赤泥中重金属元素的浸出性与结合形态

采用等离子体质谱仪分析了拜耳法赤泥(BRM)和烧结法赤泥(SRM)中Cr,Ni,Cu,Zn,As,Cd,Cs,Pb等8种重金属元素的含量。采用逐级提取的方法分析了BRM和SRM中8种重金属元素的浸出情况和形态分布差异。实验结果表明:SRM中水溶态As的质量浓度达到17.3μg/L,BRM和SRM中可交换态Cr的质量浓度均在2 300μg/L以上,对水环境可能存在潜在危害;两种赤泥中不同形态重金属的浸出率有较大差异,SRM中Ni和BRM中Zn的总浸出率分别在60%和50%以上。     

Tightening the grip: environmental governance under Xi Jinping

In the space of a few years, China’s global image with regard to environmental matters has significantly improved. Particularly since Xi Jinping’s coming-to-power in 2012 China’s reputation in the global climate change regime has improved markedly and it has gained accolades for a new determination to reverse environmental degradation at home. China’s incipient green transformation is partly due to a new actor constellation in environmental governance, a striking feature of which is the prominence of ad hoc campaigns that offer quick results but that may undermine the creation of law-based enforcement mechanisms in the long term. Another development – China’s increasing use of emerging technologies and big data analytics – has given rise to new forms of government-business alliances. These new players and innovative approaches have injected momentum into China’s environmental governance system and suggest that, contrary to conventional wisdom, authoritarian regimes can be responsive to citizen demands under certain circumstances. Yet it remains to be seen whether long-term environmental goals can be met, due to a pervasive lack of accountability, the weakening of civil society and heavy constraints on public participation.     

Environmental policy innovations in China: a critical analysis from a low-carbon city

The Chinese state is squarely ‘back’ in the business of environmental governance with an increasing number of policy innovations or experiments to resolve environmental issues. These have been mostly enacted through the ‘experimentation under hierarchy’ framework, undergirded by compensation-for-performance incentive structures for local agents. Based on on-site ethnography in local China, a critical analysis is presented of low-carbon city policy experiments – one of the most prominent environmental policies introduced in the past decade. Using lessons from the agency theory, it is hypothesized that outcomes of these policy innovations are contingent on different policy dimensions. Although a number of positive outcomes have been achieved in output-oriented dimensions, the fundamental difficulty of specifying all aspects of complex, multidimensional work tasks involved in low-carbon city development has frequently led to policy unmaking. The findings raise important questions about China’s tendency to rely excessively on compensation-for-performance structures to promote environmental policies.     

国家储备物资的属性功能及其作用价值

从全球化、国情和宏观经济运行的现代视角对国家储备物资的实质属性及其功能特征进行深入和系统分析的基础上,揭示了国家储备物资在国家发展、社会稳定和经济建设等方面的必要性及其投入使用的作用原理,对国家储备物资参与国家经济、安全和社会生活的现代价值及其意义进行了研究。研究证明,在应对突发性事件或不确定因素所造成的巨灾和风险时,国家储备物资因其属性功能而不仅具有比较优势,更具有绝对优势;它们的投入和使用对国家政治和经济的稳定,保证民生和国家安全等方面,可以发挥刚性作用与弹性作用。这种功能性的优势及其作用是市场机制不具备的效能,是社会其他资源或力量无法替代的,在经济全球化和现代化发展中,它们是国家实力与核心竞争力的重要成分。     

Analysis for Chemical Characterization of Atmospheric Aerosols Application of X-ray Microprobe System and Double Thin Film Method

The X-ray microprobe system was applied to ultra trace characterization of single Kosa aerosols and non-Kosa aerosols simultaneously collected at Yasaka, Japan and TaeAnn, Korea. We demonstrated remarkable mass increase of heavy metals as well as soil components in individual particles during the Kosa event compared with the non-Kosa period at Yasaka. Backward trajectory analysis suggested that the Kosa samples were in the mixing state of mineral components and anthropogenic heavy elements. Double thin film method was applied to investigate the seasonal change of the mixing states of single sea-salt aerosols associated with chlorine loss due to the heterogeneous reactions between sea-salt particles and acidic gases. It was revealed that the percentages of both chloride-nitrate mixed particles and sulfate-nitrate ones were larger in wintertime than those in summertime and fraction of chloride-nitrate mixed particles increased with an increase of particle size. Comparison between the size-segregated bulk analysis and the single particle analysis demonstrated that remarkable chloride depletion occurred in coarse particles sampled on May in the former analysis, while chloride depletion in coarse particles was not marked in the latter analysis. The discrepancy attributes to the difference of the sampling time between both analyses because significant change of air mass route occurred during the bulk sampling after completion of the single particle sampling.     

