直接进样-气相色谱质谱法同时测定固定污染源排气中的含氟温室气体

建立了一种直接进样-气相色谱质谱法同时分离和测定固定污染源排气中三氟甲烷、四氟甲烷、六氟乙烷和六氟化硫等含氟温室气体的方法。使用CP-Sillica PLOT毛细管填充柱可使上述4种目标化合物实现基线分离。分别用全扫描模式和选择离子扫描模式进行定量分析,方法检出限分别为0.12,0.19,0.10,0.08 mg/m~3和2.8,3.4,1.7,3.1μg/m~3。探讨了样品保存容器与保存时间对样品浓度衰减的影响,指出Tedlar采样袋或铝塑复合膜采样袋可以较长时间保存样品,在常温下,样品可保存至少7 d。实际样品测定结果表明方法快速、简便,适用于固定污染源排气中含氟温室气体的测定。     

碳排放权交易机制能否兼顾企业效益与绿色效率?

基于碳减排治理全球变暖的碳排放权交易机制,探讨了碳交易能否兼顾企业效益与绿色效率,及企业减碳优化策略。通过匹配2006—2017年中国上市公司及所在地区数据,首先运用双重差分方法,总体衡量碳交易对企业要素投入产出及全要素生产率的影响。然后运用平行趋势、滞后两期、工具变量及安慰剂,检验碳交易双效模型的稳健性,并利用三重差分检验是否存在因企业性质不同而造成差异化影响。最后运用中介与调节效应方法,检验碳交易与全要素生产率的中介效应,并考察了绿色创新、市场化与政府补贴影响下有调节的中介作用。实证结果显示:碳交易对绿色全要素生产率、企业全要素生产率均有显著负向影响。碳交易促进碳减排,导致营业成本增加、劳动生产率降低,但同时也显著正向影响资本生产率,促进企业利润与收入增长。绿色全要素生产率在绿色创新、市场化和政府补贴显著的调节影响下,对碳交易与企业全要素生产率的关系起到部分中介作用。研究表明,碳交易在一定条件下能够实现绿色效率和企业效益双赢,碳交易的作用在于依次实现碳减排、企业全要素生产率提升和绿色全要素生产率提升,而绿色效率和企业效益协同尚处于“遵循成本”阶段。因此,要建立一套集市场化、政府奖惩和绿色创新为核心的碳交易体系,进一步健全绿色低碳的激励约束机制,加强绿色创新补偿,增强企业自主研发和协同创新能力,提升绿色技术转化率,优化绿色产业结构,完善配套环保标准和管理规范,诱导企业完成“创新补偿”的蜕变。     

绿色消费的社会治理体系研究

绿色消费,伴随可持续发展战略的产生而逐步体现在居民日常生活中。消费什么主要由消费者自行决定,政府难以强求;是否消费绿色产品,受到收入、受教育程度、追求品质的动机等要素影响,购买消费品时还受认知过程、情绪过程、意志过程制约。绿色消费不仅要满足人体健康和社会需求,还要体现资源节约和环境保护基本国策要求,以实现消费品生产、流通、消费以及包装物回收利用全生命周期的环境影响最小化。政府可以通过政策激励、宣传教育、率先垂范等途径引导公众更多的消费绿色产品。     

我国绿色轮胎的发展现状

介绍了欧盟颁布的《关于化学品注册、评估、许可和限制法规》（REACH法规）以及轮胎标签法等有关绿色轮胎的法规及实施情况。从轮胎设计及对原辅材料的选用等方面概括了绿色轮胎的主要技术要求。综述了我国绿色轮胎的发展现状。对我国绿色轮胎的发展提出了提高行业整体工艺水平、产品升级换代、制定相关标准、自愿进行绿色轮胎认证等建议。     

中国农村绿色发展绩效的空间差异

运用多种DEA模型与Gini准则相结合的方法,采用2003—2012年中国31个省、直辖市和自治区农村数据,对中国及其各地区农村绿色发展绩效值进行了动态测算与分析,在此基础上,对各省市及其所属地区农村绿色发展绩效值进行排名和分析。结果表明,从全国层面来看,中国农村绿色发展绩效整体上呈现上升趋势,如综合绩效值由2.184上升至2.824,表明全国在关注农村经济发展的同时越来越注重环境保护,注重资源和能源的节约,从而促进了全国农村地区绿色发展绩效的提高;从分区域来看,农村绿色发展绩效存在地区差异,绿色发展绩效较高地区是东北,年均值为2.502,西北次之,年均值为2.385,华北、华东和中南地区绩效值相对偏低;进一步地,各省、直辖市和自治区农村绿色发展绩效逐年呈现上升趋势,但有部分省市,如辽宁、河北和山西等,农村绿色发展绩效值偏低,甚至低于该省市所在地区的平均绩效值,这不仅反映了该省市农村绿色发展绩效较低,而且表明了该省市农村绿色发展绩效的高低制约着其所在地区农村整体绿色发展绩效的提升。此外,由于不同省、直辖市和自治区在资源禀赋、技术水平、政策和制度环境等方面不同,农村绿色发展的绩效值在省际之间存在较大差异。基于研究结果,在今后我国农村地区绿色发展过程中,一方面,需要加大绿色资源的投入,为农村绿色发展提供基本的条件;另一方面,需要加大对农村绿色劳动力的投入,确保为农村绿色发展提供高素质劳动力;与此同时,还要不断提高绿色技术水平,为农村绿色发展创造良好的技术条件,以此促进我国农村地区绿色绩效的进一步提高。     

