HDTMA改性粘土吸附固定沉积物间隙水中多环芳烃的模拟研究

选用经过十六烷三甲基溴化铵(HDTMA-Br)改性的粘土矿物为吸附剂,探讨其对水中多环芳烃类有机污染物的吸附性能。结果表明,HDTMA改性土吸附固定水中多环芳烃的能力比天然沉积物要高得多且吸附稳定。本文还讨论了环境温度、pH值、盐度、振荡时间、污染物初始浓度以及投土量对吸附性能的影响以确定吸附的适宜条件。根据实验结论,将HDTMA改性土投到实际间隙水样品中,经过充分的吸附,结果显示,经HDTMA改性粘土吸附后的间隙水中多环芳烃的含量均在检出线以下,说明HDTMA改性土可以有效地吸附固定沉积物间隙水中的多环芳烃,降低其迁移性,防止其释放产生二次污染。     

Performance of a novel vertical-flow settler: a comparative study

By increasing particle concentration and G value （root-mean-square velocity gradient） to enhance flocculation, a novel vertical-flow settler was designed to increase sedimentation effectiveness, and to simultaneously improve operational stabilization. Due to the gradual decrease in upward flow-rate of raw water, a floes blanket would form and suspend in the middle section of the settler, not at the bottom as in a conventional clarifier. Enough large floes, resulted from flocculation or fltration, would continuously settle out of the floes blanket, and simultaneously, the floes in raw water or those forming above the blanket would ceaselessly enter the floes blanket. As a result, the floes concentration in the blanket could keep a dynamic balance. The hydrodynamic shear in the blanket was improved by flow separation, which was induced by the abrupt change in flow channel. Due to the floes blanket and improved hydrodynamic shear, flocculation would be enhanced, which was helpful for removing fine particles in raw water. A comparative study showed that the novel vertical-flow settler had a much better performance in the removal of the particles in raw water than a conventional one, when they treated kaolin suspensions of different concentrations （500, 100 and 50 mg/L, respectively） coagulated by polyaluminum chloride（PAC1） at the up-flow rates of 1 and 2 mm/s, respectively.     

Dissipation of chlorpyrifos in pakchoi-vegetated soil in a greenhouse

The dissipation of chlorpyrifos in pakchoi-vegetated soil was investigated in the summer and autumn in a greenhouse and field, respectively. The dissipation of chlorpyrifos in pakchoi-grown soil was comparatively described by fitting the residue data to seven models （lst-order, 1.5th-order, 2nd-order, RF lst-order, RF 1.5th-order, RF 2nd-order, and bi-exponential or two-compartment models）. Statistical analysis was performed using the SPSS 11.5 statistical package. The bi-exponential model was selected as the optimal model according to the coefficient of determination r^2. The dissipation half-lives （DT50） of chlorpyrifos in pakchoi-vegetated soil at the recommended dose in the summer and autumn, calculated by the bi-exponential model, were 0.6 and 1.2 d in a greenhouse, 0.4 and 1.0 d in a field, respectively; the corresponding values at double dose were 1.2 and 2.1 d in a greenhouse, 0.5 and 1.3 d in a field, respectively. The kinetic data indicate the dissipation of chlorpyrifos in pakchoi-grown soil in a greenhouse is slower than that in a field, and dissipates slower in the autumn than in the summer.     

Characteristics of sewage sludge and distribution of heavy metal in plants with amendment of sewage sludge

In order to better understand land application of sewage sludge, the characterization of heavy metals and organic pollutants were investigated in three different sewage sludges in Shanghai City, China. It was found that the total concentrations of Cd in all of sewage sludge and total concentrations of Zn in Jinshan sewage sludge, as well as those ofZn, Cu, and Ni in Taopu sludge are higher than Chinese regulation limit of pollutants for sludge to be used in agriculture. Leachability of rig in all of studied samples and that of Cd in Taopu sewage sludge exceed the limit values of waste solid extraction standard in China legislation. Based on the characteristics for three kinds of sewage sludge, a pot experiment was conducted to investigate the effect of soil amended with Quyang sewage sludge on the accumulation of heavy metalo.by Begonia semperfloreas-hybr; Ophiopogon japonicas （L.F.） Ker-Gaw; Loropetalum chindense-var, rubrum; Dendranthema morifolium; Viola tricolor; A ntirrhinum majas; Buxas radicans Sieb; Viburnum macrocephalum; Osmanthas fragrans Lour; Cinnamomum camphora siebold and Ligustrum lucidum ait. Results showed that 8 species of plant survived in the amended soil, and moreover they flourished as well as those cultivated in the control soil. The heavy metal concentration in plants varied with species, As, Pb, Cd and Cr concentration being the highest in the four herbaceous species studied, particularly in the roots of D. morifolium. These plants, however, did not show accumulator of As, Pb, Cd and Cr. The highest concentration of Ni and Hg was found in the roots ofD. morifolium, followed by the leaves ofB. semperflorens-hybr. Levels of Zn and Cu were much higher in D. morifolium than in the other plant species. D. morifolium accumulated Ni, Hg, Cu and Zn, which may contribute to the decrease of heavy metal contents in the amended soil. Treatment with sewage sludge did not significantly affect the uptake of heavy metals by the L. chindense-var, rubrum, however, it significantly affected the uptake of heavy metals by D. morifolium.     

