淀山湖沉积物碳、氮、磷分布特征与评价

淀山湖为黄浦江上游水源保护区,为了控制其富营养化趋势,在淀山湖影响区内实施了一系列外源污染控制措施。近年来,淀山湖水质持续改善,但每年仍有不同程度蓝藻水华暴发。为进一步探讨淀山湖水华暴发的机理,本研究对淀山湖沉积物进行了调查研究,分析了沉积物TOC、TN、TP时空分布特征。结果表明：在空间分布上,受来水与北部围网养殖影响及水体自净作用影响,淀山湖沉积物中营养物西北部高,东部低,进水口附近沉积物营养物浓度显著高于湖心及出水口。在垂直分布上,受航道回淤影响,D1与D4样点营养盐垂直分布规律不显著,其它样点均表现出随水深度增加营养盐显著降低的趋势。与20多a前相比,淀山湖沉积物营养盐存在明显的富集作用,沉积物氮、磷含量大幅上升。以有机指数与TP含量进行评价,淀山湖表层沉积物均属于重污染状态,且北部湖区污染程度较高。预测淀山湖外源污染得到控制以后,沉积物中营养物将对水体水质构成威胁     

基于多速率卡尔曼滤波方法的位移和加速度数据融合

为了尽可能地利用加速度传感器和位移传感器中的冗余信息、提高振动实测数据的精度,将结构同一位置的加速度和位移观测值进行数据融合处理,提出了一种基于维纳过程加速度模型的多速率卡尔曼滤波数据融合方法。首先给出了基于维纳过程的多速率卡尔曼滤波数融合模型;然后在加速度和位移观测值的基础上,通过多速率卡尔曼滤波数据融合得到位移、速度以及加速度的的最优估计,并对融合结果进行卡尔曼平滑处理,进一步提高了状态估计准确性;最后数值分析了不同噪声水平和采样频率比对融合算法的影响,而且与相关文献的结果作了对比分析。结果表明,本文方法合理有效且具有一定的噪声鲁棒性。     

有色金属行业CO2排放估算方法研究

通过对国内外有色金属行业温室气体排放估算方法研究现状的分析,将联合国政府间气候变化专门委员会(IPCC)温室气体排放清单指南、国际有色行业协会和环境科学研究中的一些常用算法,总结归纳应用于有色金属行业温室气体的排放量估算,从估算方法和结果上分析各种方法的优缺点和使用条件。以原铝生产CO2排放估算为例,对有色金属温室气体排放进行实证分析,为有色金属行业温室气体排放估算提供参选方法,促进有色金属工业的节能减排。     

电-袋复合除尘器功效探究

针对当前认为电-袋复合除尘器是一种新的除尘技术的观点,分析探讨了目前国内采用的电-袋复合除尘器的功效,指出电-袋复合除尘器实际为前电后袋式的电-袋结合除尘器,因而存在许多弊端,并不能克服电除尘器和袋式除尘器各自的缺点。     

Integration and integrated approaches to assessment: what do they mean for the environment?

Integration and integrated approaches are increasingly presented as new and superior ways to consider the environment in policy- and decision-making. If used in an uncritical way, this assertion could become a hindrance to good practice and could undermine efforts to defend or improve environmental quality. The aim of this paper is to provide the missing critical perspective through an investigation of the meanings of integration found in recent literature on assessment. This literature represents a broad survey of European (particularly UK) and US critiques of assessment practices, and proposals for better and usually ‘more integrated’ approaches. These critiques and proposals relate to a range of assessment contexts, from relatively technical issues of data handling, to questions of the design, choice and implementation of policy options. This paper also surveys, and contributes to, literature that questions the central goals and assumptions informing assessment practice and environmental governance more widely. Fourteen meanings of ‘integration’ are presented, with a discussion of the potential synergies and conflicts among them, and with environmental objectives. Integration is argued to be a matter of value judgements concerning assessment design in specific historical and social contexts. Far from providing a panacea, integration would appear to create as many challenges as it might resolve in seeking to achieve more sustainable development. Copyright © 2002 John Wiley & Sons, Ltd.     

