We designed photoelectrochemical cells to achieve efficient oxidation of rhodamine B (RhB) without the need for photocatalyst or supporting electrolyte. RhB, the metal anode/cathode, and O2 formed an energy-relay structure, enabling the efficient formation of O2– species under ultraviolet illumination. In a single-compartment cell (S cell) containing a titanium (Ti) anode, Ti cathode, and 10 mg·mL–1 RhB in water, the zero-order rate constant of the photoelectrochemical oxidation (kPEC) of RhB was 0.049 mg·L–1·min–1, while those of the photochemical and electrochemical oxidations of RhB were nearly zero. kPEC remained almost the same when 0.5 mol·L–1 Na2SO4 was included in the reactive solution, regardless of the increase in the photocurrent of the S cell. The kPEC of the illuminated anode compartment in the two-compartment cell, including a Ti anode, Ti cathode, and 10 mg·mL–1 RhB in water, was higher than that of the S cell. These results support a simple, eco-friendly, and energysaving method to realize the efficient degradation of RhB.
Fire events are an annual phenomenon in Greece with damages and even casualties, making their understanding and management important. In this paper, we present fire events provided by NASA Fire Information for Resource Management System and place them along a number of spatial types defined by relief and land cover classes. Results demonstrate that the occurrence of fire events is related more to some land cover classes than others. The most important in terms of overall frequency in all types of terrain is ‘Agricultural Areas’, as a result of farming practices that involve fire. The second more important type of areas is ‘Artificial Surfaces’, especially in low lying areas. These events are related to urban growth and sprawl and are very often a direct outcome of speculation practices with land properties, encouraged by the absence or poor implementation of spatial planning. 相似文献
Recent experience of hurricanes, particularly in the southeast United States, has heightened awareness of the multifaceted nature of and the challenges to effective disaster relief planning. One key element of this planning is providing adequate shelter at secure locations for people who evacuate. Some of these individuals will have ‘special needs’, yet there is little research on the relationship with shelter space. This study designed a geographic information systems‐based network optimisation methodology for the siting of special needs hurricane relief shelters, with a focus on the transportation component. It sought to find new locations for shelters that maximise accessibility by vulnerable populations, given capacity constraints, concentrating on the ageing population. The framework was implemented in a medium‐sized metropolitan statistical area in the state of Florida where data suggest a possible deficit in special needs shelter space. The study analysed options for increasing special needs shelter capacity, while considering potential uncertainties in transportation network availability. 相似文献