广西沿海重要海湾环境承载力评估

以广西沿海的珍珠港、防城港、廉州湾、钦州湾、铁山港5个海湾为例,通过剖析环境承载力的内涵,根据海洋环境的生态服务功能,构建了海洋环境承载力的评估指标体系。从定量表达和评估应用需求出发,构建了基于模法的海洋环境承载力评价模型。根据广西沿海2006～2007年908调查资料,计算了各重要海湾的环境承载力。     

基于历史记录的赤潮灾害危险性区划方法的构建与应用

利用福建省近岸海域1959—2018年的赤潮历史记录数据资料,在地理信息系统(Geographical Information System,GIS)平台下采用核密度估计函数(kernel density estimation)对赤潮历史记录数据中的赤潮发生频次、赤潮发生持续时间、赤潮面积和赤潮藻类毒性等参数进行了空间...     

近岸海域多环芳烃生态系统动力学模型及生境影响

利用生态动力学模型Delf3D,对大连葫芦山湾海域多环芳烃(PAHs)在海洋中的理化及生态动力学过程进行耦合,并以大连葫芦山湾实际监测数据及相关文献资料为基础,确定了一套适用于该近岸海域PAHs生态动力学过程的特征参数,模拟研究了PAHs在近岸海域生态动力学过程.以浮游植物生长率作为指示近岸海域生态系统健康程度的指标,将PAHs含量的数值模拟结果与浮游植物生长率的动力学响应方程相拟合,定量的评估了PAHs对海洋生态系统的影响.结果显示:排污口选址于水深大、流速快、水动力强处,对PAHs污染物扩散、水质改善具有显著作用,反之造成PAHs大规模富集.PAHs富集作用对该湾生境影响较显著,湾顶水动力作用微弱,浮游生物生长率削减度高达18%.ArcGIS分析显示,浮游生物生长率削减程度与PAHs时空分布并不完全一致,体现海湾生态系统的动力复杂性与结构稳固性.     

不同水生植物对富营养化水体释放气体的影响

水体反硝化脱N、温室气体排放以及O2释放过程均是水体生态系统中发生的重要生化反应过程。为了明确不同类型水生植物对这些过程的影响程度,采用自主研发的原位收集水体释放气体装置,于2012年7—8月对滇池草海中自然生长的挺水植物〔菖蒲(Acorus calamus)〕、浮叶植物〔睡莲(Nymhaea tetragona)和荷花(Nelumbo nucifera)〕、漂浮植物〔凤眼莲(Eichhornia crassipes)〕、沉水植物〔狐尾藻(Myriophyllum verticillatum)和轮叶黑藻(Hydrilla verticillata)〕及对照(无植物)区域内释放的N2、CH4、O2、CO2和N2O的规律进行研究。结果表明,各种水生植物生长区及对照区释放气体主要由N2、CH4和O2组成,其余成分主要是CO2和N2O。沉水植物通过光合作用明显促进了水域内O2释放过程,进而提高了水体释放气体的速率及各气体成分通量值。而睡莲、荷花和凤眼莲由于叶片覆盖水面的影响,降低了水体藻类的光合能力,造成该区域水体释放气体的速率中值低于对照区,且各气体成分释放通量值也较低。各区域释放气体中CH4浓度无显著差异(P0.05),菖蒲区释放的气体中N2浓度显著高于对照区(P0.05)。     

山水风景地区控规指标体系构建及指标赋值方法的探析——以千岛湖为例

为解决现行的传统城市地区控制性详细规划（简称控规,后同）对山水风景地区控制不力的现象,以千岛湖地区为例,对山水风景地区控规进行了探讨,对控规指标体系的内容和赋值方法进行了有针对性的扩展和改进。借助GIS等技术手段,对地方性特色元素进行分析,并以此为基础,建立了以”分区控制和分类引导”为核心的控制指标体系。将单一地块进一步划分为亚区域进行分别控制,同时通过图示的方式对不同的建设类型进行引导。根据山水风景地区的建设特征,进一步引入、明确了地表改变率、建筑绝对高度、建筑投影面积等指标的赋值方法,增加了城市设计导引等内容,丰富、强化了山水风景地区控规的内容和可操作性。     

Dispersive liquid–liquid microextraction of cadmium(II) for preconcentration prior to flame atomic absorption spectrometric detection in water

A dispersive liquid–liquid microextraction procedure for cadmium(II) as its 2-(5-bromo-2-pyridylazo)-5-diethylamino-phenol chelate is presented. Carbon tetrachloride and methanol were used as extraction and dispersive solvents, respectively. After phase separation, the preconcentrated-separated cadmium(II) is determined by flame atomic absorption spectrometry with a microinjection technique. The factors which affected the extraction efficiency, i.e. the pH of the sample solution and the volumes of reagent and sample were investigated. The effects of some alkali, alkali earth, and transition metal ions, and of some anions on the recovery of cadmium were also studied. A preconcentration factor of 250 was obtained for a sample volume of 50?mL under optimum conditions. The method was validated by analysis of certified reference materials and applied to some water samples from Turkey.     

