pH值、硫酸根和温度对钢管管垢中铬释放的影响

以市政供水管网钢管管垢为研究对象,将垢层由外向内分为表层、硬壳层和疏松多孔层.利用SEM、BET、XRD、XPS和分形态提取等技术对预吸附Cr(Ⅵ)前后的各层管垢进行表征和分析,并探究了pH值、SO₄^2-浓度和温度对各层管垢中Cr释放的影响.结果显示,钢管各层管垢的主要成分均为α-FeOOH,吸附性能排序为表层>疏松多孔层>硬壳层,管垢中铁元素大多以三价和二价形式存在,具有一定还原性.Cr(Ⅵ)通过物理和化学吸附富集于管垢,主要以铁锰氧化物结合态存在,表层管垢富集量最大.酸性环境、SO₄^2-浓度和温度的升高均会促进Cr的释放.强酸性条件下表层Cr释放浓度为中性条件下的2.76倍;SO₄^2-浓度增加使各层管垢的Cr释放量增加0.1～0.4倍;温度升高20℃,表层管垢的Cr释放量增加26.74%.     

SIMULATION OF HERBICIDE CONCENTRATIONS IN STORMFLOW FROM FORESTED WATERSHEDS1

The breakpoint rainfall hydrology and pesticide options of the field scale model CREAMS (Chemicals, Runoff, and Erosion from Agricultural Management Systems) were used to predict average concentrations of hexazinone [3 cyclohexyl-6-(dimethyl-amino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] in stormflow from four forested watersheds in the upper Piedmont region of Georgia. Predicted concentrations were compared with measured concentrations recorded over a 13-month period. CREAMS accurately predicted hexazinone concetrations in the initial stormflow events which also contained the highest concentrations. The model underestimated the hexazinone concentrations in stormflow two months and greater following pesticide application. In a companion study, the daily rainfall option of the CREAMS model was used to evaluate the reltive risk associated with the maximum expected concentration of hexazinone, bromacil (5-bromo-3 sec-butyl-6 methyuracil), picloram (4-amino-3,5,6 trichloropicolinic acid), dicamba (3,6-dichloro-0-anisic acid), and triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} in stormflow from small forested watersheds. The model predicted the following order of potential residue appearance in stormflow: bromacil>triclopyr>hexazinone>picloram>dicamba. Subsurface movement of residues via interflow and deep leaching losses are not simulated by the version of CREAMS used in these studies.     

Results from Three Field Tracer Experiments on the Neighbourhood Scale in the City of Birmingham UK

The physical processes governing flow and pollutantdispersion at the neighbourhood scale, a spatial scaleintermediate between the street scale and the city scale, is notwell understood. Furthermore, it is not clear whether a traditional approach using averaged characteristics such as theaerodynamic roughness length is sufficient to predict the concentration field at this scale. To investigate pollutant dispersion in a real urban area, three field experiments were designed within the UK-URGENT programme sponsored by NERC. Theexperiments were performed in the City of Birmingham using a finite duration release of inert, non-toxic and non-depositingtracers, vis. perfluoromethylcyclohexane (PMCH) and perfluoromethylcyclopentane (PMCP). Measurements were taken using air bag samplers placedin an arc at 3.5 km (first experiment) and 1 km (second andthird experiments) from the source; some trap samplers wereplaced outside the main arc in the outskirts of the city. Measurements were analysed in the laboratory using anovel gas-chromatography technique. Data so obtained werecompared with predictions from a simple steady-state modeland a time-dependent model. The concentration-time serieswere very asymmetrical with a sharp rise, a plateau followedby a relatively slow decrease and finally a long-livedplateau above (or possibly very slow decrease to) thebackground level.     

