微波加热对活性炭表面基团及其对SO2吸附性能的影响

采用了微波加热技术,通过在不同微波功率和辐射时间条件下对不同粒径活性炭进行改性,研究了改性前后活性炭的表面化学基团、元素组成的变化,以及对SO2吸附性能的影响.结果表明,经过微波改性后活性炭的SO2吸附性能大为提高,微波功率是影响改性活性炭脱硫性能的主要因素.活性炭经微波热处理后,酸性基团发生分解,表面含氧量减少,碱性特征增强,是吸附性能增加的主要原因之一.     

Traffic congestion and ozone precursor emissions in Bilbao (Spain)

GOAL. SCOPE. BACKGROUND: In urban environments, the measured levels of ozone are the result of the interaction between emissions of precursors (mainly VOCs and NOx) and meteorological effects. In this work, time series of daily values of ozone, measured at three locations in Bilbao (Spain), have been built. Then, after removing meteorological effects from them, ozone and traffic data have been analyzed jointly. The goal was to identify traffic situations and link them to ozone levels in the area of Bilbao. METHODS: To remove meteorological effects from the selected ozone time series, the technique developed by Rao and Zurbenko was used. This is a widely used technique and, after its application, the fraction obtained from a given ozone time series represents an ozone forming capability attributable to emissions of precursors. This fraction is devoid of any meteorological influence and includes only the apportion of periodicities above 1.7 years. In the case of Bilbao, the ozone fractions obtained at three locations have been compared on that time scale with traffic data from the area. RESULTS AND DISCUSSION: For the 1993-1996 period, a regression analysis of the ozone and traffic fractions due to periodicities above 1.7 years (long-term fractions), shows that traffic is the main explanatory factor for ozone with R2 ranging from 0.916 to 0.996 at the three locations studied. Analysis of these longterm fractions has made it possible to identify two traffic regimes for the whole area, associated to different profiles of ozone forming capability. The first one favors low ozone forming capability, and is associated with a situation of fluent traffic. The second one shows high ozone forming capability and represents congestion. Joint analysis of raw data of ozone and traffic do not show any clear pattern due to the strong masking effects that seasonal-meteorological effects (mainly radiation) have on the measured ozone signal. If only immission data of ozone are available, as in this case, a comparison between ozone and traffic can only be made on the long-term time scale, since that is the only fraction embedded in the ozone time series that can exclusively be attributed to emissions of precursors. This fact stresses the need to study the different fractions embedded in the time series of ozone measured levels separately. CONCLUSION: Though the coefficients obtained in the regression are only valid for the 1993-1996 period, these traffic regimes represent long-term targets (congestion or fluent traffic) that can inspire policies for a joint management of the traffic and pollution by ozone in the area of Bilbao beyond that period. RECOMMENDATIONS AND OUTLOOK: The results of this work show the need of a joint management of ozone and traffic in Bilbao. Since an accurate knowledge of traffic was not available, the use of emission factors to relate traffic and actual ozone levels has not been possible. For this reason, this study has focused on the long-term fractions of traffic and ozone. In the future, if a more accurate knowledge of traffic is available, it will be possible to find relationships between traffic and ozone on all time scales.     

活性炭固定床操作参数的优化

研究了操作参数对活性炭固定床处理有机废气的影响。温度升高，吸附容量下降。湿度的存在会减少活性炭对有机物的吸附容量。适当的操作气速为0.1-0.5m/s，在此范围内，气速与压降在对数坐标上呈线性关系。     

染整废水处理工程设计

采用“生物接触氧化 +混凝气浮 +生物炭”工艺处理染整废水 ,COD去除率可达到 90 %以上 ,工程实践表明 ,该工艺处理效果好 ,运行稳定 ,投资省 ,处理后出水可达标排放     

活性炭-双氧水催化氧化法深度处理DSD酸废水的研究

以活性炭为催化剂、H2O2为氧化剂的催化氧化技术来处理DSD酸母液树脂吸附出水。处理效果比单纯的活性炭吸附或H2O2氧化要好的多。在温度25℃，线速度0．10m／h，pH3．50，H2O2添加量0．35％，处理500mL水样后，脱色率达到90%以上，TOC去除率达到40．0％以上。     

炭素焙烧炉沥青烟净化处理

采用干式静电除尘技术,对炭素焙烧炉排放的含有烟尘、沥青烟的工业废气进行处理,达到既能高效净化有害气体,又能降低资金投入。处理后的各项指标为:烟尘排放浓度=20.0mg/m3,沥青烟排放浓度=14.2mg/m3,苯并(a)芘排放浓度=0.054×10-3mg/m3,所有污染物均达到排放标准。     

A microcosm approach to assessing the effects of earthworm inoculation and oat cover cropping on CO2 fluxes and biological properties in an amended semiarid soil

We designed a microcosm experiment to assess the influence of inoculation with Eisenia foetida earthworms and the establishment of an Avena sativa cover crop on biological (enzyme activities and labile carbon fractions) soil quality indicators in a soil treated with a composted organic residue, and to determine the contribution of these treatments to carbon dioxide emissions from the soil to the atmosphere of the microcosm. The microcosms were incubated for 53 days under 28 °C/18 °C day/night temperatures. The addition of earthworms and the planting of A. sativa increased dehydrogenase activity of compost amended soil by about 44% after 23 days of incubation. The metabolic potential, calculated as the ratio dehydrogenase activity/water soluble C, was higher in the compost amended soil planted with A. sativa. The highest total amount of CO₂–C evolved occurred in the soil treated with composted residue and earthworms (about 40% of the total amount of CO₂ evolved came from earthworm activity). The planting of A. sativa increased the decomposition rate constant of organic matter in the amended soil but decreased the potentially mineralizable C pool. In conclusion, the establishment of an A. sativa cover crop and the addition of E. foetida to a degraded agricultural soil treated with composted residue were effective treatments for improving the biological and biochemical quality and the metabolic potential of the soil.     

水处理工艺去除藻毒素的效果探讨

探讨了饮用水处理的各工艺过程对藻毒素的去除作用,并根据前期已进行的实验对各工艺的优化组合进行了讨论,认为以气浮代替沉淀,并附之以粉末活性炭吸附预处理可有效地去除藻毒素;对没有条件改造沉淀池的水厂可暂时采用预氯化和粉末活性炭吸附组合的工艺也可达到较好的效果;对生物预处理工艺进行适当的强化,可达到对有机物、藻类、藻毒素等物质的有效去除.     

四氯化碳的生产与应用及其淘汰策略

四氯化碳是一种消耗臭氧层物质,其生产和消费都面临着严峻的淘汰形势.简要叙述了四氯化碳的生产技术,以四氯化碳为原料生产大宗化学品和精细化学品的转化技术,四氯化碳作为化工助剂在我国的应用情况以及相应的淘汰方法和技术进展.