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331.
A new approach for isolation and identification of elecrtophilic mutagens from complex matrix was developed.Thiosulfonic anion was immobilized onto polystyrene beads and used as separation media.Potassium polystyryl-thiosulfonate,prepared from polystyryl- sulfonyl chloride and KHS,was observed to selectively react with model electrophilic mutagens such as alkyl halides,α-chloroketones andα-chloroesters to produce polystyryl-thiosulfonic esters.After separation from other nonreactive organic compounds,the beads then reacted with ethanethiol to produce unsymmetrical ethyl disulfides which are easily detected by GC/MS.For one mutagenic compound,only one unsymmetrical disulfide was found to contain its structure part.Thus,the structure of the parent mutagens could be deduced from that of the unsymmetrical disulfides.The degree of functionaiization of the potassium polystyryl-thiosulfonate resin was 1.11 mmol/g.Its reactivity was discussed and its recycling method was reported here. 相似文献
332.
333.
Hung-Suck Park Eldon R. Rene Soo-Mi Choi Anthony S.F. Chiu 《Journal of environmental management》2008
The Korea National Cleaner Production Center (KNCPC) affiliated to the Korea Institute of Industrial Technology (KITECH) has started a 15 year, 3-phase EIP master plan with the support of Ministry of Commerce, Industry, and Energy (MOCIE). A total of 6 industrial parks, including industrial parks in Ulsan city, known as the industrial capital of South Korea, are planning projects to find the feasibility of shifting existing industrial parks to eco-industrial parks. The basic survey shows that Ulsan industrial complex has been continuously evolving from conventional industrial complexes to eco-industrial parks by spontaneous industrial symbiosis. This paper describes the Korean national policies and the developmental activities of this vision to drive the global trend of innovation for converting the existing industrial parks to eco-industrial parks through inter-industry waste, energy, and material exchange in Ulsan Industrial complexes. In addition, the primary and supportive components of the Ulsan EIP pilot project, which will be implemented for 5 years is elaborated with its schedules and economic benefits. 相似文献
334.
Haruhiro Ino Yoshihisa Matsumoto Ryo Takahashi Kazukiyo Takami Junya Nishino Masaaki Itoh 《Journal of Material Cycles and Waste Management》2008,10(2):129-133
H-ZSM-5 zeolite-supported gallium oxides were studied as aromatization catalysts for polyolefin pyrolysate. The catalysts
were prepared by a conventional physical mixing method with a gallium content of 1.0 and 4.5 wt% and were reduced in flowing
hydrogen at 585°C. To test their activity, a polyolefin sample was pyrolyzed and passed over a heated catalyst layer; the
product was analyzed by gas chromatography/mass spectrometry. A continuous-flow fixed-bed reactor was used for aromatization
of a model gas of polyolefin pyrolysate. For chlorine-free sources at 450°C, the catalyst with only 1.0 wt% gallium exhibited
activity comparable to a gallium silicate catalyst. For chlorine-contaminated sources, the catalyst with 4.5 wt% gallium sustained
catalytic activity for long periods. From the activity test results, it was found that zeolite-supported gallium catalysts
prepared by the physical mixing method are suitable for converting polyolefin into aromatic hydrocarbons. 相似文献
335.
The theoretical concept, “asset specificity,” is applied to real data in the context of Danish nature conservation network
planning in order to produce illustrative examples of an economic measure of the network’s vulnerability to exogenous shocks
to the species composition. Three different measures of asset specificity are quantified from the shadow value of eliminating
a key species from the individual grid cells. This represents a novel approach and a different interpretation of the term,
as it is conventionally used as a qualitative indicator in the transaction cost economics literature. Apart from supplementing
existing cost measures with an indicator of risk associated with investments in protected areas, this study demonstrates how
the estimation and interpretation of various asset specificity measures for geographical areas may qualify policy makers’
choice of policy instrument in conservation planning. This differs from the more intuitive approach of basing policy instrument
choice solely on the rarity of the species in a given area. 相似文献
336.
This study presents a meta-analysis of a collective dataset describing the succession from abandoned fields to semi-natural
grassland and heathland vegetation over the past century. The study objectives were to develop a method for statistical discrimination
between abandoned fields and semi-natural habitats and to analyze the probability that an abandoned field had developed into
a semi-natural habitat. A statistical classification model was developed, based on lists of vascular plants from 2059 plots
from Danish semi-natural grasslands and heathlands, and abandoned fields of varying age. This model was shown to discriminate
effectively between abandoned fields and semi-natural habitats, and it was found to be potentially useful for the detection
of abandoned fields approaching semi-natural vegetation. We suggest that the model may help clarify restoration targets and
assess biological condition in formerly cultivated areas. Statistical modeling revealed that succession age, period of abandonment
and succession trajectory had significant effects on the probability that abandoned fields reached the semi-natural phase.
Our study indicates that restoration projects targeting grassland and heathland should take local species pools and soil fertility
into account.
Nomenclature: Species names follow Flora Europaea (Tutin and others 1964–1993). 相似文献
337.
338.
Mass spectrometry fingerprinting of humic acids extracted from different soils has been carried out using laser desorption/ionization mass spectrometry (LDI-TOF MS). LDI-TOF MS provides characteristic mass spectra fingerprints for the humic acids of different origin. The information given in the fingerprints was evaluated for natural grouping trends in the samples by neural networks computing tools, such as self-organizing feature map (SOFM). This approach is efficient for recognizing patterns in the humic acids samples independently of their characteristic variability; variability characterizing natural products such as humic substances. The use of multi-layer perceptron artificial neural networks gave a successful classification of the samples. 相似文献
339.
根据我国电子废物回收处理的现状,分析存在的问题,并提出相关对策。通过对北京海淀区“电子环保.循环经济”方案,从管理和技术的角度突出了政府推动和市场拉动相结合的方法在建立完善电子废物回收处理链及逐步构建完整IT产业链的重要作用,其思路和做法具有推广价值。 相似文献
340.
水循环周期对生态床内氮形态转化过程的影响 总被引:3,自引:0,他引:3
构建复合生态床修复北方景观水体,通过控制出水循环周期,研究不同循环速率下水体氮在系统内的转换及不同转换过程之间的关系,深入分析复合基质生态床修复景观水的过程及作用机理.结果表明,当循环周期为1 h和1.5 h时,溶解氧经首次循环由7提高至11左右,并始终保持较高水平;C/N由进水时4~6提高至出水时6~10,C/N的升高说明系统中N的相对去除率高于C,循环促进了氮及有机物的去除.出水循环提高了NH+4-N、NO-2-N及TN的去除率, 且循环速率的提高使得硝化作用进行得更加迅速和彻底,补充了氮从系统中去除的好氧反硝化途径.当循环周期为1.5 h和1 h时,NH+4-N与NO-2-N去除过程间的相关系数值分别为0.885 3和0.968 5;NO-2-N与TN去除过程间的相关系数随循环速率加快而增加,最高为0.942 4.当循环速率加快,NH+4-N的氧化与NO-2-N的氧化2个过程间的传递更加迅速, 缩短了氮在系统中的转化途径,且循环速率越快,整个转化越迅速. 相似文献