徽州村落旅游开发初探

村落旅游是我国近年来出现的一种新兴的特种旅游方式,表现出强劲的市场需求态势和良好的发展前景。文章以徽州为对象,对村落旅游的发展条件、市场需求、活动特点进行分析,并对村落旅游的开发、活动组织等方面进行了探讨,旨在为更好地利用区域这一普遍存在的旅游资源,完善区域旅游产品结构,实现区域旅游发展的整体推进提供一些有益的参考。     

可持续发展中合理人口规模的研究：以苏南地区集镇为例

本文在分析农业人口转移数量、经济效益、社会商品销售额、集镇容纳能力的基础上,研究了集镇合理人口规模的界线。     

乡镇工业企业发展与环境,资源协调问题初探

我国乡镇工业企业的发展与环境、资源的协调问题已经成为我国发展与环境、资源关系方面的大问题。实行工农相对分离,组建乡村工业区,是提高乡镇工业企业素质、效益,强化乡镇工业企业优化组合、规模经营的有效途径;是保护环境,实现资源有效利用的基础工作之一;是提高农业劳动生产率,实现农业规模经营的基础工作之一。     

Effective Planning and Implementation of Ecological Rehabilitation Projects: A Case Study of the Regional Municipality of Waterloo (Ontario, Canada)

The literature guides environmental planning and, specifically, how to use ecological rehabilitation projects to achieve long-term planning goals and landscape-scale environmental sustainability. There is, however, a perceived gap between principles in the literature and the use of them by practitioners involved in smaller-scale ecological rehabilitation projects. Using interviews with practitioners involved in 11 projects within the Regional Municipality of Waterloo, Ontario, Canada, we tested whether practitioners used five principles for effective planning and implementation of ecological rehabilitation that we derived from the literature. These five principles were: establishing political and ecological context, using ecologically appropriate objectives and practices, using comparative multidisciplinary and cross-scale approaches, using adaptive planning and implementation, and establishing good communication within and external to projects. Few projects followed all five principles, and practitioners indicated that they used three more project-specific principles: obtaining political/social support, promoting projects and changing attitudes about projects, and securing sufficient and persistent funding to maintain a project's life. While the literature emphasizes that ecological rehabilitation is only effective if projects are coordinated on a watershed basis, most practitioners focused solely on the goals of their specific project. The gap between literature and practice may arise because most practitioners are new to the field of ecological rehabilitation and still are focused on the methods involved. Time pressures force practitioners to obviate the literature and get projects started quickly, lest support evaporate. Complicating these difficulties is decreased support from federal and provincial governments for large-scale environmental planning. It is unclear whether ecological rehabilitation projects in Waterloo Region (at least) will ever become effective at promoting landscape-scale ecological goals or remain smaller-scale stop-gaps.     

乡村旅游与社区经济互动持续发展评估研究——以安徽省黟县西递为例

在实地调查和与专家访谈的基础上设计函调问卷,通过对函调问卷的综合分析,构建模糊评价模型,对西递旅游与社区经济互动持续发展水平做出评判。结果表明,西递旅游与社区经济处在基本可持续发展阶段,但也存在着一些制约旅游与社区经济互动持续发展的因素。在此基础上,提出促进西递旅游与社区经济互动持续发展的建议和措施。     

OBSERVATIONS ON KINEMATIC RESPONSE IN URBAN RUNOFF MODELS1

ABSTRACT: This paper first discusses the results of sensitivity analyses conducted on various parameters of the San Francisco Stormwater Model ta version of WREM) and the Penn State Runoff Model in terms of their impact on outflow hydrographs. The parameters considered within a idealized catchment include: basin shape, imperivous fraction, overland roughness and slope: deterntion depth; infiltration capacity; and hyetograph timing. Second, the results for the hypothetical catchment are extended to the lazzard laboratory surfaces (asphalt, grass, roofing material) as a mean of illustrating the need for changes in model structure, as opposed to continued parameter adjustment Finally the effect of altering the scale of hydraulic representation in the surface runoff and sewer transport calculations are demonstrated for two gaged watersheds in Hamburg, West Germany.     

Application of the Braun-Blanquet cover-abundance scale for vegetation analysis in land development studies

To document environmental impact predictions for land development, as required by United States government regulatory agencies, vegetation studies are conducted using a variety of methods. Density measurement (stem counts) is one method that is frequently used. However, density measurement of shrub and herbaceous vegetation is time-consuming and costly. As an alternative, the Braun-Blanquet cover-abundance scale was used to analyze vegetation in several ecological studies. Results from one of these studies show that the Braun-Blanquet method requires only one third to one fifth the field time required for the density method. Furthermore, cover-abundance ratings are better suited than density values to elucidate graphically species-environment relationships. For extensive surveys this method provides sufficiently accurate baseline data to allow environmental impact assessment as required by regulatory agencies.