Interparticle diffusion and thermodynamic modeling studies for the removal of heavy metals using mixed adsorbents in industrial effluents

Pollution of water, air, and soil by industrial effluents is a major problem nowadays. A variety of contaminants are too responsible for changing the physicochemical properties of the receiving body. There are practical treatment solutions available to clean up contaminants from various resources. The term “adsorption” refers to one of them. The purpose of the research work is to remove heavy metals from industrial effluent. Mixed adsorbents prepared from activated charcoal and bone charcoals were used to remove the copper and cadmium ions. The experiment carried out in a batch operation and modeling of these data for intraparticle diffusion and thermodynamic calculations were reported in this research work. At optimum operating condition pH 6; metal ion concentration 50 mg/L; dose 5 g/L; agitation 180 rpm and temperature 40°C maximum 99.41% copper ions and 88.12% cadmium ion removal was achieved. Cadmium ions were well fitted in the thermodynamic model compared to copper ions, as demonstrated by the higher correlation coefficient R² (0.9824) value. Intra particle diffusion demonstrated that film diffusion was a rate-limiting step at the start of the reaction, while microporous intraparticle diffusion was the rate-determining phase later on. A Fourier transformation infrared spectroscopy, X-ray diffraction, and scanning electron micrography analysis confirmed the suitability of mixed adsorbents for the removal of cadmium and copper metal ions.     

Effect of ignition delay on explosion parameters of corn dust/air in confined chamber

This paper presents the explosion parameters of corn dust/air mixtures in confined chamber. The measurements were conducted in a setup which comprises a 5 L explosion chamber, a dust dispersion sub-system, and a transient pressure measurement sub-system. The influences of the ignition delay on the pressure and the rate of pressure rise for the dust/air explosion have been discussed based on the experimental data. It is found that at the lower concentrations, the explosion pressure and the rate of pressure rise of corn dust/air mixtures decrease as the ignition delay increases from 60 ms; But at the higher concentrations, the explosion pressure and the rate of pressure rise increase slightly as the ignition delay increases from 60 ms to 80 ms, and decrease beyond 80 ms. The maximum explosion pressure of corn dust/air mixtures reaches its highest value equal to 0.79 MPa at the concentration of 1000 gm⁻³.     

袋式除尘器喷吹管设计参数对喷吹气量影响的计算分析

针对袋式除尘器的脉冲喷吹气流量不均匀性问题,利用CFD数值模拟建立含有结构参数、运行参数的脉冲袋式除尘器的喷吹气流分布模型,通过正交试验法研究了喷吹压力P、喷口个数N、喷口口径D、喷嘴管长H、脉冲时间T和喷口间距L对脉冲喷吹气流量不均匀性σ的影响程度,并拟合得到了各参数与σ的关系式。在设计压力条件下修正喷口管径,获得较好的气流量分布;对修正后的均匀喷吹管,得到在不同喷吹压力下其气流量不均匀性的变化情况。     

Contamination levels and state assessment in the lakes of the Oliveri-Tindari Lagoon (North-Eastern Sicily,Italy)

The Oliveri-Tindari Lagoon, located in North-Eastern Sicily (Italy) and composed of six lakes, is subject to continuous environmental changes. An integrated study focusing on sediment features and levels of contamination was carried out for three of the six lakes, which are of ancient origin: Verde, Mergolo della Tonnara and Marinello. A high primary production (26.89 μg l^?1) was detected at Lake Verde; texture classification showed a typical grain size in the sediments of all lakes; the study of macronutrients highlighted 17.08 of total carbon in sediments from Lake Mergolo della Tonnara; toxic elements were detected at higher concentrations in the sediments of Lake Marinello in comparison to the others, while arsenic was found in high concentrations in all the samples tested, especially in Lake Verde, with a mean value of 17.25 mg kg^?1 dry weight (d.w.). All the organic contaminants, except 4, 4′-dichlorodiphenyldichloroethylene, were below the detection limits in the sediments. Minimal microbiological contamination was found in both water and sediment samples. In the latter, we isolated several bacterial strains thriving in the presence of arsenic, which play a role in the biogeochemical cycle of arsenic. These preliminary results, obtained for the first time using a multidisciplinary approach, provide general information about the Oliveri-Tindari Lagoon area.     

