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111.
Allen CD 《Environmental management》2009,43(2):346-356
Characterized by expensive housing, high socioeconomic status, and topographic relief, Upper Sonoran Lifestyle communities
are found primarily along the Wildland-Urban Interface (WUI) in the Phoenix, Arizona metro area. Communities like these sprawl
into the wildlands in the United States Southwest, creating a distinct urban fringe. This article, through locational comparison,
introduces and evaluates a new field assessment tool for monitoring anthropogenic impact on soil–vegetation interactions along
the well-maintained multi-use recreational trails in Upper Sonoran Lifestyle region. Comparing data from randomly selected
transects along other multi-use trails with data from a control site revealed three key indicators of anthropogenic disturbances
on soil–vegetation interactions: soil disturbance, vegetation disturbance, and vegetation density. Soil and vegetation disturbance
displayed an average distance decay exponent factor of −0.60, while vegetation density displayed a reverse decay average of
0.60. Other important indicators of disturbance included vegetation type, biological soil crusts, and soil bulk density. The
predictive ability of this new field tool enhances its applicability, offering a powerful rapid ecological assessment method
for monitoring long-term anthropogenic impact in the Upper Sonoran Lifestyle, and other sprawling cities along the WUI. 相似文献
112.
Dongmei Han Xing Liang Menggui Jin Matthew J. Currell Ying Han Xianfang Song 《Environmental management》2009,44(2):243-255
Based on analysis of groundwater hydrochemical and isotopic indicators, this article aims to identify the groundwater flow
systems in the Yangwu River alluvial fan, in the Xinzhou Basin, China. Groundwater δ2H and δ18O values indicate that the origin of groundwater is mainly from precipitation, with local evaporative influence. d-excess values lower than 10% in most groundwaters suggest a cold climate during recharge in the area. Major ion chemistry,
including rCa/rMg and rNa/rCl ratios, show that groundwater salinization is probably dominated by water–rock interaction (e.g.,
silicate mineral weathering, dissolution of calcite and dolomite and cation exchange) in the Yangwu River alluvial fan, and
locally by intensive evapotranspiration in the Hutuo River valley. Cl and Sr concentrations follow an increasing trend in
shallow groundwater affected by evaporation, and a decreasing trend in deep groundwater. 87Sr/86Sr ratios reflect the variety of lithologies encountered during throughflow. The groundwater flow systems (GFS) of the Yangwu
River alluvial fan include local and intermediate flow systems. Hydrogeochemical modeling results, simulated using PHREEQC,
reveal water–rock interaction processes along different flow paths. This modeling method is more effective for characterizing
flow paths in the intermediate system than in the local system. Artificial exploitation on groundwater in the alluvial fan
enhances mixing between different groundwater flow systems. 相似文献
113.
Robert Kase Peter D. Hansen Birgit Fischer Werner Manz Peter Heininger Georg Reifferscheid 《Environmental science and pollution research international》2009,16(1):54-64
Background, aim, and scope The enzyme-linked receptor assay (ELRA) detects estrogenic and anti-estrogenic effects at the molecular level of receptor
binding and is a useful tool for the integrative assessment of ecotoxicological potentials caused by hormonally active agents
(HAA) and endocrine disrupting compounds (EDC). The main advantage of the ELRA is its high sample throughput and its robustness
against cytotoxicity and microbial contamination. After a methodological adaptation to salinity of the ELRA, according to
the first part of this study, which increased its salinity tolerance and sensitivity for 17-β-estradiol, the optimised ELRA
was used to investigate 13 native sediments characterised by different levels of salinity and chemical contamination. The
applicability of the ELRA for routine analysis in environmental assessment was evaluated. Salinity is often a critical factor
for bioassays in ecotoxicological sediment assessment. Therefore, salinity of the samples was additionally adjusted to different
levels to characterise its influence on elution and binding processes of receptor-binding substances.
Materials and methods The ELRA was carried out with the human estrogen receptor α (ER) in a 96-well microplate format using the experimental setup
known from the competitive immunoassay based on ligand–protein interaction. It is an important improvement that a physiologically
relevant receptor was used as a linking protein instead of an antibody. The microplates were coated with a 17-β-estradiol-BSA
conjugate, and dilution series of estradiol and of native sediment samples were added and incubated with the ER. After a washing
step, a biotinylated mouse anti-ER antibody was added to each well. Receptor binding to estradiol, agonistic and antagonistic
receptor binding, were determined by a streptavidin-POD-biotin complex with subsequent measurement of the peroxidase activity
at the wavelength of 450 nm using a commercial ELISA multiplate reader. The sediment elutriates and pore water samples of
sediments were tested in a dilution series to evaluate at which dilution step the receptor-binding potential ends. In the
elution process (see Section 2.1 to 2.2), a method was developed to adjust the salinity to the levels of the reference testings, which offers an appropriate option
to adjust the salinity in both directions. Statistical evaluation was made with a combination of the Mann–Whitney U test and the pT-method.
