Removal of citrate and hypophosphite binary components using Fenton, photo-Fenton and electro-Fenton processes

Both citrate and hypophosphite in aqueous solution were degraded by advanced oxidation processes (Fe2+/H2O2, UV/Fe2+/H2O2, and electrolysis/ Fe2+/H2O2) in this study. Comparison of these techniques in oxidation efficiency was undertaken. It was found that Fenton process could not degrade completely citrate in the presence of hypophosphite since it caused a series inhibition. Therefore, UV light (photo-Fenton) or electron current (electro-Fenton) was applied to improve the degradation efficiency of the Fenton process. Results showed that both photo-Fenton and electro-Fenton processes could overcome the inhibition of hypophosphite, especially the electro-Fenton.     

江门市应急管理局:强化基层基础 全力落实“最后一公里”

2020年,江门市聚焦关键重点和薄弱环节,强化责任落实,加大创新投入,抓好风险防控,大力推动基层应急管理治理能力和治理体系现代化,全力保障安全防范“最后一公里”得到有效落实。细化明确基层应急部门职责。江门市目前已完成镇(街)机构改革,全市73个镇(街)均独立设置应急管理办公室。     

九寨沟县地表水环境容量研究

水体中污染物的排放必须与水体的水环境容量相适应.在综合考虑城市经济发展与水资源利用状况前提下,首先,通过监测资料对九寨沟县辖区内主要污水受纳水体--白水江的地表水环境质量现状进行了评价,同时,结合对白水江流域污染源的现场调查,明确了河道水体的主要污染因子为CODCr和NH3-N,并预测了其在远、近规划期内的排放量;其次,在对河段进行功能分区基础上,采用一维稳态模型下的段首控制法计算了水环境容量.结果表明,2005年白水江CODCr与NH3-N的理论水环境容量分别为39.44 T/d和2.32 T/d,2005年其实际水环境容量分别为26.42 T/d和1.55 T/d.白水江水环境容量在近、远期内均能满足城市发展要求,但鉴于九寨沟县的旅游定位功能,应采取更为严格的控制标准;最后,结合九寨沟城镇生活污染源、农村面源与工业污染源的相应特点,提出了全面提升九寨沟县水环境质量的规划方案,为白水江实施污染总量控制与水环境管理提供了科学依据.     

京津冀区域气溶胶中无机水溶性离子污染特征分析

在北京、天津、石家庄、承德城区和北京上甸子区域本底站共设置5个采样点,2009～2010年分季节采集环境PM<,2.5>,并分析其中的无机水溶性离子,进而研究京津冀区域气溶胶中离子组分的污染特征.研究表明,京津冀PM<,2.5>污染较重,北京、天津和石家庄年均浓度均超过了100 μg/m<'3>;5个站点二次离子(SO...     

热泵蒸发及其在浓缩垃圾渗滤液中应用的初探

在热泵蒸发过程中,二次蒸汽压缩比是个至关重要的参数,它直接关系到热泵蒸发的经济程度。对热泵蒸发中的传热过程及可利用的余热作了全面分析。最后对热泵蒸发在浓缩垃圾渗滤液中的应用进行了探讨。     

Biosorption of mercury by Macrocystis pyrifera and Undaria pinnatifida: Influence of zinc, cadmium and nickel

The article investigated the adsorption of Hg(II) on Macrocystis pyrifera and Undaria pinnatifida in monometallic system and in the presence of Zn(II), Cd(II) and Ni(II).     

Material conversion from paper sludge ash in NaOH solution to synthesize adsorbent for removal of Pb^2＋, NH^4＋ and PO4^3- from aqueous solution

Material conversion from paper sludge ash (PSA) in NaOH solution was attempted to synthesize the adsorbent for removal of inorganic pollutants, such as Pb2+, NH4 + and PO4 3?? from aqueous solution. PSA of 0.5 g was added into 10 mL of 3 mol/L NaOH solution, and then heated at 80, 120, and 160°C for 6–48 hr to obtain the product. PSA mainly composed of two crystalline phases, gehlenite (Ca2Al2SiO7) and anorthite (CaAl2Si2O8), and amorphous phase. Hydroxysodalite (Na6Al6Si6O24 8H2O) was formed at 80°C, and anorthite dissolved, whereas gehlenite remained una ected. Katoite (Ca3Al2SiO4(OH)8) was formed over 120°C, and hydroxycancrinite (Na8(OH)2Al6Si6O24 2H2O) was formed at 160°C, due to the dissolution of both gehlenite and anorthite. Specific surface areas of the products were almost same and were higher than that of raw ash. Cation exchange capacities (CECs) of the products were also higher than that of raw ash, and CEC obtained at lower temperature was higher. Removal abilities of products for Pb2+, NH4 +, and PO4 3?? were higher than that of raw ash.With increasing reaction temperature, the removal e ciencies of Pb2+ and NH4 + decreased due to the decrease of CEC of the product, while removal e ciency for PO4 3?? was almost same. The concentrations of Si and Al in the solution and the crystalline phases in the solid during the reaction explain the formation of the product phases at each temperature.     

Experimental studies on ozonation of ethylenethiourea

The experimental study on ozonation of ethylenethiourea(ETU) is conducted.The reaction of gas-phase ETU with 0.63 × 10-6 mol/L ozone is carried out in a 200-L reaction chamber.The secondary organic aerosol(SOA) resulted from the ozonation of gas-phase ETU is observed with a scanning mobility particle size(SMPS).The rapid exponential growth of SOA reveals that the atmospheric lifetime of ETU vapor towards ozone reaction is less than four days.The ozonation of dry ETU particles,ETU-contained water droplets an...     

镜泊湖水环境容量与水污染防治对策研究

随着镜泊湖旅游业快速发展,环境压力指数化增加长,环境保护面临着巨大的挑战。针对镜泊湖水环境污染严重的状况,在水质现状评价的基础上,计算了镜泊湖高锰酸盐指数和总磷两项指标的水环境容量值,并对计算结果进行了分析。在水环境容量计算结果的基础上,结合实际情况提出了镜泊湖流域水环境保护的措施和建议,为合理有效地利用水环境容量资源和区域可持续发展提供理论支撑和对策。     

种适用于分布式电源管理的新型智能开关

分布式电源改变了配电网的运行模式,对配电网的运行管理提出了新的挑战和要求。针对这种情况,运用一、二次融合的设计理念,提出了一种适用于分布式电源管理的新型智能开关设计,应用结果表明:该智能开关采用电子式互感器采集全部运行数据,具备三段式过流方向保护、零序方向保护、电能量计量等功能,可以很好地解决分布式电源管理及多电源线路的故障判断与故障隔离等问题。