Metal accumulation risks in regularly flooded and non-flooded parts of floodplains of the River Rhine: Extractability and exposure through the food chain

Ecotoxicological risks of sediment contamination in floodplains are supposed to be highest in the regularly flooded parts. Therefore, in risk assessments, the non-flooded parts are neglected or considered to be reference areas. We investigated the metal extractability and levels in important food sources for vertebrates, viz. grass shoots and earthworms, in flooded as well as non-flooded parts and compared these with total metal concentrations. A comparison of these areas in the moderately polluted 'Afferdensche en Deestsche Waarden' floodplains along the River Rhine showed that total Zn, Pb, and Cd concentrations were highest in the regularly flooded parts. However, CaCl₂-extractable Zn concentrations were highest in non-flooded areas, and those of Pb and Cd were equal in both areas. Total Cu concentrations were not significantly different between the two areas, but CaCl₂-extractable Cu concentrations were highest in the regularly flooded areas. The metal concentrations in grass shoots of non-flooded areas were equal to (Zn, Cu, Cd) or higher than (Pb) those in regularly flooded areas. Zn concentrations in earthworms in regularly flooded areas were higher, but concentrations of Cu, Pb, and Cd were not. Ecotoxicological risk assessments require analysis of the total and potentially bioavailable metal concentrations in soils as well as concentrations in biota. This study shows that the less contaminated non-flooded areas in moderately polluted floodplains cannot be neglected in metal accumulation studies and cannot be used as pristine reference areas.     

Burden levels of polychlorinated dibenzo-p-dioxins, dibenzofurans, and polychlorinated biphenyls in typical edible meat animals

The concentrations and distributions of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and polychlorinated biphenyls (PCBs) in the whole blood and meat of eight typical edible animals (chicken, donkey, horse, cattle, rabbit, sheep, duck, and pig) were illustrated. Total concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and PCBs (on a basis of liquid volume) in animal bloods were 142-484 pg/L and 46-62 ng/L, respectively. Total concentrations of PCDD/Fs and PCBs (on a basis of dry weight (dw) and lipid weight (lw)) in animal meat samples were 0.47-1090 pg/g dw (0.47-4513 pg/g lw) and 7.2-23 ng/g dw (10-776 ng/g lw), respectively. TEQs for both PCDD/Fs and PCBs in animal blood and meat samples were (67 ± 27) pg/L and (5.3 ± 14) pg/g dw (24 ± 56 pg/g lw), respectively. Besides, the dietary intakes of PCDD/Fs and PCBs were also estimated. Chicken and pig contributed more TEQs than other animals. Chicken contributed the most (95%) with high toxicity, followed by pig (3.4%) with high consumption. The dietary intake of chicken might pose risks to consumers who prefer to eat chicken products, who should comprehensively consider the essential nutrients and contaminants in food during dietary intake.     

中国粮食自给率研究——粮食、谷物和口粮自给率分析

由于统计口径与计算方法的不同,粮食自给率的计算结果往往差异较大,得出的中国粮食安全的结论也大相径庭,从而引起国内各界的广泛争议。为了准确分析当前中国的粮食安全情势,避免误判对相关决策造成误导,有必要对粮食的统计口径和自给率计算方法进行分析研究。本文选用三种粮食自给率计算方法—定额统计法、流向统计法和消费统计法,测算中国2000-2016年的粮食、谷物和口粮自给率,并对结果进行对比分析。结果显示：（1）定额统计法计算结果容易造成失真,流向统计法与消费统计法计算结果较为准确;（2）谷物和口粮自给率更能反映中国实际的粮食供需情况;（3）中国谷物自给率在98%以上,口粮自给率高于100%。然而,随着工业化和城市化进程的加快,城市发展对土地的需求越来越大,这会造成耕地被侵占、粮食需求激增等严重问题,口粮生产仍然不能放松,建议未来调整农业结构,稳定小麦、稻米生产。     

