相似文献
677.
678.
采用基于燃料消耗的排放因子法,按照经济部门(电力、工业、生活消费及其他)、燃料类型(原煤、洗煤、焦炭、型煤)、燃烧方式(层燃炉、煤粉炉、流化床锅炉等)和除尘脱硫设施(机械式除尘器、湿式除尘器、电除尘器、袋式除尘器等)等将燃煤排放源进行分类,根据各省、市、自治区不同排放源类型的煤炭消耗量及平均锑含量,建立了2005年中国燃煤大气锑排放清单.结果表明,2005年中国燃煤导致的大气锑排放总量约为530.86t,排放量超过30t的省份依次为贵州(49.28t)、湖南(45.96t)、河北(37.36t)、山东(35.12t)、安徽(30.92t),表明中国燃煤大气锑排放主要集中在中东部地区.大部分排放来自工业和电力部门,分别占排放总量的47.2%和39.9%. 相似文献
679.
Demirak A 《Environmental monitoring and assessment》2007,129(1-3):189-196
In this study, the chemical composition of the rainwater in Yatağan, which is a region surrounding a coal power plant was
investigated from February to April 2002. Rainwater samples were obtained from Yatağan, located northwest of Muğla City in
Turkey. pH values and concentrations of major ions (Ca2+, Na+, K+, , , ) in the rainwater samples were analyzed. The pH varied from 5.1 to 7.9 with an average of 6.7 which was in alkaline range
considering 5.6 as the neutral pH of cloud water in equilibrium with atmospheric CO2. In the total of 30 rain events, only three events were observed with water in the acidic range (<5.6), which occurred after
continuous rains. The equivalent concentration of components followed the order: Ca2+ > > Na+ > > > K+ > H+. The anion and cation concentrations in the rainwater samples showed a high sulphate concentration (131 μEq/l), as well as
high sodium (40 μEq/l) and calcium (298 μEq/l) concentrations. These values indicate that one probable source of the high
sodium concentration is fly ash, after the coal burning process and the power plant can be effective on level concentrations in rainwater. In addition, the dust-rich local and surrounding limestone environment might have caused the
high concentration of Ca2+ in rainwater of the Yatağan Basin. Due to a large contribution of these cations to the sulphate neutralization action, the
rainwater of this region displays only a moderate acidity, which does not cause significant environmental impact. 相似文献
680.
中国煤电和核电的环境影响与健康风险比较 总被引:1,自引:0,他引:1
将煤电与核电的环境影响和健康风险从全燃料链角度进行比较 ,结果表明 ,煤电燃料链的环境影响和健康风险比核电燃料链大。 相似文献