Facile fabrication of dolomite-doped biochar/bentonite for effective removal of phosphate from complex wastewaters

● Dolomite-doped biochar/bentonite was synthesized for phosphate removal. ● DO/BB exhibited a high phosphate adsorption capacity in complex water environments. ● PVC membrane incorporated with DO/BB can capture low concentration phosphate. ● Electrostatic interaction, complexation and precipitation are main mechanisms. The removal of phosphate from wastewater using traditional biological or precipitation methods is a huge challenge. The use of high-performance adsorbents has been shown to address this problem. In this study, a novel composite adsorbent, composed of dolomite-doped biochar and bentonite (DO/BB), was first synthesized via co-pyrolysis. The combination of initial phosphate concentration of 100 mg/L and 1.6 g/L of DO/BB exhibited a high phosphate-adsorption capacity of 62 mg/g with a removal efficiency of 99.8%. It was also stable in complex water environments with various levels of solution pH, coexisting anions, high salinity, and humic acid. With this new composite, the phosphate concentration of the actual domestic sewage decreased from 9 mg/L to less than 1 mg/L, and the total nitrogen and chemical oxygen demand also decreased effectively. Further, the cross-flow treatment using a PVC membrane loaded with DO/BB (PVC-DO/BB), decreased the phosphate concentration from 1 to 0.08 mg/L, suggesting outstanding separation of phosphate pollutants via a combination of adsorption and separation. In addition, the removal of phosphate by the PVC-DO/BB membrane using NaOH solution as an eluent was almost 90% after 5 cycles. The kinetic, isotherm and XPS analysis before and after adsorption suggested that adsorption via a combination of electrostatic interaction, complexation and precipitation contributed to the excellent separation by the as-obtained membranes.     

从供应链模式看校企合作的功能与约束条件

将企业供应链管理理论引入到职业教育研究,指出供应链能够降低校企合作的交易成本、机会成本和管理成本,而实现上述功能必须以树立集成化供应链管理观念、构建校企合作的激励与利益协调机制、搭建校企合作的网络信息平台、重组高职院校组织结构与流程为条件。     

多源专题数据在国家重点生态功能区生态环境状况评价中的应用

为了建立一套生态遥感快速监测方法,实现生态环境状况评价,以2015年广西40个国家重点生态功能区为例,以全国第一次地理国情普查、高分影像、地貌为基础数据,利用RPC模型及网络刺点进行影像纠正,使用空间分析等程序化处理方法进行代码转换和信息抽取,实现了广西国情普查成果转化,得到了2014年和2015年生态遥感数据,形成一套较为完整的生态遥感快速监测方法,最终得到2015年全区重点生态功能县生态环境状况指数, 40个重点生态功能县中有15个县生态环境质量状况等级为"优",25个为"良"。     

城市河流整治的生态规划要点——以北京市温榆河为例

在城市化进程中人们对城市河流的利用强度日益增大,在饱受污染危害之后,城市的规划和建设者注意到,河流不仅是饮水之源、排污渠道,更是人类生存的重要生态依托,因此,碧水工程已经成为各地城市生态整治的工作重点。但是,河流的生态功能是什么？服务功能又是什么？碧水工程不应只解决水质污染问题,而应保护和恢复河流的生态功能,利用好河流的生态服务功能。本文以北京市温榆河的生态规划为例,充分尊重河流的线性廊道特征,在景观生态学理论和技术的支持下,提出了修复温榆河生态通道功能和恢复天然河流水的运动规律的生态建设要点。     

Dietary bioflavonoid quercetin modulates porcine ovarian granulosa cell functions in vitro

Quercetin is a dietary bioflavonoid used widely as a food supplement and is generally recognized as safe. The aim of this in vitro study was to examine the steroid hormone (progesterone and 17- β estradiol) release, proliferation (PCNA and cyclin B1) and apoptosis (caspase 3 and p53) of porcine ovarian granulosa cells after the addition of quercetin at concentrations 0.01, 0.1, 1, 10 and 100?μmol?L^?1. Progesterone release was stimulated at the concentration 10?μmol?L^?1. Quercetin neither had any impact on 17-β estradiol secretion nor on the presence of PCNA. However, a significant enhancement of the occurrence of cyclin B1 was noted except for the lowest concentration 0.01?μmol?L^?1. Quercetin did not have any influence on the number of granulosa cells containing caspase 3, but at the concentration 10?μmol?L^?1 it inhibited p53 occurrence. Results confirm the safety of quercetin in porcine ovarian granulosa cell model and further suggest its possible concentration-dependent influence on ovarian functions through pathway that may involve progesterone, cyclin B1 and p53.     