Results This part of the study characterised the environmental factor ‘salinity’ for prospective applications of the ELRA. Using reference
substances such as 17-β-estradiol, the ELRA showed sigmoid concentration-effect relations over a broad range from 0.05 μg/l
to 100 μg/l under physiological conditions. After methodological optimisation, both sensitivity and tolerance of the assay
against salinity could be significantly raised, and the ELRA became applicable under salinity conditions up to concentrations
of 20.5‰. The mean relative inter-test error (n = 3) was around 11% with reference substances and below 5% for single sediments elutriates in three replicates each. For
sediment testings, the pore water and different salinity-adjusted elutriates of 13 sediments were used. A clear differentiation
of the receptor-binding potential could be reached by application of the pT-method. Thereby, pT-values from one to six could
be assigned to the sediments, and the deviation caused by the different salinity conditions was one pT-value. The mean standard
deviation in the salinity adaptation procedure of the elutriates was below 5%.
Discussion Although the ELRA has already been used for assessments of wastewater, sludge and soil, its applicability for samples to different
salinity levels has not been investigated so far. Even if the ELRA is not as sensitive as the E-screen or the YES-assay, with
regard to reference substances like 17-β-estradiol, it is a very useful tool for pre-screening, because it is able to integrate
both estrogenic as well as anti-estrogenic receptor-binding effects. According to the results of sediment testing, and given
the integrative power to detect different directions of effects, the ELRA shows sufficient sensitivity and salinity tolerance
to discriminate receptor-binding potentials in environmental samples.
Conclusions The optimised ELRA assay is a fast, cost-effective, reliable and highly reproducible tool that can be used for high-throughput
screening in a microplate format in detecting both estrogenic and anti-estrogenic effects. Additionally, the ELRA is robust
against microbial contaminations, and is not susceptible towards cytotoxic interferences like the common cell-culture methods.
The general applicability and sufficient sensitivity of the ELRA was shown in freshwater environments. Marine and brackish
samples can be measured up to salinity levels of 20.5‰.
Recommendations and perspectives In view of the proven sensitivity, functionality and the fastness of the ELRA, it is recommendable to standardise the test
method. At the moment, no adequate in vitro test procedure exists which is standardised to DIN or ISO levels. The E-screen
and the yeast estrogen/androgen screens (YES/YAS) sometimes underlie strong cytotoxic effects, as reported in the first part
of this study. Further development of an ELRA assay using human androgen receptors appears to be very promising to gain information
about androgenic and anti-androgenic effects, too. This would offer a possibility to use the ELRA as a fast and reliable pre-screening
tool for the detection of endocrine potentials, thus minimising time and cost-expensive animal experiments. 相似文献
114.
Degassing of H/He, CFCs and SF6 by denitrification: Measurements and two-phase transport simulations
Ate Visser Joris D. Schaap Hans Peter Broers Marc F.P. Bierkens 《Journal of contaminant hydrology》2009,103(3-4):206-218
The production of N2 gas by denitrification may lead to the appearance of a gas phase below the water table prohibiting the conservative transport of tracer gases required for groundwater dating. We used a two-phase flow and transport model (STOMP) to study the reliability of 3H/3He, CFCs and SF6 as groundwater age tracers under agricultural land where denitrification causes degassing. We were able to reproduce the amount of degassing (R2 = 69%), as well as the 3H (R2 = 79%) and 3He (R2 = 76%) concentrations observed in a 3H/3He data set using simple 2D models. We found that the TDG correction of the 3H/3He age overestimated the control 3He/3He age by 2.1 years, due to the accumulation of 3He in the gas phase. The total uncertainty of degassed 3H/3He ages of 6 years (± 2 σ) is due to the correction of degassed 3He using the TDG method, but also due to the travel time in the unsaturated zone and the diffusion of bomb peak 3He. CFCs appear to be subject to significant degradation in anoxic groundwater and SF6 is highly susceptible to degassing. We conclude that 3H/3He is the most reliable method to date degassed groundwater and that two-phase flow models such as STOMP are useful tools to assist in the interpretation of degassed groundwater age tracer data. 相似文献
115.
