液化石油气站装卸连接装置改造的安全隐患分析

针对目前液化石油气站内装卸软管已强制要求改装为液体装卸臂的现状,本文梳理了原质监部门和安监部门对液化石油气站内装卸连接装置的不同要求,对在用液体装卸臂改造存在的安全隐患和后续的监管问题进行了分析,并对液体装卸臂的改造和监管提出了几点建议.     

Characterization of products from photooxidation of toluene

Photooxidation reaction of toluene in smog chamber systems was initiated by the UV radiation of tolucne/CH5ONO/NOx mixtures. The products of the photooxidation reaction of toluene and its subsequent reactions were analyzed directly utilizing Fourier transform infrared spectrometer （FTIR）. Detailed assignments to FTIR spectrum of gas-phase products were given. The information of some important functional groups in the products, such as, carbonyl groups （C-O）, hydroxyl groups （-OH）, carboxylic acid （- COOH）, C-C bonding, N O bonding and C-H bonding （C H）, was got from this analysis. These results were compared to those analyzed by aerosol time of flight mass spectrometer （ATOFMS）. It was found that there are some differcnccs between FTIR analysis of gas-phase products and that of particle-phase, for example, the products with carbonyl groups, which were connected to unsaturated chemical bonds, was relatively higher in the gas phase, while kctoncs, aldehydes, carboxylic acid and organonitrates were the dominant functional groups in the aerosol-phase reaction products. The possible reaction pathways of some important products in the gas phase were also discussed.     

傅立叶变换红外多组分气体分析仪在水污染应急监测中的应用

为了更好地为水污染应急监测工作服务,利用顶空原理,采用傅立叶变换红外多组分气体分析仪,测定水样中的有机污染物,快速筛查定性水体中主要污染物,再选用标准方法准确定量污染物浓度。结果表明,该方法具有测定范围广、仪器携带方便、筛查定性快速的优点。     

粪大肠菌群快速测定——纸片法的应用

采集苏州具有代表性的地表水水体22个点位的样品,进行粪大肠菌群的测定方法比较,结果表明,《粪大肠菌群快速测定--纸片法》适于测定受粪便污染程度较轻的湖泊水体.但是,该方法的培养时间对阳性管率有明显影响,认为16 h～18 h是比较理想的培养时间.     

Virgin and recycled engine oil differentiation: a spectroscopic study

As a result of the changes that occur during their use, used engine oils tend to differ in chemical and physical composition from a virgin oil. In general recycled oils have: much higher water and sediment levels than virgin oil; relatively higher concentrations of organic compounds (oxidation products); and relatively higher levels of metals such as Fe, Cd, Cr, Pb, etc. Therefore, the aim of this work was to investigate, assess and to observe, by means of the physical and the chemical properties of the oils, atomic absorption (AA), inductive couple plasma (ICP) and Fourier transform infrared (FTIR) analyses the extent of the differences occurring between the virgin and recycled oil. In important part of this work was also the development of analytical techniques based on the use of FTIR spectroscopy; in relation to the rapid analysis of lubricants; in particular for the differentiation of virgin and recycled oil. The results obtained were expected to be useful for differentiation purposes, providing information on whether the metal concentrations and oxidation products could be an appropriate feature for differentiating a particular oil sample from the others. This work is categorized into a two-step procedure. Firstly, an evaluation of a typical FTIR spectrum of an engine oil sample (mono- and multigrade) is presented. The broad feature centered at 1716 cm(-1) is due to the presence of carbonyl containing degradation products of oil. A band observed at 1732, 1169, 1154 and 1270 cm(-1) assigned to the polymethacrylate stretching vibrations, allows the determination of viscosity modifier and pour point depressant additives. The observed differences in the specific spectral bands (1732, 1169, 1154 and 1270 and 1716 cm(-1)) are investigated and discussed. Secondly, an analytical technique for the measurement of the levels of the wear metals is also applied.     

基于傅里叶级数的自然灾害损失预测模型研究——以湖南省自然灾害经济损失预测为例

针对湖南省自然灾害经济损失发生的现状,结合傅里叶级数的相位特征,利用傅里叶级数时间序列模型给出自然灾害损失的变化趋势。根据1986—2007年湖南省自然灾害所造成的直接经济损失数据,在SPSS环境下进行拟合,并对未来5年湖南省的自然灾害所造成的直接经济损失进行预测。结果表明:傅里叶级数时间序列模型符合自然灾害损失发生的特点,有效地解决了传统损失预测模型在灾害经济损预测中误差大、稳定性差的缺陷,提高了预测精度;且得出未来5年湖南灾害灾情仍然具有递增的趋势的结论。采用该模型对自然灾害损失进行预测,其结果比较可靠,可供减灾决策部门参考。     

Enhanced degradation of bioremediation residues in petroleum-contaminated soil using a two-liquid-phase bioslurry reactor

A study was performed to determine the potential of two-liquid-phase (TLP) bioslurry reactors using silicon oil as solvent for degradation of residual contaminants in petroleum-contaminated soil. The residues were characterized by gas chromatography–mass spectrometry and electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. This allowed for the identification of a mixture of residual biomarkers, metabolic byproducts, oxygenated and hetero-polynuclear aromatic hydrocarbons in the contaminated soil. The removal amount of total extractable organics (TEO) was 15 900 mg kg⁻¹ soil in the TLP reactor within 12 weeks. However, TEO remained intact in the bioslurry reactor without the addition of silicon oil for the duration of the experiment, due to high toxicity of metabolites to the microorganisms. The availability of TEO was calculated using a mild extraction with Triton X-100, and the amount of TEO extracted was in accord with the amount of biodegraded TEO. Significantly reduced toxicity in soil was observed at week 12 through TLP remediation. Dehydrogenase activity in the bioslurry reactor was strongly suppressed. Fluorescein diacetate was significantly hydrolyzed by the composition of bioremediation residues in the contaminated soil. Microbial adhesion to the solvent was revealed by the determination of microbial activity in the water-immiscible-liquid.     

多层采空区条件下的高速公路路堑边坡稳定性数值分析

高速公路建设过程中常穿越各种矿山采空区,采空区对路堑边坡的稳定性产生较大的影响。基于有限差分分析的快速拉格朗算法FLAC3D程序,由于具有强大的数值模拟分析功能,可以模拟多种结构形式的地质体,因而广泛应用于各种岩土工程问题。本文结合国家某重点交通项目,采用快速拉格朗算法FLAC3D程序对多层采空区条件下的某路堑边坡稳定性进行了评价,主要包括开挖、注浆和锚固等工况下路堑边坡的应力和位移分析。分析结果表明,采空区经过处理后的路堑边坡是稳定的,FLAC3D应用于多层采空区条件下的路堑边坡稳定性评价是可行的。