全文获取类型
收费全文 | 528篇 |
免费 | 48篇 |
国内免费 | 182篇 |
专业分类
安全科学 | 47篇 |
废物处理 | 19篇 |
环保管理 | 110篇 |
综合类 | 315篇 |
基础理论 | 94篇 |
污染及防治 | 104篇 |
评价与监测 | 31篇 |
社会与环境 | 36篇 |
灾害及防治 | 2篇 |
出版年
2024年 | 6篇 |
2023年 | 17篇 |
2022年 | 24篇 |
2021年 | 39篇 |
2020年 | 24篇 |
2019年 | 14篇 |
2018年 | 26篇 |
2017年 | 25篇 |
2016年 | 29篇 |
2015年 | 28篇 |
2014年 | 40篇 |
2013年 | 81篇 |
2012年 | 46篇 |
2011年 | 47篇 |
2010年 | 30篇 |
2009年 | 32篇 |
2008年 | 27篇 |
2007年 | 38篇 |
2006年 | 30篇 |
2005年 | 20篇 |
2004年 | 24篇 |
2003年 | 21篇 |
2002年 | 17篇 |
2001年 | 16篇 |
2000年 | 11篇 |
1999年 | 4篇 |
1998年 | 7篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有758条查询结果,搜索用时 772 毫秒
111.
Extractable atrazine and its metabolites (hydroxyatrazine, deethylatrazine and deisopropylatrazine) were evaluated in agricultural
soils from the temperate humid zone (Galicia, NW Spain) under laboratory conditions. The experiment was performed with five
soils with different properties (organic C, soil texture and atrazine application history), both unamended and treated with
atrazine at field application rate. Measurements of the atrazine compounds were made at different time intervals (1, 3, 6,
9 and 12 weeks) during a 3-month incubation period. Results showed that only hydroxyatrazine was detected in the extractable
fraction of the unamended soils, with values remaining relatively constant throughout the incubation period. Atrazine addition
notably increased the concentration of the parent compound and its degradation products; deisopropylatrazine and hydroxyatrazine
were the main metabolites detected in the extractable fraction of the treated soils, whereas deethylatrazine was not detected.
After 7 days incubation, values of total extractable residues, expressed as percentage of initially added atrazine, ranged
from 75 to 86% (25–68% of atrazine, 7–11% of hydroxyatrazine and 9–57% of deisopropylatrazine). The values decreased rapidly
during the first 3 weeks of incubation, showing values of 2–8% in soils with higher atrazine application and from 28 to 30%
in soils with lower application history. At the end of the incubation, 2–8% of total extractable residues were still detected
(0–4% of atrazine, 2–3% of hydroxyatrazine and 0–2% of deisopropylatrazine), indicating a residual effect of atrazine addition.
These variations in the extractable fraction indicated that most added atrazine was rapidly degraded, especially in soils
with higher application history. 相似文献
112.
113.
Separate collection of municipal solid waste has overcome the 50% threshold in the Asti District in northern Italy, nearly one-third being composed of household and green organic waste. In order to address present and future solutions, it becomes therefore fundamental to assess the environmental performances of the current management of organic waste from separate collection. A from-gate-to-cradle life cycle assessment (LCA) model has been developed by expanding system boundaries, in order to carry out the assessment in the context of the whole waste management streamline. The environmental performances of an existing aerobic plant were made available, based on field measured data, by paying attention to the role and contribution of waste management subsystems. The need for actual and reliable data on materials and energy input, as well as gross and net gains from materials recovery, including benefits arising from use of compost in farming activities, was probably the major drawback that had to be faced. The study integrated the findings of different investigations from the literature with field measured data in order to obtain a more comprehensive framework representative of the area under study. The results may help public administrators to better understand the suitability of using LCA tools when dealing with solid waste management strategies. 相似文献
114.
G. S. Kalacheva E. S. Zadereev V. G. Gubanov I. V. Gribovskaya 《Russian Journal of Ecology》2000,31(2):113-117
The chemical composition of water conditioned by colonies ofMoina macrocopa and involved in the regulation of their life cycle was analyzed in comparison with water samples from natural water bodies.
Dechlorinated tap water was used as the control medium. The results showed that metabolism of crustaceans leads to an increase
in the concentrations of phosphorus and nitrogen in all forms, the appearance of protein and carbohydrate fractions, and changes
in the composition of lipid fractions in the water conditioned by their colonies. The contents of all organic components are
very low, which makes their identification difficult. Concentrations of substances identified in the conditioned water do
not exceed those occurring in nature. 相似文献
115.
Yingying Chen Ruiping Li Yan Gu Hailin Tian Yingping Huang Junsong Chen Yanfen Fang Changying Yang 《环境科学学报(英文版)》2021,33(2):203-215
Photocatalytic process represents a promising approach to overcome the pollution challenge associated with the antibiotics-containing wastewater. This study provides a green, efficient and novel approach to remove cephalosporins, particularly cefoperazone sodium (CFP). Bi4O5Br2 was chosen for the first time to systematically study its degradation for CFP, including the analysis of material structure, degradation performance, the structure and toxicity of the transformation products, etc. The degradation rate results indicated that Bi4O5Br2 had an excellent catalytic activity leading to 78% CFP removal compared with the pure BiOBr (38%) within 120 min of visible light irradiation. In addition, the Bi4O5Br2 presents high stability and good organic carbon removal efficiency. The effects of the solution pH (3.12 - 8.75) on catalytic activity revealed that CFP was mainly photocatalyzed under acidic conditions and hydrolyzed under alkaline conditions. Combined with active species and degradation product identification, the photocatalytic degradation pathways of CFP by Bi4O5Br2 was proposed, including hydrolysis, oxidation, reduction and decarboxylation. Most importantly, the identified products were all hydrolysis rather than oxidation byproducts transformed from the intermediate of β-lactam bond cleavage in CFP molecule, quite different from the mostly previous studies. Furthermore, the final products were demonstrated to be less toxic through the toxicity analysis. Overall, this study illustrates the detailed mechanism of CFP degradation by Bi4O5Br2 and confirms Bi4O5Br2 to be a promising material for the photodegradation of CFP. 相似文献
116.
