Moisture distribution in sludges based on different testing methods

Moisture distributions in municipal sewage sludge, printing and dyeing sludge and paper mill sludge were experimentally studied based on four different methods, i.e., drying test, thermogravimetric-differential thermal analysis (TG-DTA) test, thermogravimetricdifferential scanning calorimetry (TG-DSC) test and water activity test. The results indicated that the moistures in the mechanically dewatered sludges were interstitial water, surface water and bound water. The interstitial water accounted for more than 50% wet basis (wb) of the total moisture content. The bond strength of sludge moisture increased with decreasing moisture content, especially when the moisture content was lower than 50% wb. Furthermore, the comparison among the four different testing methods was presented.The drying test was advantaged by its ability to quantify free water, interstitial water, surface water and bound water; while TG-DSC test, TG-DTA test and water activity test were capable of determining the bond strength of moisture in sludge. It was found that the results from TG-DSC and TG-DTA test are more persuasive than water activity test.     

论灾害的生态经济性质

本文从灾害的产生与灾害概念的发展、灾害的成因与过程、灾害的后果等多个方面论证和论述了灾害的生态经济性质。灾害生态经济性质的揭示为开展各类灾害的系统总体研究—灾害的生态经济研究提供了理论依据。     

煤与瓦斯突出起动过程的突变理论研究

分析了煤与瓦斯突出的起动和发展机制,在此基础上,应用突变理论,采取拓扑变换的方法,得到了描述突出起动过程的突变势函数,讨论了突出起动过程的突变条件,并据此解释了防突措施的机理。所得结论与防突工程实践中的认识相一致,表明突变理论可望为研究煤与瓦斯突出机制提供一种新的方法     

双金属冷压焊固相结合强度的分析和计算

分析了表面状态及金属性能对双金属冷压焊结合强度的影响 ,运用金属 金属界面结合力的计算方法 ,对冷压焊固相结合强度进行了分析和研究     

关于环保基础设施债券化融资的设想

本文通过分析美国环保基础设施市场化融资中债券工具的应用,并结合我国实际情况,提出利用债券这一金融工具来解决环保基础设施融 资金中存在的障碍和问题,并提出了若干努力方向和具体措施。     

薄隔水层井筒底板突水的突变模型

在薄板理论的基础上,建立了立井井筒底板突水的突变模型。运用突变理论的分析方法,求得了井筒底板隔水层的最小理论安全厚度,这与典型案例实际情况基本相符。论文根据在大涨落存在的前提下突变发生所遵循的Ｍａｘｗ ｅｌｌ规则,对理论值和实际值的偏差作了合理的解释,还提出了解决该偏差的一种近似计算方法。所进行的研究工作,为井筒突水的预测及确定隔水层的安全厚度,提供一种新的理论方法和途径。     

Mechanism and rate constants for complete series reactions of 19 fluorophenols with atomic H

Fluorine-containing halogenated fluorophenol may have efect as intermediate species involved in the formation of polyfluorinated dibenzo-p-dioxin/dibenzofurans(PFDDs/Fs). The mechanism for the atomic H initiated reactions with complete series of nineteen fluorophenol congeners was studies using the density functional theory. At the MPWB1K/6-31+G(d,p) level, the geometries and frequencies of reactants, transition states, and products were obtained, and the accurate energetic values were acquired at the MPWB1K/6-311+G(3df,2p) level. The rate constants were evaluated by the canonical variational transition-state theory with the small curvature tunneling contribution over a wide temperature range of 600–1000 K. The study shows that the intramolecular hydrogen-bond in the ortho-substituted FPs as well as the inductive efect of the electron-withdrawing fluorine and steric repulsion of multiple substitutions may ultimately be responsible for the relative strength of the O–H bonds in FPs. The results can be used for further studies on PFDD/Fs formation mechanism.     

蒸馏水吸收直接进样气相色谱法测定空气中的甲醛

用蒸馏水吸收富集室内空气中的甲醛,直接进样,经毛细管柱GC/FID测定样品中的甲醛,以保留时间定性,以峰面积定量。