Using thermal analysis with kinetic calculation method to assess the thermal stability of 2-cyanopropan-2-yliminourea

Azo compounds, which are commonly used as initiators and blowing agents, are also typical self-reactive materials capable of undergoing runaway reaction during storage and transportation, which can cause severe fires and accidents. To ensure the thermal safety of azo compounds in the process, transportation, and applications, this study investigated 2-cyanopropan-2-yliminourea, which can also be called V-30. First, thermal decomposition characteristics under the non-isothermal conditions were obtained using differential scanning calorimetry. Second, the collected data were combined with a mathematical model to evaluate the primary thermal hazard during the process for V-30. Then, based on a heat-transfer model, the self-accelerating decomposition temperature (SADT) was extrapolated for consideration and non-consideration of consumption of chemicals. The results showed that SADT of V-30 was less than 80 °C. Therefore, it is essential to avoid a temperature beyond SADT or the cooling system will fail. The influence of consumption was also considered for SADT in this study.     

HazMat transportation safety assessment: Analysis of a “Viareggio-like” incident in the Netherlands

Relevant safety issues are associated with hazardous materials transportation, especially when transport routes cross populated areas. On March 6th, 2015, a passenger train collided with the last rail car of a freight train in Tilburg, the Netherlands. The last car contained 50 t of liquefied 1,3-butadiene. As a result of the collision, the last car showed deformation; a small leakage occurred but fortunately with no relevant consequences. However, extremely severe consequences could have happened, such as in the rail accident that occurred in Viareggio, Italy in 2009. In this work, the case of Tilburg was firstly outlined and explored by qualitative methods, in order to identify possible realistic final scenarios that could have happened. Second, the potential consequences of the identified scenarios were estimated through conventional integral model for physical effects evaluation. Comparison with the Viareggio case was also shown in order to support the discussion of the results obtained. Finally, lessons learned after the incident, policy making considerations, and indications for the risk mitigation of hazardous materials transportation are given.     

特殊环境中气载放射性物质的监测研究

本文对特殊环境下气载放射性物质中β放射性气体以及β放射性气溶胶做以实验,并根据后期的实验结果进行分析,详细探讨两者的测量结果,希望能为相关人士提供有效参考。     

基于双层规划的应急物资调配研究

为在突发性自然灾害发生后的黄金救援时间内,使各应急物资调配中心的物资在最短时间内高效地运往各受灾点,最大程度地平衡受灾程度不同的受灾点群众对应急物资救援的心理满意度,构建以应急物资救援时间最短为目标的上层模型;通过借鉴前景理论量化受灾群众的心理满意度,在考虑各受灾点对有限应急物资存在竞争关系的基础上,建立下层非合作博弈模型;设计遗传算法求解上层模型、改进粒子群算法求解下层模型的层次混合算法。结果表明:构建的多应急物资调配中心多受灾点的非线性整数双层规划模型,使应急物资的调配具有时效性,且更加客观地衡量各灾点物资调配的公平合理性,该模型为应急物资调配研究提供借鉴与参考。     

防灭火泡沫流体在采空区高位倾斜裂隙通道中的扩散研究

防灭火泡沫材料是1种新型的防灭火材料,对高位倾斜裂隙火灾的降温隔热、充填加固具有很好的应用性能。为了了解高位倾斜裂隙通道中泡沫流体的扩散规律,通过理论推导得出不同裂隙倾角和方位角下浆体2端面压力差随时间的变化方程式,以理论公式为基础进行修正,提出了泡沫流体的扩散规律函数式,并通过用其他实验测点进行误差对比分析。研究结果表明:误差均在允许的范围之内,证明拟合出的函数式具有普遍适用性,可以为大采空区隐蔽高温火源点的防治提供理论支持。     

一种早强型注浆封孔材料的制备与性能研究

针对矿井复杂环境对封孔材料使用性能提出的要求,通过引入２-丙烯酰胺基-２-甲基丙磺酸（AMPS）复合三乙醇胺（TEA）作为有机早强组分,氯化钠（NaCl）、硫酸钠（NaSO4）为无机早强组分,模拟井下高湿环境,,通过正交试验并利用热失重分析（TG）、X射线衍射分析（XRD）及扫描电子显微镜（SEM）等研究手段考察了早强剂的制备与性能。研究结果表明:当掺量为氯化钠0.5%,硫酸钠0.5%,三乙醇胺0.05%,AMPS1.0%时,早强效果最显著。封孔材料1 d抗压强度为5.5 MPa,3 d抗压强度为9.7 MPa,7 d抗压强度为13.9 MPa,分别比基准组强度提高了323%,137%和167%。     

The Country,the City,and the Corporation: Rio Tinto Kennecott and the Materiality of Corporate Rhetoric

Contributing to extant discourses about corporate environmental advocacy, this paper argues that corporations can embed discursive rhetorical strategies in material places and spaces. This argument contributes to environmental communication by bridging divisions between discursive and materialist approaches to corporate rhetoric. Corporate materiality is realized in the study of Rio Tinto Kennecott (RTK) at places of corporate community where RTK enunciates a dominant environmental discourse about the necessity of the Bingham Canyon Mine through strategies such as the technological shell game, the hypocrite's trap, and corporate heterotopia, which are made manifest materially alongside cultural values such as epistemic trust, technological progress, community, and home. Using participatory critical rhetoric as a methodology, I analyse RTK's material rhetoric at the Natural History Museum of Utah, the Rio Tinto Soccer Stadium, and the Daybreak suburban community. This case study reveals that corporations are assemblages that assert many different, and sometimes competing, arguments that can deflect environmental criticism, materially.     

硅胶复合材料吸附重金属汞的研究进展

针对高毒性、易累积的重金属汞污染物,介绍了对硅胶基底材料进行化学改性的方法,从液相和气相两方面详述了硅胶复合材料(包括有机官能团改性硅胶材料和无机磁性硅胶复合材料)在汞吸附分离领域的研究和应用进展,分析了现有研究的不足之处,并对该领域未来的研究方向提出了建议。指出,研制出高效、高选择性、高稳定性、易回收的汞吸附剂是治理工业废水和燃煤烟气中汞污染的关键。     

拉萨站线缆材料短期试验性能分析

分析了线缆材料在拉萨自然环境试验站中1～2年的短周期试验性能变化。线缆高分子材料在土壤环境中性能变化较小,而在大气环境中力学性能有所下降,HDPE耐环境性能、应力开裂性能下降26％;金属在土壤环境中腐蚀较轻。拉萨大气与土壤自然环境对材料的短期腐蚀（老化）作用比较轻微。