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981.
Two Gram (+) bacterial strains, BSB6 and BSB12, showing resistance and potential for Se(IV) reduction among 26 moderately halotolerant isolates from the Bhitarkanika mangrove soil were characterized by biochemical and 16S rDNA sequence analyses. Both of them were strictly aerobic and able to grow in a wide range of pH (4-11), temperature (4-40 °C) and salt concentration (4-12%) having an optimum growth at 37 °C, pH ∼7.5 and 7% salt (NaCl). The biochemical characteristics and 16S rDNA sequence analysis of BSB6 and BSB12 showed the closest phylogenetic similarity with the species Bacillus megaterium. Both the strains effectively reduced Se(IV) and complete reduction of selenite (up to 0.25 mM) was achieved within 40 h. SEM with energy dispersive X-ray and TEM analyses revealed the formation of nano size spherical selenium particles in and around the bacterial cells which were also supported by the confocal micrograph study. The UV-Vis diffuse reflectance spectra and XRD of selenium precipitates revealed that the selenium particles are in the nanometric range and crystalline in nature. These bacterial strains may be exploited further for bioremediation process of Se(IV) at relatively high salt concentrations and green synthesis of selenium nanoparticles. 相似文献
982.
Wölz J Grosshans K Streck G Schulze T Rastall A Erdinger L Brack W Fleig M Kühlers D Braunbeck T Hollert H 《Chemosphere》2011,85(5):717-723
Bankside groundwater is widely used as drinking water resource and, therefore, contamination has to be avoided. In the European Union groundwater protection is explicit subject to Water Framework Directive. While groundwater pollution may originate from different sources, this study investigated on impacts via flood events.Groundwater was sampled with increasing distance to the river Rhine near Karlsruhe, Germany. Samples were HPLC-MS-MS analyzed for the river contaminant carbamazepine to indicate river water infiltration, giving permanent presence in 250 m distance to the river (14-47 μg L−1). Following a flood event, concentrations of about 16-20 μg L−1 could also be detected in a distance of 750 m to the river. Furthermore, estrogenic activity as determined with the Yeast Estrogen Screen assay was determined to increase up to a 17β-ethinylestradiol equivalent concentration (E-EQ) = 2.9 ng L−1 near the river, while activity was initially measured following the flood with up to E-EQ = 2.6 ng L−1 in 750 m distance. Detections were delayed with increasing distance to the river indicating river water expansion into the aquifer.Flood suspended matter and floodplain soil were fractionated and analyzed for estrogenic activity in parallel giving up to 1.4 ng g−1 and up to 0.7 ng g−1, respectively. Target analysis focusing on known estrogenic active substances only explained <1% of measured activities.Nevertheless, river water infiltration was shown deep into bankside groundwater, thus, impacting groundwater quality. Therefore, flood events have to be in the focus when aiming for groundwater and drinking water protection as well as for implementation of Water Framework Directive. 相似文献
983.
Quantification of nitrate leaching from German forest ecosystems by use of a process oriented biogeochemical model 总被引:1,自引:0,他引:1
Kiese R Heinzeller C Werner C Wochele S Grote R Butterbach-Bahl K 《Environmental pollution (Barking, Essex : 1987)》2011,159(11):3204-3214
Simulations with the process oriented Forest-DNDC model showed reasonable to good agreement with observations of soil water contents of different soil layers, annual amounts of seepage water and approximated rates of nitrate leaching at 79 sites across Germany. Following site evaluation, Forest-DNDC was coupled to a GIS to assess nitrate leaching from German forest ecosystems for the year 2000. At national scale leaching rates varied in a range of 0–>80 kg NO3–N ha−1 yr−1 (mean 5.5 kg NO3–N ha−1 yr−1). A comparison of regional simulations with the results of a nitrate inventory study for Bavaria showed that measured and simulated percentages for different nitrate leaching classes (0–5 kg N ha−1 yr−1:66% vs. 74%, 5–15 kg N ha−1 yr−1:20% vs. 20%, >15 kg N ha−1 yr−1:14% vs. 6%) were in good agreement. Mean nitrate concentrations in seepage water ranged between 0 and 23 mg NO3–N l−1. 相似文献
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987.
在给水曝气生物滤池内置粉末活性炭,对比分析其对各工艺单元水质净化效果的影响,确定给水曝气生物滤池内置粉末活性炭的作用与最佳投加量,研究表明,给水曝气生物滤池将活性炭截留在滤池内,大幅度提高了粉末活性炭利用率,部分未饱和粉末活性炭通过反冲洗排入后续常规处理系统,作为生物载体仍能够进一步发挥生物强化作用。当粉末活性炭的投加量为8 mg/L时,砂滤出水氨氮、CODMn、浊度和色度均值分别为:0.02 mg/L,1.82 mg/L0,.46 NTU和6度,去除率分别达到99.6%、71.2%、99.1%和80.6%,出水指标达到《生活饮用水卫生标准(》GB5749-2006)和《饮用净水水质标准(》CJ94-2005)规定的标准。与常规工艺相比,投加量降低了20%~60%。 相似文献
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990.
在反复实验的基础上建立了运用Bran+Luebbe AutoAnalyzer 3流动注射分析仪快速测定地表水中总氰化物的分析方法。结果表明,该方法与传统的分光光度法相比,具有自动进样、分析速度快、测定成本低等优点。与经典的分析方法相对照,结果无显著性差异,能够满足大批量地表水监测的要求。在测试系统中引入了恒温槽,进一步提高了测试的精密度和准确度。 相似文献