Process of rice straw degradation and dynamic trend of pH by the microbial community MC1

The process of the rice straw degradation in the fermentor with aeration at 290 ml/h was studied. The results of dissolved oxygen （DO） indicated that the optimum DO during cellulose degradation by microbial community MC1 ranged from 0.01 to 0.12 mg/L. The change model ofpH values was as follows： irrespective of the initial pH of the medium, pH values decreased rapidly to approximate 6.0 after being inoculated within 48 h when cellulose was strongly degraded, and then increased slowly to 8.0--9.0 until cellulose was degraded completely. During the degradation process, 15 kinds of organic compounds were checked out by GC-MS. Most of them were organic acids. Quantity analysis was carried out, and the maximum content compound was ethyl acetate which reached 13.56 g/L on the day 4. The cellulose degradation quantity and ratio analyses showed that less quantity （under batch fermentation conditions） and longer interval （under semi-fermentation conditions） of rice straw added to fermentation system were contributed to matching the change model of pH, and increasing the quantity and ratio of rice straw degradation during cellulose degrading process. The highest degradation ratio was observed under the condition office straw added one time every five days （under semi-fermentation conditions）.     

Degradation of 2,4-dichlorophenoxyacetic acid in water by ozone-hydrogen peroxide process

IntroductionAt present, several types of organic pollutantsreferred to as environmental endocrine disruptors(ED) have been suggested to be associated withabnormal sexual development (Hu, 2000). It wasreported that the ED led to the decline of reproductive…     

强化思政教育在专业精神建设中的引领作用

建设高素质专业化应急管理干部队伍是新时代的发展要求,2019年应急管理部印发关于贯彻落实《2018?2022年全国干部教育培训规划》实施意见中提出,培养造就忠诚干净担当的高素质专业化应急管理干部队伍。专业精神是对专业化能力的凝练升华,表现为在任何工作岗位都会自觉刻苦钻研、力求精益求精、勇于担当作为。     

安全信息认知对心理安全感的作用机理研究

为揭示安全信息认知对员工心理安全感的影响,把握信息时代背景下心理安全感的研究趋势。基于安全信息认知的背景与特征,构建心理安全感的安全信息认知流程模型。通过描述安全信息对心理安全感的影响机理,从需要、动机、意识、期望剖析心理安全感的安全信息认知动力,归纳心理安全感的安全信息认知偏好,并从风险管控、安全氛围、安全管理落地、安全防护措施设计、员工安全生产积极性方面论述心理安全感在企业的应用对策。研究表明,员工安全信息认知对其心理安全感具有重要影响,是引起心理安全感波动的关键因素,也为心理安全感在企业的应用提供指导。     

基于时序InSAR的覆砂石尾矿坝形变演化研究

为解决目前采用在尾矿坝坝体及滩面覆盖砂石进行防尘治理与闭库,但传统监测手段难以实现坝体整体监测的问题,采用时序InSAR技术对2014年10月至2018年7月的Sentinel-1A影像进行处理,提取了对应时间段内卡房尾矿坝的形变信息,并结合实地调查及尾矿坝建设资料,研究了卡房尾矿坝的时序形变演化规律。结果表明:SBAS InSAR监测到坝体出现第1次异常形变加速运动时间与坝体开始铺设砂石工程的施工时间节点完全吻合,体现SBAS InSAR技术在受人为工程影响的坝体形变监测方面具有极高的敏感性。坝体在施工结束后,坝体形变加剧趋势并未缓解,并且出现2次加速现象,分析认为是由于在坝体铺设约2 m厚的碎砂石极大地增加了坝体荷载,打破了坝体原有的应力平衡状态,且识别出雨季对坝体形变影响显著,表明铺设砂石会使得降雨在坝体中的停滞时间加长,进一步引发非雨季期间坝体形变加剧。研究结果不仅能还原坝体出现异常形变的时间与演化过程,而且还可以对引起异常形变的内在影响因素进行分析与论证,对指导尾矿坝灾害识别、分析与治理具有重要的指导意义。     

波浪与抛石潜堤相互作用的MPS法数值模型研究

为了研究波浪与抛石潜堤相互作用过程中大自由表面变形和堤内渗流等强非线性紊流运动问题,利用改进的MPS法,建立了模拟波浪与抛石潜堤相互作用的MPS法数值计算模型。模型将抛石潜堤假定为均质多孔介质,采用Drew的二相流运动方程描述多孔介质内外的流体运动;通过在动量方程中增加非线性阻力项,并引入亚粒子尺度紊流模型,模拟波浪与可渗结构物相互作用过程中的紊流运动。选取“U”型管中多孔介质内渗流过程和孤立波与可渗潜堤相互作用两个典型的渗流问题,通过将数值计算结果与理论解和实测值的对比分析,对所提出的MPS法紊流渗流模型的模拟精度进行验证。结果表明：基于改进的MPS法构建的垂向二维紊流渗流模型可以很好地再现 “U”型管中多孔介质内渗流以及波浪作用下可渗潜堤内外的复杂流场,显著缓解流-固界面处的压力震荡与粒子分布不均匀问题,实现了较高的模拟精度。