Protective effects of curcumin on antioxidant status,body weight gain,and reproductive parameters in male rats exposed to subchronic 2,3,7,8-tetrachlorodibenzo-p-dioxin

The aim of this study was to investigate the effects of curcumin (CUR) on antioxidant status, body weight (BW) gains, and some reproductive parameters in male rats exposed to subchronic doses of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Thirty-two rats were divided into four groups. The first group was kept as control. The second group (TCDD group) was given TCDD at a dose of 50 ng·kg^?1 BW per day; the third group (CUR group) was treated with CUR at a dose of 80 mg·kg^?1 BW per day. The fourth group (TCDD + CUR group) was given TCDD and CUR at the same doses simultaneously. Malondialdehyde (MDA) levels were significantly increased in the TCDD group. In addition, TCDD exposure decreased liver superoxide dismutase (SOD) activity, catalase (CAT) activities of kidney and brain, glutathione peroxidase (GSH-Px) activities of liver, kidney, and brain, and glutathione levels of liver, kidney, and heart. However, CUR treatment with TCDD exposure decreased MDA levels in all tissues and increased SOD activities of liver, kidney, and brain, CAT activity of heart, and GSH-Px activities of heart and brain. TCDD caused a decrease in BW gain, and CUR partially eliminated this effect of TCDD. In addition, while reproductive organ weights, sperm concentration, and sperm motility tended to decrease with TCDD exposure, these effects tended to be close to normal levels by CUR treatment. In conclusion, CUR was seen to be effective in the treatment and prevention of toxicity induced by subchronic TCDD exposure.     

Effect of dietary Jatropha curcas seed meal on rabbits infested by adult ticks of Hyalomma marginatum marginatum

The objective of this study was to investigate the effectiveness of the oral administration of Jatropha curcas seed meal (JCSM) on serum biochemical parameters and histopathology of skin, liver, and kidney of rabbits experimentally infested by Hyalomma marginatum marginatum. Thirty healthy mixed-breed rabbits were randomly divided into five equal groups. The first group was kept as a control and fed soya bean meal. The remaining groups were fed diets containing 2.5%, 5%, 7.5%, or 10% JCSM. At the sixth week, each group was divided into two subgroups. Ticks were introduced to all members of one subgroup, the other subgroup being kept as control. Blood samples were collected and analyzed for biochemical parameters before (zero time) and after the treatment, on the 6th and 8th weeks. Histopathological studies were conducted 8 weeks after the treatment. The results revealed that JCSM could be used in the treatment of ectoparasites at levels of less than 10% in the diet without any serious effects on liver and kidney functions.     

