全文获取类型
收费全文 | 1568篇 |
免费 | 135篇 |
国内免费 | 361篇 |
专业分类
安全科学 | 128篇 |
废物处理 | 100篇 |
环保管理 | 149篇 |
综合类 | 779篇 |
基础理论 | 283篇 |
污染及防治 | 266篇 |
评价与监测 | 287篇 |
社会与环境 | 27篇 |
灾害及防治 | 45篇 |
出版年
2024年 | 11篇 |
2023年 | 13篇 |
2022年 | 36篇 |
2021年 | 45篇 |
2020年 | 41篇 |
2019年 | 57篇 |
2018年 | 42篇 |
2017年 | 41篇 |
2016年 | 79篇 |
2015年 | 76篇 |
2014年 | 89篇 |
2013年 | 188篇 |
2012年 | 127篇 |
2011年 | 154篇 |
2010年 | 103篇 |
2009年 | 114篇 |
2008年 | 98篇 |
2007年 | 114篇 |
2006年 | 115篇 |
2005年 | 81篇 |
2004年 | 78篇 |
2003年 | 73篇 |
2002年 | 46篇 |
2001年 | 39篇 |
2000年 | 39篇 |
1999年 | 28篇 |
1998年 | 31篇 |
1997年 | 32篇 |
1996年 | 23篇 |
1995年 | 20篇 |
1994年 | 11篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有2064条查询结果,搜索用时 93 毫秒
151.
针对曝气沉砂池小试装置模型,通过配砂实验对沉砂池除砂率进行统计分析,研究曝气强度与HRT对沉砂池除砂率的影响。实验结果表明,不同曝气强度下,随着HRT变化,除砂率逐渐上升,并最终趋于平衡状态;不同HRT下,曝气强度与除砂率近似呈现一定的线性关系,且随着曝气强度的增大,除砂率降低;在HRT小于1min时,砂粒的运行路径和沉降时间缩短,不利于砂粒的去除;在HRT大于1min时,其中1、3和4min,随着气水比的增加除砂率降低幅度相对较小,曝气所引起的横向环流在一定程度上有利于砂粒的沉降,而HRT为2min时,除砂率降幅却很大,这与砂粒在曝气沉砂池池体断面分布有关,即断面处旋转流速和水平流速的大小变化将影响砂粒的运动;相比曝气强度,HRT对除砂率的影响较大。 相似文献
152.
《Environmental Forensics》2013,14(4):313-317
Supercritical fluid extraction (SFE) was investigated to evaluate its potential for obtaining high quality chromatographic fingerprints from soils encountered in environmental investigations. While the volatile and semivolatile fractions of light nonaqueous phase liquid (LNAPL) samples can be “fingerprinted” in a single chromatographic run, it is commonly not possible to obtain samples of LNAPL in the locations of interest. For this and other reasons, it was desirable to develop this method (SFE) of soil extraction, which allows chromatographic fingerprinting of the same quality routinely obtained with LNAPL so that environmental forensic investigations could be extended to areas beyond those containing LNAPL in monitoring wells. In this study, SFE was compared to conventional dichloromethane extraction. Both artificially spiked soil and soil from petroleum release sites were tested. Since water can be a problem when using the SFE method, particular attention was given to handling soils with high moisture contents. The SFE extracts showed excellent retention of low molecular components, including pentanes. Gas chromatography of SFE extracts yielded molecular distributions that showed no significant bias toward either low or high molecular weight components. These results show that SFE can be used to obtain an unbiased, single-run chromatographic “fingerprint” of both volatile and semivolatile hydrocarbons in contaminated soil samples. 相似文献
153.
154.
155.
Factors controlling the transport of geogenically-derived arsenic from a coastal acid sulfate soil into downstream sediments are identified in this study with both solid-phase associations and aqueous speciation clearly critical to the mobility and toxicity of arsenic. The data from both sequential extractions and X-ray adsorption spectroscopy indicate that arsenic in the unoxidised Holocene acid sulfate soils is essentially non-labile in the absence of prolonged oxidation, existing primarily as arsenopyrite or as an arsenopyrite-like species, likely arsenian pyrite. Anthropogenically-accelerated pedogenic processes, which have oxidised this material over time, have greatly enhanced the potential bioavailability of arsenic, with solid-phase arsenic almost solely present as As(V) associated with secondary Fe(III) minerals present. Analyses of downstream sediments reveal that a portion of the arsenic is retained as a mixed As(III)/As(V) solid-phase, though not at levels considered to be environmentally deleterious. Determination of arsenic speciation in pore waters using high performance liquid chromatography/Inductively Coupled Plasma-Mass Spectrometry shows a dominance of As(III) in upstream pore waters whilst an unidentified As species reaches comparative levels within the downstream, estuarine locations. Pore water As(V) was detected at trace concentrations only. The results demonstrate the importance of landscape processes to arsenic transport and availability within acid sulfate soil environments. 相似文献
156.