Evaluation of fungal potentiality for bioconversion of domestic wastewater sludge

This study was undertaken to screen the filamentous fungi isolated from its relevant habitats (wastewater, sewage sludge and sludge cake) for the bioconversion of domestic wastewater sludge. A total of 35 fungal strains were tested against wastewater sludge (total suspended solids, TSS 1%-5% w/w) to evaluate its potentiality for enhancing the biodegradability and dewaterability using liquid state bioconversion(LSB) process. The strains were divided into five groups i. e. Penicillium, Aspergillus, Trichoderma, Basidiomycete and Miscellaneous, respectively. The strains WWZP1003, SCahmA103, SCahmT105 and PC-9 among their respective groups of Penicillium,Aspergillus, Trichoderma and Basidiomycete played potential roles in terms of separation (formation of pellets/flocs/filaments),biodegradation(removal of COD) and filtration(filterability) of treated domestic wastewater sludge. The Miscellaneous group was not considered due to its unsatisfactory results as compared to the other groups. The pH value was also influenced by the microbial treatment during fermentation process. The filterability of treated sludge was improved by fungal treatment, and lowest filtration time was recorded for the strain WWZP1003 and SCahmA103 of Penicillium and Aspergillus groups respectively compared with other strains.     

加工工业城市——常州市城市生态安全评价

针对常州市生态环境现状,利用"压力-状态-响应(P-S-R)"理论,构建基于城市资源环境压力、资源环境状态和人文环境响应3个类别的城市生态安全评价模型,以常州市2000—2007年发展过程中的人口,经济、环境等相关指标建立的城市生态安全评价体系进行评价,结果表明:常州市的城市生态安全总体水平在中等偏下,多数城市生态指标处于较低水平,影响常州城市生态安全整体水平的提高。利用P-S-R模型对于常州市城市生态建设和城市发展规划具有一定的参考价值。     

煤层条带开采整体安全系数确定方法研究

为评价工程中条带开采方案的煤层整体稳定性,确定开采方案的安全程度,基于强度折减原理,应用FLAC3D数值模拟软件,将工程实际与数值实验相结合,研究煤层条带开采对地表沉陷、围岩变形和破坏的影响,用安全系数对安全程度进行评价。提出条带开采整体失稳的临界状态判断标准为采空区之间及采空区至地表岩体塑性区域连通,并以地表最大沉降和顶板最大位移突然增大作为临界状态判断标准的验证条件,结果表明:应用强度折减原理进行数值模拟确定的条带开采整体安全系数与工程实际相吻合。     

基于突变理论的非常规突发事件下个体行为状态研究

针对非常规突发事件下个体行为状态,考虑物质环境、社会环境和个体属性等因素,建立评价影响个体行为状态的3级指标体系;在分析非常规突发事件下个体行为状态突变特征的基础上,建立非常规突发事件下个体行为状态的尖点突变模型;采用突变级数法对4类非常规突发事件进行实例分析,得到4类突发事件下个体行为状态的影响度。实例表明,不同类型非常规突发事件下个体行为状态的影响度不同;重大自然灾害和公共卫生类型突发事件中个体行为所受影响最大,社会安全事件次之,事故灾难突发事件中最小。     

Levels of Heavy Metals in Karelian Wildlife, 1989–91

The levels of mercury, cadmium, lead, copper, nickel, zinc and iron were determined in samples of liver, kidney, skeletal muscle, heart, lungs and hair of moose (N = 67), reindeer (N = 45), brown bear (N = 18), wild boar (N = 10) and squirrel (N = 18) shot in Karelia from 1989 to 1991 during regular hunting. The highest heavy-metal concentrations were found in livers, kidney, lungs and hair samples. The samples of muscle contained lowest levels of these elements. The tissues of moose, reindeer and brown bear were contaminated with heavy metals to a greatest extent. Lowest levels of toxicants were recorded in wild boar. Results indicate a widespread presence of heavy metal in the environment and in wildlife, which may be linked to acid precipitation. There was no evidence of these elements accumulated to toxic levels, but Karelian public have been informed that the eating of moose liver and kidney would probably result in their exceeding WHO standard weekly intake limit for cadmium.