Fenton试剂预处理化工综合废水的研究

以化学工业园区废水为研究对象初步研究了Fenton试剂预处理化工综合废水时各影响因子的作用机制,通过正交实验确定了Fenton反应的最佳操作条件为：反应时间70 min,硫酸亚铁投加量为2.6 mmol/L,温度为40℃,初始pH3.5,二价铁离子和过氧化氢的摩尔比为1∶8时,COD的去除率可达到60%以上,B/C值可...     

Welch功率谱估计方法的参数选择

研究了welch谱估计方法中窗函数和窗长度及FFT点数对谱估计结果的影响,应用Matlab中的Pwelch函数,作了仿真分析。根据分析结果,提出了有关窗函数、窗长度和FFT点数确定问题的建议。     

河流水质评价中模糊数学评价法的应用与比较

选择2005年6个典型日（1月12日、3月10目、5月10日、7月13日、9月8日和11月10日）的水质,运用两种模糊数学评价法对浙江西苕溪流域港口断面的水质进行评价并作比较。第一种数学评价法采用较为简单的单因素模糊综合评价法,另一种采用多级模糊数学评价法。评价结果表明,1月12日、3月10日和11月10日的水质达到国家Ⅰ类水质标准;而5月10目的水质相对最差。比较两种评价方法,单因素模糊综合评价法对单个因素的影响敏感,特别是超标值对最后的相对隶属度贡献大;而多级模糊评价法综合各个因素来评价现状水质,因而反映出水质的综合情况。结合港口断面的特点分析水质变差的原因,结论是：流域农业劳作带来的面源污染物质进入港口断面使得该断面在农作高峰期水质较差;同时,断面的水资源短缺问题较为严重,导致水环境容量较小,污染物较难稀释扩散。     

英语电影教学与英语综合应用能力的培养

英语电影教学是走在前端的一项多媒体教学尝试。语言学习轻松、直观,内容生动、丰富,在减轻学生语言学习焦虑及培养学生语言的应用能力,了解西方社会文化、历史等方面起到了有效的促进作用。     

Inherent risk assessment—A new concept to evaluate risk in preliminary design stage

Quantitative Risk Assessment (QRA) has been a very popular and useful methodology which is widely accepted by the industry over the past few decades. QRA is typically carried out at a stage where complete plant has been designed and sited. At that time, the opportunity to include inherent safety design features is limited and may incur higher cost. This paper proposes a new concept to evaluate risk inherent to a process owing to the chemical it uses and the process conditions. The risk assessment tool is integrated with process design simulator (HYSYS) to provide necessary process data as early as the initial design stages, where modifications based on inherent safety principles can still be incorporated to enhance the process safety of the plant. The risk assessment tool consists of two components which calculate the probability and the consequences relating to possible risk due to major accidents. A case study on the potential explosion due to the release of flammable material demonstrates that the tool is capable to identify potential high risk of process streams. Further improvement of the process design is possible by applying inherent safety principles to make the process under consideration inherently safer. Since this tool is fully integrated with HYSYS, re-evaluation of the inherent risk takes very little time and effort. The new tool addresses the lack of systematic methodology and technology, which is one of the barriers to designing inherently safer plants.     

侧沟式膜泥法一体化OCO工艺中水力停留时间对脱氮除碳的影响

在传统OCO工艺基础上设计了一体化OCO工艺,在厌氧区放置填料,将二沉池和生物反应器合建,并就水力停留时间(HRT)对生物反应器脱氮除碳的影响进行研究。在进水COD为260～360 mg/L,好氧区DO为2 mg/L左右,缺氧区<0.5 mg/L,MLSS为4 500 mg/L左右时,分别研究了不同HRT下的脱氮除碳效果。研究结果表明：随着HRT的逐渐增大,出水COD值无明显波动,COD去除率达到90%以上,出水氨氮随着HRT的增大而降低;但仅当HRT为12 h左右时,氨氮和总氮均有良好的去除效果,去除率分别可达到93%和80%。     

Embracing sustainability: the incorporation of sustainability principles in municipal planning and policy in four mid-sized municipalities in Ontario,Canada

The issue of planning for sustainability is becoming more established within Canadian municipal planning. As municipalities begin to align their planning policy to reflect a more sustainable approach, there is an increased interest in how sustainability is being operationalised within municipal documents. This research aims to better understand how principles of sustainability are imbedded within Ontario municipal documents, with a specific focus on the Integrated Sustainability Community Planning approach that has emerged in Canada. Drawing on a nested comparative case study of four mid-sized municipalities, we uncover the language and strategies employed by the municipalities as they relate to the principles of sustainability developed by Gibson [2006a. Sustainability assessment: basic components of a practical approach. Impact Assessment and Project Appraisal, 24 (3), 170–182]. The findings suggest that current policy-based approaches to sustainability are considering more socially oriented strategies focused on promoting community involvement, inclusive decision-making, equity, socio-ecological civility, long-term integrative planning, and responsibility through stewardship. However, there are potential limitations that will require future research to examine policy outcomes associated with sustainability uptake. The ICSP approach must still overcome the issues relating to lack of regulatory authority and the incorporation of policies based on popular trends rather than empirical evidence.     

