磁性Fe_3O_4/石墨烯纳米复合材料催化降解水中17β-雌二醇

利用化学沉淀法制备磁性四氧化三铁/石墨烯(Fe3O4/GE)纳米复合材料,并将其与H2O2构成非均相Fenton体系用于催化降解水中微量的17β-雌二醇(E2),研究了初始p H值,初始H2O2浓度,催化剂用量对E2降解的影响。结果表明,Fe3O4/GE纳米复合材料在无需外加光源的条件下能够有效催化降解E2。在p H 7.0,E2初始浓度为1 mg/L,初始H2O2浓度为15 mmol/L,Fe3O4/GE投加量为15 mg/L的条件下,反应8 h后可去除92.9%的E2。Fe3O4/GE具有便捷的磁分离特性和稳定的催化活性,经过7次循环使用后对E2的降解效率仍保持在91.5%左右。     

我国废钢加工装备发展现状与展望

以绿色经济和循环经济的重大需求为背景,系统阐述了废钢加工装备的现状与发展,详细介绍了废钢加工装备的种类与用途,分析并总结了废钢加工装备的应用现状,指出了废钢加工装备以及废钢加工行业的发展方向。     

Metals recycling in the United States

Twenty-two metals for which secondary recovery is important, in terms of quantity and/or value, were compared and ranked for rate and efficiency of recycling, and availability of recycled metal. In general, their recycling rates trended upward over the period 1970–1993. Iron, aluminum, copper, gold, platinum, and lead accounted for most of the value of all secondary metal produced, while iron and steel dominated in terms of quantity produced and exported. The factors most influential on recycling rates are profitability, public support, organization of infrastructure, sortability, legislative support, and scrap purity. The share of supply accounted for by secondary metals is expected to surpass that of primary metals sometime in the next decade.     

我国废钢铁资源的可持续利用政策

本文概述了我国废钢铁资源回收利用的现状以及钢铁工业对废钢铁资源的需求现状，用三种不同的模型预测了未来钢铁工业的发展对废钢铁资源的需求，提出了废钢铁资源可持续利用存在的问题和政策建议。     

Manufacture of strand board made from construction scrap wood

The objective of this research was to evaluate the physical and mechanical properties of strand board made from construction scrap wood. The strand board was manufactured using Sugi (Cryptomeria japonica D. Don) and Douglas-fir (Pseudotsuga japonica) strands selected from construction scrap wood. The strands were oriented, and three-layer (face/core/face) strand board of three types was produced: one in which the strands of the face layer were oriented at a right angle to those of the core layer (R board), another in which the strands of the face layer were oriented parallel to those of the core layer (P board), and a third in which the strands of both layers were oriented at random (Ra board). The physical and mechanical properties of the boards were evaluated based on Japanese Industrial Standard (JIS). The main results obtained are as follows: the bending strength of the strand board with a density larger than 0.55 g/cm³ exceeded the standard value of type 18 particleboard of JIS A 5908. The bending strength of the strand board was affected by board density, strand orientation and resin content, and became larger with increased density as well as resin content. That of the parallel specimen of P board was the largest among the specimen-orientations and types. The internal bond strength of the strand board with a density larger than 0.55 g/cm³ exceeded the standard value of type 18 particleboard and type 24-10 particleboard of JIS A 5908. The internal bond strength was markedly affected by the resin content of the core layer, and became larger with increased density. The thickness swelling of the strand board decreased with increased resin content, and become larger with increased density.     