采用盆栽实验的方法研究了在Cd胁迫下As污染物对水稻(Oryze sativa L.)、大豆(Glycine mdx L .)生长发育及重金属吸收积累的影响,As-Cd污染土壤采用不同改性剂对农产品安全性的影响研究.研究结果表明:单元素As处理与对照相比水稻株高降低了10.3锄、产量下降了9.8%,而大豆株高、产量分别增加了6 cm、36.9%,在实验设计污染物浓度范围内,As对大豆生长发育有刺激作用.As-Cd处理与对照相比水稻的株高、产量分别下降了2.3 cm、1.75%,而大豆株高、产量下降了12 cm、5.6%,As-Cd污染处理抑制了作物的生长发育;As-Cd处理比单元素As处理其水稻籽实、茎叶、根中As含量分别多4.2倍、1.14倍、1.7倍,As-Cd处理比单元素As处理大豆籽实、茎叶、根中As含量分别多4.63倍、2.82倍、1.85倍,Cd元素的存在对水稻、大豆吸收As具有协同作用;采用腐殖酸4%、pH4处理改性措施使土壤中有效态As含量降低,降低了As对农作物的健康风险. 相似文献
117.
浙江沿海藻类共生细菌的生理生化特性研究 总被引:3,自引:0,他引:3
利用梯度稀释法,从浙江象山、朱家尖等海域所采集的几种海藻中分离出海洋细菌50株,运用杯碟法研究了其胞外代谢产物活性,结果表明,100%的菌株含有胶原蛋白酶、淀粉酶,96%的菌株含有酪蛋白酶,70%的菌株含有酯酶,30%的菌株含有卵磷脂酶、脲酶,还有6%含微量的壳多糖水解酶。同时将这50株菌分别培养在高温(55℃)、高盐(质量分数5.5×10-2)、酸性(pH4.5)环境中,同样对胞外产物活性进行分析。结果显示:外界环境胁迫下,水解明胶、淀粉、酪蛋白和吐温的酶活性仍然存在,但活性有了很大的变化。因胶原蛋白酶、酪蛋白酶能分解胶原蛋白等成分,淀粉酶具分解淀粉、糖原的作用,因此,这些细菌的产物对其他生物有毒害作用,可能是致病菌,也可能对已知致病菌起抑制、破坏作用。本研究为寻找海洋活性先导化合物,为海洋药物的开发等提供了广阔的前景。 相似文献
118.
目的 将电子产品在野外环境下日变化波动与季节差异明显的温度载荷编制成温循载荷谱和转换为加速载荷谱。方法 通过四点雨流计数法提取原谱中的载荷循环信息,对提取的循环信息进行分布拟合、相关性检验等统计分析,进而构建循环均值与范围值的联合概率密度函数,再运用概率密度法,编制出8×8二维环境载荷谱。在二维载荷谱基础上,编制出温循载荷谱,使用针对电子部件参数修正的加速方程转化为加速载荷谱。结果 利用野外作业现场1个作业周期内的气温纪录,提供了一套编制温循载荷谱和转换加速载荷谱的合理化流程和解决方案。结论 该制谱方法可以利用原始环境谱中绝大部分有效信息,较好地还原电子部件野外作业阶段经历的温度变化过程,为电子产品的加速寿命试验和使用寿命预测奠定基础。 相似文献
119.
生态产品价值实现是推动“绿水青山”向“金山银山”转化的关键路径,近年来成为研究习近平生态文明思想的热点领域。本文就生态产品价值的内涵理解、实现机理、主要路径及具体实践模式,梳理了近年来国内学者的研究成果,并在此基础上总结与分析,指出存在的问题、提出相关建议。对生态产品价值的理解,目前国内学者从早期的分歧已逐步形成统一的认识,即生态产品本质上是人类从自然生态系统中直接或间接获取的物质和服务的总称,其价值来自生态系统服务价值。生态产品价值实现则是其存在价值通过各种路径被人类消费或使用,最终转化为经济收益或是民生福祉的过程。生态产品价值实现的基本路径主要包括产业发展、市场交易、金融扶持、政府调控和社会参与5种方式,国内目前的实践案例则可以归类为15种模式。但各地在实践过程中也面临生态产品识别边界不清晰、生态产品价值实现机理认识不统一、配套机制不完善以及路径模式创新与实践不够等问题,后续应加快建立生态产品调查统计与评估核算方法体系、完善自然资源产权制度、加强实践模式创新与推广应用。 相似文献
120.
Sorption of biodegradation end products of nonylphenol polyethoxylates onto activated sludge 总被引:3,自引:1,他引:3
Nguyen Viet Hung Masafumi Tate Michihiko Ike Masanori Fujit Shinji Tsunoi Minoru Tanaka 《环境科学学报(英文版)》2004,16(4):564-569
IntroductionRecently ,nonylphenolpolyethoxylates (NPnEO (n :numberofethoxyunits(EOs) )havebecomeaproblematicissueforthereasonthatthesecompounds,animportantgroupofnonionicsurfactants ,havebeenusedwidelyinvariousindustriesasflocculants,dispersants,emulsifie… 相似文献