Freshwater systems and ecosystem services: Challenges and chances for cross-fertilization of disciplines

Freshwater ecosystems are among the most threatened in the world, while providing numerous essential ecosystem services (ES) to humans. Despite their importance, research on freshwater ecosystem services is limited. Here, we examine how freshwater studies could help to advance ES research and vice versa. We summarize major knowledge gaps and suggest solutions focusing on science and policy in Europe. We found several features that are unique to freshwater ecosystems, but often disregarded in ES assessments. Insufficient transfer of knowledge towards stakeholders is also problematic. Knowledge transfer and implementation seems to be less effective towards South-east Europe. Focusing on the strengths of freshwater research regarding connectivity, across borders, involving multiple actors can help to improve ES research towards a more dynamic, landscape-level approach, which we believe can boost the implementation of the ES concept in freshwater policies. Bridging these gaps can contribute to achieve the ambitious targets of the EU’s Green Deal.     

Approximating pollution abatement costs via alternative specifications of a multi-output production technology: a case of the US electric utility industry

Using a panel of observations from the US electric utility industry, we analyze the output set frontiers that are produced by modeling the technology with different functional forms. Our specifications rely on a series of mapping regimes, based on the paths in which the outputs are scaled toward the frontier, and their outcomes are assessed against the general axiomatic framework of the production model. We demonstrate that different parameterization methodologies produce different empirical analogues of the output set and, as a consequence, can generate rather different estimates of the shadow prices of socially undesirable outputs, or 'bads,' as well. We benchmark our results by assessing the shadow price estimates, often interpreted as the opportunity cost of pollution reduction, against the market prices of pollution permits. The outcomes of our analysis suggest that the estimate of the output set boundary varies with the choice of a parameterization technique, which provides a possible explanation for the sizeable differences between the shadow prices of bads reported in the literature. We also demonstrate that among a variety of existing parametric methodologies no single technique is superior to all others.     

Estimating animal densities and home range in regions with irregular boundaries and holes: A lattice-based alternative to the kernel density estimator

Density estimates based on point processes are often restrained to regions with irregular boundaries or holes. We propose a density estimator, the lattice-based density estimator, which produces reasonable density estimates under these circumstances. The estimation process starts with overlaying the region with nodes, linking these together in a lattice and then computing the density of random walks of length k on the lattice. We use an approximation to the unbiased crossvalidation criterion to find the optimal walk length k. The technique is illustrated using walleye (Sander vitreus) radiotelemetry relocations in Lake Monroe, Indiana. We also use simulation to compare the technique to the traditional kernel density estimate in the situation where there are no significant boundary effects.     

A novel approach combining bootstrapped non-intrusive reduced order models and unscented transform for the robust and efficient CFD analysis of accidental gas releases in congested plants

The risk assessment for safety-critical, complex systems is a very challenging computational problem when it is performed with high-fidelity models, e.g. CFD, like in the case of accidental gas releases in congested systems. Within this framework, a novel CFD approach, named Source Box Accident Model, has been recently proposed to efficiently model such phenomena by splitting the simulation of the gas release and its subsequent dispersion in the system in two steps. In this view, the present paper proposes a non-intrusive, Proper Orthogonal Decomposition-Radial Basis Functions reduced order model that exploits the two-step nature of the SBAM approach, to mimic the behaviour of the original, long-running CFD model code at a significantly lower computational cost. Moreover, the paper presents a methodology combining the bootstrap and unscented transform approaches to efficiently assess the ROM uncertainty in the safety-critical simulation output quantities of interest, e.g. the flammable volume. The results obtained in a test case involving a high pressure, accidental gas release in an off-shore Oil & Gas plant are in very satisfactory agreement with those produced by CFD, with a relative error smaller than 10% and a reduction in the computational time of about three orders of magnitude.