A new sample treatment method for the determination of four common booster biocides (Diuron, TCMTB, Irgarol 1051 and Dichlofluanid) in harbour sediment samples has been developed that uses liquid chromatography-tandem mass spectrometry (LC-MS/MS) after microwave-assisted extraction, followed by clean-up and a solid phase extraction preconcentration step (MAE-SPE). The effects of different variables on MAE-SPE were studied. The recoveries obtained were greater than 75%, and the relative standard deviation was less than 7%. The detection limits ranged between 0.1 and 0.3 ng g−1. The developed methodology was successfully applied to the evaluation of the presence of booster biocides in sediment samples from different harbours and marinas of Gran Canaria Island (Canary Islands, Spain). 相似文献
157.
文中采用江苏盐城滩涂响水到滨海一带的滩涂土壤样品,利用索氏提取法提取、硅胶柱净化、高效液相色谱法分离检测土壤样品中的多环芳烃(PAHs),并用优化洗脱程序对滩涂土壤中PAHs的含量进行了测定。结果表明:11个滩涂土壤样品中检出萘、苊烯、菲、蒽、荧蒽、芘六种PAHs,其含量较低,说明该段滩涂土壤尚未受到多环芳烃的污染。 相似文献
158.
采用高效液相色谱-串联质谱(HPLC-MS/MS)检测,建立了地表水中13种药物及个人护理品的测定方法。水样用盐酸与氢氧化钠溶液调p H值至7.0左右,过固相萃取小柱进行富集,用14 m L甲醇洗脱。以C18柱为分离柱,0.01%甲酸的甲醇-0.01%甲酸水溶液为流动相,目标物在10 min内分离,在0.50~250μg/L范围内,13种化合物峰面积与内标物质峰面积之比与质量浓度的线性关系良好(0.99),检出限在0.05~0.5 ng/L范围内。基质加标实验结果表明,13种化合物在水中的回收率分别在56.2%~123.2%之间(加标水平5 ng/m L)和58.0%~107.8%(加标水平50 ng/m L),相对标准偏差在1.60%~19.9%(n=6)之间。应用该方法测定了从2条纳污河流采集的10份水样,结果表明,除美托诺尔和普洛萘尔未被检出外,其余11药物的检出频率在30%~100%之间。在13种目标物质中,咖啡因的检测浓度最高达287.5ng/L,舒必利次之,为277.5 ng/L。本方法快速、准确,适用于地表水中PPCPs类的快速测定。 相似文献
159.
针对绿藻,采用超声波提取,以荧光激发-发射波长差216nm,建立了同步荧光法测定绿藻叶绿素a含量的新方法,其线性范围为0.02~1.25 mg/L,检出限为1.6ug/L,加标回收率在97.0%~104%之间。与分光光度法测定叶绿素a的对比试验结果表明,两者无显著性差异,但该方法具有快速、灵敏,其他常见色素不干扰测定的优点,能够满足供水中绿藻叶绿素a含量快速检测的需要。 相似文献
160.
苯甲地那铵是一种广泛使用的苦味剂,近年来被发现在欧洲水体中普遍存在。建立灵敏可靠的环境样品前处理分析方法对评价其环境行为具有重要意义。通过优化关键前处理过程参数,建立了水中苯甲地那铵的固相萃取-超高效液相色谱串联质谱分析方法,系统考察了该方法的准确度、精密度、基质效应、检出限以及线性范围。研究表明:当调节水样pH至8以上,采用混合型阳离子交换小柱(200 mg, 3 mL)富集水样,采用含体积分数2%甲酸的甲醇溶液洗脱时,该方法可获得最佳回收率;纯水和环境水样中加标回收率分别为97%~105%和89%~119%,相对标准偏差小于7%;基质效应均在24%以内;方法检出限为0.07 ng/L,线性范围为0.01~50μg/L。该方法可用于环境水体中苯甲地那铵的痕量检测。 相似文献