Influence of temporally variable groundwater flow conditions on point measurements and contaminant mass flux estimations 总被引:2,自引:0,他引:2
Arno Rein Sebastian Bauer Peter Dietrich Christof Beyer 《Journal of contaminant hydrology》2009,108(3-4):118-133
Monitoring of contaminant concentrations, e.g., for the estimation of mass discharge or contaminant degradation rates, often is based on point measurements at observation wells. In addition to the problem, that point measurements may not be spatially representative, a further complication may arise due to the temporal dynamics of groundwater flow, which may cause a concentration measurement to be not temporally representative. This paper presents results from a numerical modeling study focusing on temporal variations of the groundwater flow direction. “Measurements” are obtained from point information representing observation wells installed along control planes using different well frequencies and configurations. Results of the scenario simulations show that temporally variable flow conditions can lead to significant temporal fluctuations of the concentration and thus are a substantial source of uncertainty for point measurements. Temporal variation of point concentration measurements may be as high as the average concentration determined, especially near the plume fringe, even when assuming a homogeneous distribution of the hydraulic conductivity. If a heterogeneous hydraulic conductivity field is present, the concentration variability due to a fluctuating groundwater flow direction varies significantly within the control plane and between the different realizations. Determination of contaminant mass fluxes is also influenced by the temporal variability of the concentration measurement, especially for large spacings of the observation wells. Passive dosimeter sampling is found to be appropriate for evaluating the stationarity of contaminant plumes as well as for estimating average concentrations over time when the plume has fully developed. Representative sampling has to be performed over several periods of groundwater flow fluctuation. For the determination of mass fluxes at heterogeneous sites, however, local fluxes, which may vary considerably along a control plane, have to be accounted for. Here, dosimeter sampling in combination with time integrated local water flux measurements can improve mass flux estimates under dynamic flow conditions. 相似文献
116.
M.J. Robertson T.G. Measham G. Batchelor R. George R. Kingwell K. Hosking 《Journal of environmental management》2009,90(10):3023-3030
Community and catchment-based approaches to salinity management continue to attract interest in Australia. In one such approach, Catchment Demonstration Initiative (CDI) projects were established by the Western Australian (WA) Government in 2000 for targeted investment in large-scale catchment-based demonstrations of integrated salinity management practices. The aim was to promote a process for technically-informed salinity management by landholders. This paper offers an evaluation of the effectiveness of one CDI project in the central wheatbelt of WA, covering issues including: its role in fostering adoption of salinity management options, the role of research and the technical requirements for design and implementation of on-ground works, the role of monitoring and evaluation, the identification and measurement of public and private benefits, comparison and identification of the place and value of plant-based and engineering-based options, reliance on social processes and impacts of constraints on capacity, management of governance and administration requirements and an appreciation of the value of group-based approaches.A number of factors may reduce the effectiveness of CDI-type approaches in facilitating landholder action to address salinity, many of these are socially-based. Such approaches can create considerable demands on landholders, can be expensive (because of the planning and accountability required) on the basis of dollars per hectare impacted, and can be difficult to garner ownership from all involved. An additional problem could be that few community groups would have the capacity to run such programs and disseminate the new knowledge so that the CDI-type projects can impact outside the focus catchment. In common with many publicly-funded approaches to salinity, we found that direct benefits on public assets are smaller than planned and that results from science-based requirements of monitoring and evaluation have long lead times, causing farmers to either wait for the information or act sooner and take risks based on initial results. We also found that often it is a clear outline of the process that is of most importance in decision making as opposed to the actual results. We identified limitations in regulatory processes and the capacity for local government to engage in the CDI.The opportunities that CDI-type approaches provide centre around the value of its group-based approach. We conclude that they can overcome knowledge constraints in managing salinity by fostering group-based learning, offer a structured process of trialling options so that the costs and benefits can be clearly and transparently quantified, and avoid the costly mistakes and “learning failures” of the past. 相似文献
117.
Michael J. White Daniel E. Storm Michael D. Smolen Hailin Zhang 《Journal of the American Water Resources Association》2009,45(2):397-406
Abstract: Assessment tools to evaluate phosphorus loss from agricultural lands allow conservation planners to evaluate the impact of management decisions on water quality. Available tools to predict phosphorus loss from agricultural fields are either: (1) qualitative indices with limited applicability to address offsite water quality standards, or (2) models which are prohibitively complex for application by most conservation planners. The purpose of this research was to develop a simple interface for a comprehensive hydrologic/water quality model to allow its usage by farmers and conservation planners. The Pasture Phosphorus Management (PPM) Calculator was developed to predict average annual phosphorus (P) losses from pastures under a variety of field conditions and management options. PPM Calculator is a vastly simplified interface for the Soil and Water Assessment Tool (SWAT) model that requires no knowledge of SWAT by the user. PPM Calculator was validated using 33 months of data on four pasture fields in northwestern Arkansas. This tool has been extensively applied in the Lake Eucha/Spavinaw Basin in northeastern Oklahoma and northwestern Arkansas. PPM Calculator allows conservation planners to take advantage of the predictive capacity of a comprehensive hydrologic water quality model typically reserved for use by hydrologists and engineers. This research demonstrates the applicability of existing water quality models in the development of user friendly P management tools. 相似文献
118.