金莲木（Ochna integerrima（Lour．）Merr．）的生态生物学特征及其播种繁殖技术

金莲小（Ochnaintegerrima（Lour．）Merr．）足金莲术科落叫淞小或小乔小,址潜在的优良Ⅲ林绿化树种．文章从其形态解削特,其光合生理生态特征及播种繁殖技术方面进行了系统的研究。结果表明：金莲小为rft性偏阳性树种,光合速率LI进秤星单峰曲线,尤午休现象;其光饱和点（LSP）和I光补偿点（LCP）分别在800μmol·m^-2.s^-1及52．2μmol·m^-2．s^-1左右、在高于光饱和点的光强下,其叶片的光合速率并未出现叫娃下降趋势,州时还维持了较i舟的蒸腾速率,、金莲小叶绿素荧光参数显水其具有较高的能精利用效率,叶绿素a／b比值（5．677：1）略高于理论价（3：1）,表明它能有效吸收比能许传到光反应叭tl山。播种前金莲小种子宵进行浸泡处理,浸泡24h处理后足发芽率高日．发芽较早,播种住泷炭土中的种f较沙土中的种子发芽要甘H荫发周期短,但往沙土中播种的种子最终的发芽率耍相对较高。、㈧此,金莲l术适合生长存水热充沛、土壤十}1对JJ巴沃的热带亚热带地区,栽培时要尽量选择十层肥沃的壤土或砂质壤土。金莲术（Ochnaintegerrima（Lout．）Merr．）是金莲术科落叶灌本或小乔木,是潜在的优良冈林绿化树种。文章从其形态解剖特征、光合生理生态特征及播种繁殖技术方面进行了系统的研究。结果表明：金莲木为中性偏阳性树种,光合速率日进程呈单峰曲线,无午休现象;其光饱和点（LSP）和光补偿点（LCP）分别在800μmol·m^-2．s^-1及52．2μmol·m^-2．s^-1左右。在高于光饱和点的光强下,其叶片的光合速率并未出现明显下降趋势,同时还维持了较高的蒸腾速率。金莲术叶绿素荧光参数显示其具有较高的能量利用效率,叶绿素a／b比值（5．677：1）略高于理论值（3：1）,表明它能有效吸收光能并传到光反应中心。播种前金莲木种子宜进行浸泡处理,浸泡24h处理后其发芽率高且发芽较早,播种在泥炭土中的种子较沙土中的种子发芽要早且萌发周期短,但在沙土中播种的种子最终的发芽率要相对较高。因此,金莲木适合生长在水热充沛、土壤相对肥沃的热带亚热带地区,栽培时要尽量选择土层肥沃的壤土或砂质壤土。     

液中膜MBR工艺在中水处理中的工程应用

液中膜MBR工艺是将膜分离技术与传统生化处理技术相结合的一种新型、高效的污水处理方法,具有出水水质好、设备占地面积小、活性污泥浓度高、剩余污泥量少等特点。采用该工艺对生活污水处理进行了工程应用,对工程设计运行参数和污染物去除机制进行研究,并进行技术经济分析。结果表明:出水COD、氨氮、SS等指标均优于GB/T18920—2002《城市污水再生利用——城市杂用水水质》要求,出水可回用于浇洒道路、绿化、冲厕等,并提出根据出水氨氮浓度的变化作为系统排泥的依据,有效地指导工程的稳定运行。     

基于环境参数监测评估的丙烯腈装置安全预警技术研究

以丙烯腈生产装置为研究对象,调查分析其存在的主要危险因素以及工艺特性,依据偏差分析原理建立了丙烯腈装置的异常处置原则与标准,设计了具有环境质量浓度监测评估和过程参数偏差预警分析的双重监控预警平台。该平台通过建立的OPC通讯技术,实时获得现场环境质量浓度及关键参数的信息,进行泄漏扩散事故的早期预警和早期干预处置,并通过对监测数据的综合动态分析预测危险气体环境质量浓度的变化趋势以及可能对周边带来的危害。     

Multiannual trend of microcystin production in the toxic cyanobacterium Planktothrix rubescens in Lake Garda (Italy)

Massive developments (blooms) of cyanobacteria represent a major concern in many natural and artificial waterbodies, because of the high levels of toxins that can be released into water. Microcystins, potent hepatotoxins, represent the most frequent toxins produced by cyanobacteria. The determination of the microcystins’ profile in waterbodies is important for determining the real toxic potential. We have investigated the evolution of the microcystins’ profile of Lake Garda (Italy) from both a qualitative and a quantitative point of view over a period of five years. We have also analysed possible correlations between toxin profile and selected environmental parameters. We found that a demethylated microcystin variant (RRdm) was always dominant but showing a cyclic trend, alternating periods in which it represented the only variant, and periods in which other variants were present (LRdm, HtyrRdm, RR, and LR). These changes are probably due to changes in chemotypes composition inside the resident Planktothrix rubescens population and do not seem to be exclusively linked to the considered environmental variables. Total microcystin concentrations were always low (in the ng?L^?1 scale), and showed typical peaks in the metalimnetic layer during summer–autumn time of each year.