天津近海富营养化及环境因子的时空变化特征

基于1995—2010年监测数据,通过Mann-Kendall趋势检验和Kriging空间插值等方法,对天津近岸海域氮磷营养盐、有机污染物和富营养状况的时空变化趋势及其成因进行了分析. 结果表明:在天津近岸海域的48个监测时段中,有81.3%的监测时段处于富营养状态,有39.6%的ρ(DIN)和16.7%的ρ(DIP)超过海洋水质四类标准,有89.6%的ρ(COD_Mn)符合海洋水质一类标准;氮和磷为主要污染物,污染物质量浓度和富营养状态的季节性差异显著. ρ(DIP)、ρ(COD_Mn)和营养状态指数的年际变化主要呈下降趋势,ρ(DIN)呈先下降后显著上升的趋势;ρ(DIN)、ρ(DIP)和ρ(COD_Mn)在空间分布上基本遵循近岸高、远岸低的规律,其中ρ(DIN)和ρ(DIP)均显著呈带状分布,并且基本为北高南低. 防治天津近岸海域水体富营养化的关键是削减丰水期和平水期入海径流的氮负荷以及北部海域入海径流的磷负荷.      

Seasonal and tidal impact on the organic compounds and nutrients distribution in tropical mangroves,Kerala, India

Seasonal changes in the concentration of nutrients and various organic compounds were studied in the waters surrounding mangroves and in the marshy areas of mangroves. Higher amounts of nutrients and organic compounds were observed during low tide. This is due to the remineralisation of plant detritus in this area. High concentration of carbohydrates, proteins, chlorophyll and phosphate were observed during monsoon, which can be attributed to the leaching of plant detritus as well as the land run-off. During pre-monsoon and post-monsoon high tannin and lignin concentration was noted. A 24-hour sampling was also done to study the tidal impact on the concentrations of various organic compounds and nutrients in this ecosystem. Even though a tidal impact was observed, a clear picture was not reported in this study.     

高灵敏光度法在环境水样中无机铬形态分析中的应用

按显色剂分类综述了1997—2002年国内高灵敏光度法(ε′≥1 0×105L·mol-1·cm-1)在环境水样中无机铬形态分析中的应用进展。     

A general process-based mass-balance model for phosphorus/eutrophication as a tool to estimate historical reference values for key bioindicators,as exemplified using data for the Gulf of Riga

This work describes how a general, process-based mass-balance model (CoastMab) for phosphorus for coastal areas may be used as a tool to estimate realistic values of “natural” or preindustrial reference levels of key bioindicators in coastal science, including the Secchi depth, a standard measure of water clarity, the chlorophyll-a concentration, an operational measure of phytoplankton biomass and the concentration of cyanobacteria, a measure of the concentration of harmful algae. The CoastMab-model is an ecosystem model giving monthly predictions to achieve seasonal variations of basin-wide properties. The selected case-study area, the Gulf of Riga, is sensitive to nutrient loading because of its shallowness and low openness towards the Baltic Proper. The morphometry of any coastal area, as given by the size and form parameters, influences all internal processes, such as sedimentation, resuspension, diffusion in water and from sediments to water, biouptake and retention in biota, stratification, mixing and outflow. There has been no mass-balance modeling for nitrogen (N) in this work because empirical data (from the HELCOM database) clearly indicate that the monthly primary production in the Gulf of Riga is regulated by phosphorus (P) – the mean monthly total-N to total-P ratios are well over 7.2 (the Redfield-ratio) and generally higher than 15 for the data used in this study (from 1992 to 2005). At present anthropogenic loads, the average modeled monthly values for Secchi depth, chlorophyll (Chl), cyanobacteria (CB) and total-P (TP) are 3.2 m, 3.8 μg/l, 78 μg/l and 31.3 μg/l, respectively. If 50% of all anthropogenic sources to the Gulf of Riga via rivers, point sources and diffuse sources were to be removed, these values would be 3.6 m, 3.4 μg Chl/l, 63 μg CB/l and 29.1 μg TP/l. If 60% of the anthropogenic phosphorus fluxes to the Baltic Proper were to be omitted and as well as 75% of all direct anthropogenic sources to the Gulf of Riga, the values would be 4.6 m, 2.7 μg Chl/l, 45 μg CB/l and 25.4 μg TP/l. These values represent the “natural” reference levels and it is not realistic to expect that remedial measures would improve the conditions more than that. Using the CoastWeb-model, similar calculations can be made for any given coastal area and the data necessary for such calculations are discussed in this work.