Kristina Cydzik Terri S. Hogue 《Journal of the American Water Resources Association》2009,45(3):702-714
Abstract: This paper investigates application of the Army Corps of Engineers’ Hydrologic Engineering Center Hydrologic Modeling System (HEC‐HMS) to a burned watershed in San Bernardino County, California. We evaluate the HEC‐HMS’ ability to simulate discharge in prefire and postfire conditions in a semi arid watershed and the necessary parameterizations for modeling hydrologic response during the immediate, and subsequent recovery, period after a wildfire. The model is applied to City Creek watershed, which was 90% burned during the Old Fire of October 2003. An optimal spatial resolution for the HEC‐HMS model was chosen based on an initial sensitivity analysis of subbasin configurations and related model performance. Five prefire storms were calibrated for the selected model resolution, defining a set of parameters that reasonably simulate prefire conditions. Six postfire storms, two from each of the following rainy (winter) seasons were then selected to simulate postfire response and evaluate relative changes in parameter values and model behavior. There were clear trends in the postfire parameters [initial abstractions (Ia), curve number (CN), and lag time] that reveal significant (and expected) changes in watershed behavior. CN returns to prefire (baseline) values by the end of Year 2, while Ia approaches baseline by the end of the third rainy season. However, lag time remains significantly lower than prefire values throughout the three‐year study period. Our results indicate that recovery of soil conditions and related runoff response is not entirely evidenced by the end of the study period (three rainy seasons postfire). Understanding the evolution of the land surface and related hydrologic properties during the highly dynamic postfire period, and accounting for these changes in model parameterizations, will allow for more accurate and reliable discharge simulations in both the immediate, and subsequent, rainy seasons following fire. 相似文献
119.
Mohamed Edali Ahmed Aboudheir Raphael Idem 《International Journal of Greenhouse Gas Control》2009,3(5):550-560
New comprehensive numerically solved 1D and 2D absorption rate/kinetics models have been developed, for the first time, to interpret the experimental kinetic data obtained with a laminar jet apparatus for the absorption of carbon dioxide (CO2) in CO2 loaded mixed solutions of mixed amine system of methyldiethanolamine (MDEA) and monoethanolamine (MEA). Three MDEA/MEA weight ratios ranging from 27/03 to 23/07, over a concentration range of 2.316–1.996 kmol/m3 for MDEA and of 0.490–1.147 kmol/m3 for MEA were studied. The models take into account the coupling between chemical equilibrium, mass transfer, and the chemical kinetics of all possible chemical reactions involved in the CO2 reaction with MDEA/MEA solvent. The partial differential equations of the 1D model were solved by two numerical techniques; the finite difference method (FDM) based on in-house coded Barakat–Clark scheme and the finite element method (FEM) based on COMSOL software. The FEM comprehensive model was then used to solve the set of partial differential equations in the 2D cylindrical coordinate system setting. Both FDM and FEM produced very accurate results for both the 1D and 2D models, which were much better than our previously published simplified model. The reaction rate constant obtained for MEA blended into MDEA at 298–333 K was kMEA = 5.127 × 108 exp(−3373.8/T). In addition, the 2D model, for the first time, has provided the concentration profiles of all the species in both the radial and axial directions of the laminar jet, thereby enabling an understanding of the correct sequence in which the reaction steps involved in the reactive absorption of CO2 in aqueous mixed amines occur. 相似文献
120.
基于Petri网的铁路车站安全防护系统建模及可靠性分析 总被引:2,自引:2,他引:0
郑伟 《中国安全科学学报》2009,19(9)
采用单一的随机Petri网对车站线路结构、列车运行过程及车站防护系统建模,基于欧洲电工标准委员会定义的安全目标,确定车站安全防护系统的可靠性需求。对无防护系统的列车入站进行建模和分析,然后基于防护系统功能及可靠性特性,结合列车入站动态特性,对防护系统的功能和可靠性进行建模,并根据安全目标与车站事故率之间的数学关系进行系统的安全分析和可用性分析。其结果表明,车站防护系统的可靠性与乘客的个人风险存在着定量的关系,从而可以依据个人风险的标准来确定防护系统可靠性需求。 相似文献