基于UD-PLS对牛粪堆制Cu和Zn钝化预测模型的研究

选取钝化材料木醋液和影响堆肥质量的关键因素:含水量和C/N,每个因素安排6个水平,利用均匀设计进行多因素多水平试验,对试验结果进行偏最小二乘回归分析,建立对重金属的钝化预测模型.结果表明:木醋液添加比例为0.50%、含水量为40%和C/N为40时,Cu和Zn的钝化效果均达到最大值,分别为13.5%和30.2%;其中重金属Cu的钝化预测模型为 ,其中交叉有效性为 ,模型达到精度要求;重金属Zn的钝化预测模型为 ,其中交叉有效性为 ,模型达到精度要求.针对多因素多水平的复杂堆肥系统中,将均匀设计与偏最小二乘法有机耦合,有效地解决了试验次数多、因素间多重相关性的问题,从而使模型精度和实用性都得到提高.     

Biomolecules preserved in ca. 168 million year old fossil conifer wood

Biomarkers are widely known to occur in the fossil record, but the unaltered biomolecules are rarely reported from sediments older than Paleogene. Polar terpenoids, the natural products most resistant to degradation processes, were reported mainly from the Tertiary conifers, and the oldest known are Cretaceous in age. In this paper, we report the occurrence of relatively high concentrations of ferruginol derivatives and other polar diterpenoids, as well as their diagenetic products, in a conifer wood Protopodocarpoxylon from the Middle Jurassic of Poland. Thus, the natural product terpenoids reported in this paper are definitely the oldest polar biomolecules detected in geological samples. The extracted phenolic abietanes like ferruginol and its derivatives (6,7-dehydroferruginol, sugiol, 11,14-dioxopisiferic acid) are produced only by distinct conifer families (Cupressaceae s. l., Podocarpaceae and Araucariaceae), to which Protopodocarpoxylon could belong based on anatomical characteristics. Therefore, the natural product terpenoids are of great advantage in systematics of fossil plant remains older than Paleogene and lacking suitable anatomical preservation.     

汞的树木年轮化学研究进展

由于可以有效揭示重金属污染的时间变化序列,近年来,树木年轮被广泛应用于环境重金属污染的历史追溯。年轮化学技术也被应用于示踪某地区的汞污染历史,本文系统介绍了利用树木年轮化学对汞污染积累历史进行追溯研究的相关研究成果,包括样品采集与处理、含量测定及数据分析,并对木质汞来源进行了讨论,最后对汞年轮化学研究的未来发展进行了展望。     

Assessment of the coherence of the Swiss waste wood management

Waste wood recovery by thermal treatment with energy recovery or by recycling allows the substitution and conservation of primary resources. Swiss government notes the potential presence of tensions between policies which simultaneously encourage the cascade use of wood, the recycling or the energy recovery by thermal treatment of waste wood. The aim of the present research is to assess the coherence of waste wood management in Switzerland by a quantitative and qualitative approach. First, a material flow analysis allows to model the wood resources and waste wood metabolism over one century. The simulation results of various scenarios of waste wood management establish that the additional impacts of the immediate thermal treatment are less significant for the reduction of CO₂eq emissions but more significant for the energy production than its cascade treatments on Swiss territory. Secondly, a documentary analysis examines the determinants of the current waste wood treatments prevailing in Switzerland. Thus, the causes of the strong presence on Swiss territory of the sector of thermal treatment, the export of almost half of waste wood generated and the sub-exploitation of Swiss forest act as barriers or drivers that result in introducing a crowding-out effect where no amount of waste wood is available for recycling in Switzerland. The comparison of the results of the two approaches leads to the conclusion that the current waste wood management is coherent in relation to the various goals of the Swiss federal policies but the waste wood potential for energy production is not fully exploited. The recommendations on the waste wood management and the possibilities to use the model for other case studies are given in the conclusion.     

Influence of fuel moisture, charge size, feeding rate and air ventilation conditions on the emissions of PM, OC, EC, parent PAHs, and their derivatives from residential wood combustion

Controlled combustion experiments were conducted to investigate the influence of fuel charge size, moisture, air ventilation and feeding rate on the emission factors (EFs) of carbonaceous particulate matter, parent polycyclic aromatic hydrocarbons (pPAHs) and their derivatives from residential wood combustion in a typical brick cooking stove. Measured EFs were found to be independent of fuel charge size, but increased with increasing fuel moisture. Pollution emissions from the normal burning under an adequate air supply condition were the lowest for most pollutants, while more pollutants were emitted when an oxygen deficient atmosphere was formed in the stove chamber during fast burning. The impacts of these factors on the size distribution of emitted particles was also studied. Modified combustion efficiency and the four investigated factors explained 68%, 72%, and 64% of total variations in EFs of PM, organic carbon, and oxygenated PAHs, respectively, but only 36%, 38% and 42% of the total variations in EFs of elemental carbon, pPAHs and nitro-PAHs, respectively.     