Rapid determination of residues of pesticides in honey by µGC-ECD and GC-MS/MS: Method validation and estimation of measurement uncertainty according to document No. SANCO/12571/2013

A simple and straightforward method for simultaneous determination of residues of 13 pesticides in honey samples (acrinathrin, bifenthrin, bromopropylate, cyhalothrin-lambda, cypermethrin, chlorfenvinphos, chlorpyrifos, coumaphos, deltamethrin, fluvalinate-tau, malathion, permethrin and tetradifon) from different pesticide classes has been developed and validated. The analytical method provides dissolution of honey in water and an extraction of pesticide residues by n-Hexane followed by clean-up on a Florisil SPE column. The extract was evaporated and taken up by a solution of an injection internal standard (I-IS), ethion, and finally analyzed by capillary gas chromatography with electron capture detection (GC-µECD). Identification for qualitative purpose was conducted by gas chromatography with triple quadrupole mass spectrometer (GC-MS/MS). A matrix-matched calibration curve was performed for quantitative purposes by plotting the area ratio (analyte/I-IS) against concentration using a GC-µECD instrument. According to document No. SANCO/12571/2013, the method was validated by testing the following parameters: linearity, matrix effect, specificity, precision, trueness (bias) and measurement uncertainty. The analytical process was validated analyzing blank honey samples spiked at levels equal to and greater than 0.010 mg/kg (limit of quantification). All parameters were satisfactorily compared with the values established by document No. SANCO/12571/2013. The analytical performance was verified by participating in eight multi-residue proficiency tests organized by BIPEA, obtaining satisfactory z-scores in all 70 determinations. Measurement uncertainty was estimated according to the top-down approaches described in Appendix C of the SANCO document using the within-laboratory reproducibility relative standard deviation combined with laboratory bias using the proficiency test data.     

城市居民生活能源消费研究进展综述

近十年来中国城市消费领域能耗年增长率已达到7.4%,超过中国总能耗量5.9%的年增长率。随着中国逐渐完成工业化进程,其工业用能将呈现增速放缓甚至总量减少的趋势,而居民生活及交通能源需求将随着人民生活水平提高而稳步增长,最终呈现总量与比重逐渐增加的态势。城市居民活动与其能源消费的定量化分析已成为当前多学科的研究热点。本文以家庭室内和室外直接能源消费作为研究对象,对城市居民生活能耗的影响因素、能源足迹核算方法、时间-室内能耗模拟,及空间-交通-能源耦合模拟等关键问题的研究进展进行综述。研究发现,第一,家庭能源消费属于派生性需求,不同的时间利用方式会产生能源消费水平和结构上的差异,但现有研究较少从时间及活动链分析角度展开。第二,由于家庭预算及时间约束的存在,室内外能源消费行为密切相关,但少有研究对上述两个城市生活部门的能源消费进行整体性分析核算。第三,基于活动的建模方法可以提供一种将居民室内外用能行为进行整合的分析框架。最后对今后该领域的研究开展进行了展望:第一,从活动分析和时间利用视角,建立自下而上的居民室内外用能活动仿真模型,在更小的时间和空间尺度模拟家庭能源需求,识别家庭能耗的主要来源、控制的重点人群、时段和区域,指导能源政策制定;第二,深入剖析能源回弹效应产生的决策机理,以及怎样的政策或政策组合可以有效减少回弹;第三,将社会网络分析引入居民生活能耗研究,更加全面理解影响家庭用能行为的机制,为家庭能源消费管理提供新思路。     

雷达定量估测降水技术在三峡流域面雨量估算中的应用

利用完全覆盖三峡流域的3部多普勒天气雷达探测资料,并结合三峡流域周边水文自动站实时观测资料,集成多种定量降水估算方法,对三峡流域进行面雨量估算。结果表明：这种方法在一定程度上弥补了传统利用自动站观测资料采用插值方法计算流域面雨量中由于自动站观测资料时空分辨率不足的缺点,提高了流域面雨量的估算精度,从而更好的为三峡水资源利用和洪峰预报提供重要参考