我国粮食自给水平目标设定：研究综述与政策启示

确保重要农产品特别是粮食供给,是实施乡村振兴战略的首要任务。粮食自给水平目标设定是粮食安全状况评价和政策制定的基础,直接影响到国家粮食产业发展的战略方向和实施路径。本文通过对已有关于我国粮食自给水平目标设定的文献进行研读,在总结粮食自给率相关概念和回顾国家粮食自给方针演变的基础上,着重对我国粮食自给率目标设定水平、依据、意义,以及自给率变动的原因和产生的影响等问题进行系统梳理。结果显示：现有研究对于我国粮食安全自给水平设定目标尚无明确且统一的判断。研究提出,现阶段应以资源环境承载力为硬约束,以保持粮食生产稳定性为红线,设定粮食总量自给水平目标替代自给率目标,通过充分利用国外资源和国际市场,更好地实现粮食安全保障与生态环境保护的高度统一。     

Nano-selenium controlled cadmium accumulation and improved photosynthesis in indica rice cultivated in lead and cadmium combined paddy soils

Selenium nanoparticles (Se NPs) are less toxic and more biocompatible than selenite or selenate. However, studies involving spraying with Se NPs for reducing accumulation of cadmium (Cd) and lead (Pb) in rice grains have been rarely reported as yet. Herein, indica rice seedlings cultivated in Cd+Pb-spiked paddy soils (denoted as positive control) were sprayed with Se NPs sols for four times from tillering to booting stage. Compared to positive control, 50–100 μmol/L Se NPs downregulated Cd transporters-related genes such as OsLCT1, OsHMA2 and OsCCX2 in leaves and OsLCT1, OsPCR1 and OsCCX2 genes in node I at filling stage. Meanwhile, Se-binding protein 1 was distinctly elevated, involving the repression of Cd and Pb transportation to rice grains. Se NPs also differentially improved RuBP carboxylase and chlorophylls especially some key genes and proteins involving photosynthetic system. Besides, 25–50 μmol/L Se NPs diminished reactive oxygen species overproduction from NADPH oxidases whereas boosted glutathione peroxidase, reducing protein carbonylation in rice seedlings. However, the antioxidant isozymes and oxidatively modified proteins were slightly rebounded at 100 μmol/L. Se contents were noticeably elevated and confirmed to exist as selenomethionine in the rice grains following all the treatments by Se NPs. Thus, the optimal dosage of Se NPs for foliar application is 50 μmol/L, which significantly decreased Cd accumulation, improved photosynthesis and Se enrichment whereas caused no distinct reduction of Pb in the grains. Thus, an appropriate dosage of Se NPs can be conducted to decrease Cd accumulation, improve photosynthesis, and organic Se contents in rice grains.     

Identifying motivations and barriers to minimising household food waste

The amount of food discarded by UK households is substantial and, to a large extent, avoidable. Furthermore, such food waste has serious environmental consequences. If household food waste reduction initiatives are to be successful they will need to be informed by people's motivations and barriers to minimising household food waste. This paper reports a qualitative study of the thoughts, feelings and experiences of 15 UK household food purchasers, based on semi-structured interviews. Two core categories of motives to minimise household food waste were identified: (1) waste concerns and (2) doing the ‘right’ thing. A third core category illustrated the importance of food management skills in empowering people to keep household food waste to a minimum. Four core categories of barriers to minimising food waste were also identified: (1) a ‘good’ provider identity; (2) minimising inconvenience; (3) lack of priority; and (4) exemption from responsibility. The wish to avoid experiencing negative emotions (such as guilt, frustration, annoyance, embarrassment or regret) underpinned both the motivations and the barriers to minimising food waste. Findings thus reveal potentially conflicting personal goals which may hinder existing food waste reduction attempts.     