Application of hinokitiol potassium salt for wood preservative

The decay of wood and other cellulosic materials by fungi cause significant economic loss. The widely used chromated copper arsenate was prohibited for the environmental impact and safety of arsenic and chromium. It was found that natural product hinokitiol (HK) had fungicidal and insecticidal activities, and its toxicity was bearable for the environment. We described the practical synthesis of HK-K salt. According to the GB/T18261-2000 and LY/T1283-1998, wood preservative performance of HK-K salt was tested. The results showed that the best inhibitory concentration of HK-K salt was 50 mg/L, for which the prevention effectiveness on mold is better, the killed value is between 0 and 1, and the corrosion-resistant for wood-rotting fungi is grade A.     

A lidar-based assessment of riparian shade and large wood potential in the Skagit River watershed,WA

Wild salmon stocks in the Pacific Northwest are imperiled by a variety of declining habitat factors, including riparian shade and in-channel large wood. In this paper, a relatively simple lidar model of the riparian canopy was used along anadromous streams in the Skagit River watershed in western Washington State, United States, to delineate where riparian trees were most lacking, and where restoration efforts would have the greatest benefit in terms of shade and large wood recruitment potential. Within a 45-m riparian buffer, 61% of riparian zones were currently incapable of delivering large wood to the stream. Current potential for large wood recruitment is greatest adjacent to stream edges and falls off rapidly with distance from the channel. Approximately 99% of large wood recruitment potential lies within 45 m of the channel edge, and 50% of the wood potential is within 9 m. A hypothetical canopy model in which all trees mature to a 100-year height would provide 18% more shade distributed over the entire watershed, and 90% more shade in the tributaries. Most of the potential gains in improved shade and large wood contributions are in agricultural areas, as opposed to forestry or urban land uses. The shade and large wood models were constructed from widely available geographic information system tools and are readily transferable to other watersheds with similar characteristics. Model outputs are intended for use in planning restoration projects, as an input to stream temperature models, and to inform policy on restoration priorities and regulatory buffer widths.     

A Two‐Decade Watershed Approach to Stream Restoration Log Jam Design and Stream Recovery Monitoring: Finney Creek,Washington

A federal, state, and private partnership leveraged resources and employed a long‐term, systematic approach to improve aquatic habitat degraded by decades of intensive forest management in Finney Creek, a tributary to the Skagit River of Northwest Washington State. After more than a decade of work to reduce sediment sources and the risk of landslides within the watershed, log jam installation commenced in 1999 and progressed downstream through 2010. Log jam design was adapted as experience was gained. A total of 181 log jams, including 60 floating log ballasted jams, were constructed along 12 km of channel. The goal was to alter hydraulic processes that affect aquatic habitat formation along 39 km of stream with emphasis on 18.5 km of lower Finney Creek. Aquatic habitat surveys over a five‐year period show an increase in the area of large pools and an accompanying increase in residual and maximum pool depth in the lower river reach. Channel cross sections show a generally deeper channel at the log jams, better channel definition in the gravel deposits at the head of the log jams, and improved riffle and thalweg development below the log jams. Stream temperature in the upper river decreased by 1.0°F in the first three years, and 1.1°F in the lowest treated reach over nine years. There is a trend of less stream heating over the restoration time period. Photo points show that riparian vegetation is recolonizing gravel bars.     

桉树遗态Fe/C复合材料对水中Cr(Ⅵ)的动态吸附探讨

为研究桉树遗态Fe/C复合材料（PBGC-Fe/C）对水中Cr（Ⅵ）的净化能力及其动态吸附过程,以PBGC-Fe/C吸附剂为固定床,选择溶液初始pH、进水流速、溶液初始浓度、吸附剂投加量和环境温度为影响因素开展动态吸附试验分析.结果表明:在溶液初始pH为2,进水流速为5.14 mL/min,吸附剂投加量为2 g和环境温度为35℃的条件下,PBGC-Fe/C对水中Cr（Ⅵ）的最佳平衡吸附容量达到10.72 mg/g;提高溶液初始pH、进水流速和溶液初始质量浓度或降低吸附剂投加量均可缩短反应穿透时间和衰竭时间;Thomas和Yoon-Nelson模型均能较好地描述PBGC-Fe/C对水中Cr（Ⅵ）的动态吸附过程,说明该吸附过程中内部扩散和外部扩散均为非限速步骤,吸附速率常数（k_Th）随着进水流速的增大从1.3×10-3 mL/（min·mg）升至2.6×10-3 mL/（min·mg）,随着溶液初始质量浓度的增大从2.7×10-3 mL/（min·mg）降至1.4×10-3 mL/（min·mg）.研究显示,PBGC-Fe/C对水中Cr（Ⅵ）具有较好的动态吸附能力,具有较好的市场应用前景.      

常用木质家具材料在不同氧浓度下的热分析

利用热重差热分析仪对几种常用木质家具材料在不同氧气浓度下的热分解和燃烧行为进行了研究。通过对TGA曲线,DTG曲线以及DTA曲线的分析,得出了氧气浓度对各种样品热分析结果的影响。求出了各样品的动力学参数,提出了相应的燃烧动力学反应模型。