人力资本、产业结构调整与绿色发展效率的作用机制

寻求经济增长与环境改善的双赢已成为中国推进绿色发展的内在要求。人力资本与产业结构调整相互作用,均被视作改善绿色发展效率的重要支撑条件,然而两者的相互作用能否促进中国绿色发展效率提升尚未得到关注。本文梳理人力资本、产业结构调整与绿色发展效率之间的作用机制,在使用包含非期望产出的SBM模型测算中国1997—2013年各省份绿色发展效率的基础上,识别人力资本、产业结构调整及其交互对于绿色发展效率的作用方向与影响力度。结果显示:总体而言,样本期内绿色发展效率存在无效率状态,这与中国粗放型发展方式有关;从空间尺度上看,绿色发展效率呈现出东部高于中西部的态势;从时间尺度上看,绿色发展效率在样本前半期与后半期的变动趋势并不一致,前半期效率值呈现出下降趋势而后半期则表现为波动变动;全国层面与东、中、西部人力资本水平以及人力资本结构未能发挥提升绿色发展效率的作用,产业结构调整的两个维度——产业结构高级化与产业结构合理化在全国层面与东、中部均表现出改善绿色发展效率的态势;人力资本水平(人力资本结构)与产业结构高级化、产业结构合理化的交互项对于绿色发展效率的提升作用在全国层面与东部有所体现但力度不强。应以联动性而非割裂的视角看待中国所进行的人力资本培育与产业结构调整,应当努力减少人力资本与产业结构调整之间相互脱节、不相适应的状况,不断增进人力资本与产业结构调整的适配性以提升中国各省份绿色发展效率。     

Energy conservation and waste utilization in the cement industry serve the green technology and environment

The cement industry is one of the most energy-intensive industries consuming 4 GJ/ton of cement, i.e. 12–15% of the energy use in total industry. Energy cost accounts for 30% of the total cost of cement production. Seventy-five per cent of this energy is due to the thermal energy for clinker production. It is also found that 35% of this supplied thermal energy is lost in flue gas streams. Most modern kilns use pet coke or coal as their primary fuel. Instead, the municipal waste in landfills offer a cheap source of energy and reduce the environmental effects of dumping solid waste. The calcination and drying processes and the kiln need large quantities of thermal energy. About 40% of the total energy input is lost in the hot flue gases and cooling the stack plus the kiln shell. Hence, it is suitable to use an organic Rankine cycle (ORC) to recover the exhaust energy from the kiln. Alternatively, a 15 MW gas turbine engine combined with a steam turbine could be utilized. It was found that ORC produces 5 MW with a capital cost recovery period of 1.26 years. However, the gas turbine combined system produces 21.45 MW with a maximum recovery period of 2.66 years.     

Evaluation of pressurized liquid extraction for the determination of neonicotinoid pesticides in green onion

Abstract

A pressurized liquid extraction (PLE) method was presented for the determination of six neonicotinoid pesticides, acetamiprid, clothianidin, dinotefuran, imidacloprid, thiacloprid, and thiamethoxam in green onion. The critical parameters of PLE, e.g. extraction solvent, temperature, pressure, number of cycles, and static extraction time, were optimized by test on the spiked green onion with six neonicotinoids and the incurred green onion applied with four commercial neonicotinoid insecticide formulations (acetamiprid, dinotefuran, imidacloprid, and thiamethoxam). As a result, the recoveries of six neonicotinoids obtained by one cycle PLE with acetonitrile at 140?°C and 50?bar for 10?min were 94.7–99.5%. These results were acceptable according to the validation guideline for testing method of agricultural chemicals in food by Ministry of Health, Labour, and Welfare in Japan. PLE was also validated by the test on the incurred green onion. The analytical values of four neonicotinoids obtained by PLE were good agreement with those obtained by solid–liquid extraction with homogenizer, which is employed for Japanese official method for the analysis of pesticide residues in food (the ratios of analytical values obtained by PLE to those obtained by solid–liquid extraction were 99.7–101.2%). These results indicate that PLE is applicable for the determination of neonicotinoids in green onion.     

Green energy for the battlefield

Population of the world is growing with increasing rate and it seems that existing fossil fuel energy sources will not be able to meet energy demand in the near future. Energy is not only crucial for civil sector but also it is one of the most important assets in defense sector. Energy for military operations is mostly provided from fossil fuel as it is the case in other sectors; however, fossil fuels have hazardous effects to the environment and cause global environment concerns. These drawbacks of fossil fuels are also valid for battlefield. Furthermore, transportation of fossil fuels causes extra safety and logistics problems in military case. In this study, we developed a hybrid green energy solution with wind, solar, and batteries together to minimize or eliminate the fossil fuel demand for the battlefield. Results of our algorithm are superior to the already used diesel generator solution from the point of view of cost and various other aspects. The novelty of our study stems from applying optimization of hybrid green energy solution to military case with battlefield constraints.     

天水市麦积区大气总悬浮颗粒物与绿地分布的关系研究

以麦积区城郊2013年实测绿地大气总悬浮颗粒物(TSP)为根据,应用空间变异分析、克里格插值、重分类等方法,对麦积区城郊绿地大气TSP进行了分析,得出如下结论:当绿地结构是乔木和灌木组成的针阔混交林、森林覆盖率在73%时,大气TSP质量浓度小于0.08mg/m3;当绿地结构是天然林、小部分经济林和绿化带组成的阔叶林、森林覆盖率在51%时,大气TSP质量浓度为0.08~0.20mg/m3;当绿地结构是经济林、绿化带和农田、森林覆盖率在30%以下时,大气TSP质量浓度在0.20mg/m3以上;森林覆盖率在10%左右时,大气TSP质量浓度在9.700~13.548mg/m3。麦积区城市绿地结构和森林覆盖率直接影响大气TSP浓度,这为麦积区城市绿地规划和建设、改善城市环境质量提供了理论依据和技术指导。