The onset of surface-enhanced Raman scattering for single-particle detection of submicroplastics

Microplastics represent an emerging environmental problem worldwide, raising ecological and food safety concerns. Compared to microplastics, there is growing evidence of an even higher abundance of submicro- and nanoplastics in the environment, but a reliable monitoring method for detecting these smaller-sized plastics is lacking. Herein we presented the application of surface-enhanced Raman scattering (SERS) for this purpose. Particles of polystyrene (PS; 600 nm) were used as the probe analyte. Gold nanourchins (AuNU; 50 nm), i.e. urchin-shaped nanoparticles with irregular spikes around the core, were used as the SERS-active substrate. The effectiveness of SERS on PS was evaluated at a single-particle level with different numbers of AuNU in order to determine the minimum conditions required for the onset of the SERS effect. Our findings suggest that SERS of a single particle of PS can be induced by as few as 1–5 particles of AuNU, and that the use of excitation wavelength at 785 nm is appropriate to meet the red-shifted surface plasmon resonance of AuNU upon aggregation. These specifications provide additional information for the development of SERS-based tools for detecting plastic particles < 1 µm in food and environmental samples.     

Integrated modelling of foraging behaviour, energy budget and memory properties

A predator's foraging performance is related to its ability to acquire sufficient information on environmental profitability. This process can be affected by the patchy distribution and clustering of food resources and by the food intake process dynamics.We simulated body mass growth and behaviour in a forager acting in a patchy environment with patchy distribution of both prey abundance and body mass by an individual-based model. In our model, food intake was a discrete and stochastic process and leaving decision was based on the estimate of net energy gain and searching time during their foraging activities. The study aimed to investigate the effects of learning processes and food resource exploitation on body mass and survival of foragers under different scenarios of intra-patch resource distribution.The simulation output showed that different sources of resource variability between patches affected foraging efficiency differently. When prey abundance varied across patches, the predator stayed longer in poorest patches to obtain the information needed and its performance was affected by the cost of sampling and the resulting assessment of the environment proved unreliable. On the other hand, when prey body mass, but not abundance, varied among the patches the predator was quickly able to assess local profitability. Both body mass and survival of the predator were greatly affected by learning processes and patterns of food resource distribution.     

Effects of local fisheries and ocean productivity on the northeastern Ionian Sea ecosystem

To better understand the effects of fisheries and ocean productivity on the northeastern Ionian Sea we constructed an Ecopath with Ecosim model with 22 functional groups. Data on biomass, production/biomass, consumption/biomass, and diet for each group were estimated or extrapolated from the literature. Fisheries landings and discards were also included. Temporal trajectories were simulated using Ecosim. The model was fitted with time-series data for the most important groups from 1964 to 2006. Simulations highlighted a decline of top predators and of most of the commercial species since the late 1970s. The model shows that the decline of fish resources was mainly caused by an intensive fishing pressure that occurred in the area until the end of the 1990s and also by changes in primary production that impacted the trajectories of the main functional groups. In particular, simulated changes through time in PP impacted the abundance trends of all the commercial species, showing a cascade-up effect through the ecosystem. The application of Ecopath with Ecosim was a useful tool for understanding the trends of the main functional groups of the northeastern Ionian Sea. The model underlined that management actions are needed to restore and protect target species including marine mammals, pelagic and demersal fishes. In particular, measures to reduce overfishing, illegal fishing activities and to respect existing legislations are in need. Moreover, the adoption of marine protected areas could be an effective management measure to guarantee prey survival and to sustain marine predators.     

Environmental assessment of packaging: The consumer point of view

When marketing environmentally responsible packaged products, the producer is confronted with consumer beliefs concerning the environmental friendliness of packaging materials. When making environmentally conscious packaging decisions, these consumer beliefs should be taken into account alongside the technical guidelines. Dutch consumer perceptions of the environmental friendliness of packaged products are reported and compared with the results of a life-cycle analysis assessment. It is shown that consumers judge environmental friendliness mainly from material and returnability. Furthermore, the consumer perception of the environmental friendliness of packaging material is based on the postconsumption waste, whereas the environmental effects of production are ignored. From the consumer beliefs concerning environmental friendliness implications are deduced for packaging policy and for environmental policy.