森林保险支付意愿及影响因素分析——基于异质性营林主体视角

基于期望效用函数理论分析了异质性营林主体的森林保险支付意愿及差异,并以传统小林农和新型林业经营主体为研究对象,以福建省382户传统小林农和88户新型林业经营主体的调研数据为基础,综合运用条件估值法、卡方检验及Cox比例风险模型,对异质性营林主体的森林保险支付意愿与差异及支付意愿影响因素进行对比与分析。研究表明：传统小林农和新型林业经营主体的森林保险意愿支付水平存在显著差异,在1000~2500元/亩保障水平下,传统小林农的意愿支付水平分别为1.911元/亩、2.941元/亩、3.532元/亩及3.979元/亩,新型林业经营主体为1.632元/亩、3.971元/亩、5.809元/亩及6.864元/亩;两类营林主体的支付意愿均随保额的提高而提高,但新型林业经营主体的提升幅度远高于小林农。异质性营林主体的森林保险支付意愿影响因素也存在明显差别,这与其在森林保险认知特征、林业生产经营特征、林业灾损特征、森林保险产品评价特征等方面存在显著差异有关。此外,林地面积对两类营林主体支付意愿均具有显著影响,规模化、集约化的林业生产经营可促进林业经营主体的森林保险愿意支付水平。     

纳米Fe3O4/CeO2-H2O2非均相类Fenton体系对3,4-二氯三氟甲苯的降解

以浸渍法制备的新型纳米Fe3O4/Ce O2为催化剂,3,4-二氯三氟甲苯(3,4-DCBTE)为目标污染物,在Fe3O4/Ce O2-H2O2非均相类Fenton体系中对目标污染物的降解进行研究,考察催化剂的催化效果和温度、p H、H2O2投加量等因素对催化剂催化效果的影响.结果表明,以纳米Fe3O4/Ce O2作为催化剂的非均相类Fenton体系对3,4-二氯三氟甲苯的处理效果极佳;随着温度的升高,纳米Fe3O4/Ce O2的催化效果不断提高;在偏酸性环境中,p H越低催化效果越好,p H=2时反应去除效率可达96.67%;随着H2O2投加量的增加,3,4-二氯三氟甲苯的降解效率先提高后降低,投加量为15 mg·L-1时去除效果最好可达99.47%;随着催化剂投加量的增加,同样出现了处理效果先升高后降低的现象,投加量为0.5 g·L-1时催化效果最好可达99.64%.在以纳米Fe3O4/Ce O2为催化剂的非均相类Fenton体系中,3,4-二氯三氟甲苯的降解符合一级反应动力学,反应所需活化能较低只需30.26 k J·mol-1.     

炮采放顶煤采空区自然发火的数值模拟应用

针对炮采放顶煤开采采空区容易发生自燃问题，基于漏风渗流方程、气体渗流一扩散-氧消耗方程，建立了采空区自然发火非稳定数值模型，采空区按非均质考虑，耗氧汇按煤矸氧化和瓦斯涌出稀释两方面综合考虑，用有限元数值方法联立求解模型。结合羊草沟矿实例，通过该矿自然发火后来的测试区的现场实测结果，拟合反演得到采空区煤的耗氧速度、瓦斯涌出强度和渗透特征参数，用确定的模型分析了前段出现自然发火的原因；描绘了炮采放顶煤开采时采空区冷却带、自燃带和窒息带等三带的形状，指出冒落压实的不均衡的非均质采空区，自燃点在偏人风一侧。用三带划分理论讨论了工作面参数（风量、推进度、控顶距）同自燃的量化关系，提出了从根本上预防采空区自然发火的途径与方法。     

The use of nanovermiculite catalyst in the study of removal of the organic load and degradation of atrazine via ozone process in RPB reactor

Abstract

The main objective of this study is the degradation of a synthetic solution of atrazine by a modified vermiculite catalyzed ozonation, in a rotating packed bed (RPB) reactor. A 0.5?L RPB reactor was used to perform the experiments, using a Central Composite Design (CCD) response surface to construct the quadratic model based on the factors: pH, catalyst concentration and reactor rotation frequency. The response variable was the removal of the organic load measured in terms of Chemical Oxygen Demand (COD). After the complete quadratic model was constructed through the response surface, the COD degradation process had an optimal removal of 41% under the following conditions: pH 8.0, rotation of 1150?rpm and catalyst concentration 0.66?g L^?1.