Individual sensitivity distribution evaluation from survival data using a mechanistic model: implications for ecotoxicological risk assessment

Two main alternatives are typically used to model mechanistically dose-survival relationship in ecotoxicity tests. Effects are related to a concentration of concern, for instance body concentration, and, to account for their differences relative to time-to-death, individuals have either different concentration thresholds for death (“individual tolerance approach”), or equal probability to die, with death occurring randomly (“stochastic death approach”). A general framework to unify both approaches has recently been proposed. We derived a model from this framework to analyse five datasets (daphnids exposed to selenium, guppies exposed to dieldrin and second, third and fourth instars chironomids exposed to copper), by extending the standard stochastic death approach. We showed the possibility to estimate properly the toxicity parameters together with inter-organisms differences of sensitivity for at least one of these parameters (here the threshold for effect). For the daphnids, there was no improvement of using the extended model, which confirms the expected low variability among genetically identical individuals. For all the other datasets, our model outperformed the standard approach without accounting for differences of sensitivity. We estimated coefficients of variations in the distribution of the logarithm of the threshold from 44% to 4% and showed, for chironomids, a decrease of inter-individual differences of sensitivity with the age of the larvae. All standard threshold estimates were close but above the medium value of the distribution in the new approach, which means that a concentration equal to the standard threshold would ultimately result in the death of more than half of the exposed organisms. A more relevant parameter, such as the concentration protecting 95% of the population, would be 2-4 times inferior to the standard threshold.     

常规组合工艺-稳定塘-湿地系统处理印染废水

针对工业园区印染企业产生的印染废水和生活污水,采用独特的"常规组合工艺与‘植物稳定塘-人工湿地系统’联合工艺"对其进行集中统一处理,并考察了运行效果。数据结果表明,系统出水COD、BOD5、SS、色度、NH3-N和TP平均分别为63.2 mg/L、13.8 mg/L、5.0 mg/L、49倍、0.2 mg/L和0.4 mg/L,出水水质达到国家污水综合排放一级标准(GB8978-1996)。该工艺运行稳定,可有效去除废水中的COD、SS和色度,去除率均在90%以上。按日均处理量4×104m3计算,此工艺每年将削减COD排放近30万t。     

真空膜蒸馏和膜吸收及其集成工艺处理高氨氮废水

采用PP中空纤维膜组件,对VMD(真空膜蒸馏)和MA(膜吸收)脱氨过程进行了研究。考察了料液p H值(9.0~11.0)、料液进口温度(20~50℃)对脱氨效率的影响。研究结果表明,VMD和MA脱除率分别达85%和99%以上。料液p H和料液进口温度对VMD脱氨效果的影响较大,提高料液p H和进口温度可以明显提高VMD的脱氨效率;料液p H对MA的脱氨效率影响较为显著。对2种膜工艺进行了技术集成,利用该集成工艺可达到99.96%以上的氨去除率,出水可达标排放,并且可以有效防止硫酸铵的二次污染。     

利用太阳能驱动的一体化氧化沟的运行方式

污水处理的高能耗和新能源利用已引起人们的关注,本文根据太阳光照强度的周期变化和农村污水昼夜排放量悬殊的特征,提出了一种新型的利用无蓄电池太阳能光伏系统驱动的污水生物处理系统,可有效降低太阳能光伏系统的成本。生物反应器是一个双沟式一体化氧化沟。按照启动的用电设备的数量,一体化氧化沟具有5种运行方式。在不同的运行方式下,一体化氧化沟的内沟和外沟具有不同的功能,其中运行方式3到运行方式5对污染物去除效率最高。采用阶梯型电量输出模式,可以充分利用太阳能,并保障一体化氧化沟的高效运行时间。在160 d的连续运行实验中,COD、氨氮、总氮和总磷的平均去除率分别为87.8%、98.4%、68.7%和80.3%。证明无蓄电池太阳能光伏系统驱动污水生物反应器处理农村分散污水是可行的。     

Multiple batch extraction test to estimate contaminant release parameters using a Bayesian approach

Industrial activities produce vast amounts of weakly contaminated materials which are commonly reused as filling materials on natural ground. There is a strong demand to define guidelines for the application of these materials, to estimate the leaching potential of contaminants from the materials, and to assess the potential hazard for groundwater pollution. We present a multiple batch experiment, where measurements of liquid-phase concentrations at varying liquid/solid ratios are used to estimate the total mass of contaminant that can be extracted from a contaminated material with a mild extractant like water. Furthermore, the experiment yields estimates of the isotherm describing the partitioning of the contaminant between the solid and liquid phases, and a concentration that might be expected under soil hydraulic conditions representative for the field situation. Model parameters are estimated from liquid-phase concentrations within a Bayesian framework by applying the Shuffled Complex Evolution Metropolis Algorithm (SCEM-UA), an efficient Markov Chain Monte Carlo sampler. A sensitivity analysis and inversions of synthetically generated data corrupted with noise show the general suitability of the proposed method. An uncertainty analysis for model parameters and model predictions shows the expected accuracy of the estimates. An application to concentration measurements obtained from a multiple batch extraction test illustrates the applicability of the approach for a real situation.