Assessment of interfacial mass transfer in water-unsaturated soils during vapor extraction

This paper presents results of a numerical investigation of soil vapor extraction (SVE) systems at the laboratory scale. The SVE technique is used to remove volatile chlorinated hydrocarbons (VCHC) from the water-unsaturated soil zone. The developed numerical model solves equations of flow, transport and interfacial mass transfer regarding an isothermal n-component and three-phase system. The mathematical model is based on a simple pore network and phase distribution model and designed to be scaled by a characteristic length. All mathematical expressions are structured into VCHC specific and VCHC non-specific parameters. Furthermore, indicators are introduced that help to separate thermodynamic equilibrium from thermodynamic non-equilibrium domains and to determine the controlling physical parameters. For numerical solution, the system of partial differential equations is discretized by a finite volume method and an implicit Euler time stepping scheme. Computational effort is reduced notably through techniques that enable spatial and temporal adaptivity, through a standard multigrid method as well as through a problem-oriented sparse-matrix storage concept. Computations are carried out in two dimensions regarding the laboratory experiment of Fischer et al. [Water Resour. Res. 32 (12) 1996 3413]. By varying the characteristic length scale of the pore network and phase distribution model, it is shown that the experimental gas phase concentrations cannot be explained only by the volatility and diffusivity of the VCHC. The computational results suggest a sorption process whose significance grows with the aqueous activity of the less or non-polar organic compounds.     

Metals distribution in soils around the cement factory in southern Jordan

Thirty one soil samples were collected from south Jordan around the cement factory in Qadissiya area. The samples were obtained at two depths, 0-10 cm and 10-20 cm and were analyzed by atomic absorption spectrophotometery for Pb, Zn, Cd, Fe, Cu and Cr. Physicochemical factors believed to affect their mobility of metals in soil of the study area were examined such as; pH, TOM, CaCO3, CEC and conductivity. The relatively high concentrations of lead, zinc and cadmium in the soil samples of the investigated area were related to anthropogenic sources such as cement industry, agriculture activities and traffic emissions. It was found that the lead, zinc and cadmium have the highest level in area close to the cement factory, while the concentration of chromium was low. This study indicate that all of the metals are concentrated on the surface soil, and decreased in the lower part of the soil, this due to reflects their mobility and physical properties of soil and its alkaline pH values. The use of factor analysis showed that anthropogenic activities seem to be the responsible source of pollution for metals in urban soils.     

Environmental impact of the Gulf War: An integrated preliminary assessment

This article provides an objective integrated environmental impact assessment of the Gulf War consequences. The environmental damage was evaluated and found to be significantly exaggerated by the media and speculators. The total amount of burned crude oil was calculated to be 52.5 million metric tons. Most air pollution field measurements were comparable to those found in Western cities. The health impact associated with such exposure was found to be minimal. The total amount of oil released into the marine environment ranged between 2 and 4 million barrels, much less than the early estimation of 12–14 million barrels. The marine environment is expected to recover much faster than earlier anticipations. Unlike water and air, soil pollution is likely to persist for some years to come.     

RESEARCH: Managing Mountainous Degraded Landscapes After Farmland Abandonment in the Central Spanish Pyrenees

Genista scorpius. Under a dense shrub cover both runoff and sediment yield are strongly controlled. As the shrub cover becomes open, sediment yield and runoff increase greatly. A dense herbaceous cover yields high runoff coefficients but moderate soil losses. From the results obtained, the possibility of abandoned field reclamation by means of selective clearing of scrub is discussed.     

Ground flora trampling studies: Five years after closure

Trampling as an ecological factor is a major concern of the management of park, forest, nature preserves, and wilderness areas as recreational resources. Of particular importance to the management concept of carrying capacity is the relative resistance of native plant communities, to trampling and the resilience or the capacity of impacted communities to recover. This information can be used by management to establish seasonal use limits to prevent irreversible degradation of these resources. The purpose of this study was to follow the recolonizaton of experimental trail surfaces barren of vegetative cover and hiked at three levels of use intensity. Results of this study indicate that soil compaction as measured by soil penetration resistance increased progressively with use level while the total number of species, species diversity, and dominant index scores declined. A major finding was that the greatest degree of change occurred at the first level of hiking, indicating that major floristic measures were most affected by the least amount of hiking. Recolonization of impacted areas that received 100 trampling passes as measured by plant cover, dominant indices, floristic dissimilarity, and species diversity was similar to areas receiving four and eight times more trampling, despite major differences in soil penetration resistance. These data suggest limited use delivered at one time can be as damaging as increasing levels of use delivered at over time.     

Rainfall Response of Degraded Soil Following Reforestation in the Copper Basin, Tennessee, USA

2 Copper Basin in southeastern Tennessee became the site of increasingly extensive and successful reforestation efforts. To determine the effectiveness of more than 50 years of reforestation efforts, we compared rainfall infiltration, sediment detachment, and soil organic matter of reforested sites to those properties of unvegetated sites and forested reference sites outside the basin. Results of 54 rainfall simulation experiments conducted in zones of the basin known to have been planted during different decades demonstrate that hydrologic recovery of soils in the Copper Basin lags significantly behind the establishment of tree cover and the protection offered by vegetation against soil erosion. Soils in new “forests” have significantly less organic matter and lower infiltration than forests more than 50 years old. The long-term persistence of low infiltration rates serves as a reminder that, at sites where the A and B soil horizons have been lost, restoration of the hydrologic function of a landscape requires decades, at least.     

MACROSCALE HYDROLOGIC MODELING FOR REGIONAL CLIMATE ASSESSMENT STUDIES IN THE SOUTHEASTERN UMTED STATES1

ABSTRACT: A macroscale hydrologic model is developed for regional climate assessment studies under way in the southeastern United States. The hydrologic modeling strategy is developed to optimize spatial representation of basin characteristics while maximizing computational efficiency. The model employs the “grouped response unit” methodology, which follows the natural drainage pattern of the area. First order streams are delineated and their surface characteristics are tested so that areas with statistically similar characteristics can be combined into larger computational zones for modeling purposes. Hydrologic response units (HRU) are identified within the modeling units and a simple three‐layer water balance model, Soil and Water Assessment Tool (SWAT), is executed for each HRU. The runoff values are then convoluted using a triangular unit hydrograph and routed by Muskingum‐Cunge method. The methodology is shown to produce accurate results relative to other studies, when compared to observations. The model is used to evaluate the potential error in hydrologic assessments when using GCM predictions as climatic input in a rainfall‐runoff dominated environment. In such areas, the results from this study, although limited in temporal and spatial scope, appear to imply that use of GCM climate predictions in short term quantitative analyses studies in rainfall‐runoff dominated environments should proceed with caution.     

Tijuana Childhood Lead Risk Assessment Revisited: Validating a GIS Model with Environmental Data

The objective of this research was to determine the spatial distributions of childhood lead poisoning and soil lead contamination in urban Tijuana. The Bocco–Sanchez model of point-source emissions was evaluated in terms of validity and reliability. We compared the model's predicted vulnerable populations with observed cases of childhood lead poisoning in Tijuana, identified fixed point sources in the field, and analyzed 76 soil samples from 14 sites. The soil lead results were compared to the blood lead analyses performed on Tijuana children whose blood lead levels were ≥10 μg/dL, who reported that they did not use lead-glazed ceramics for cooking or storing food (n = 63). Using GIS, predicted vs observed risk areas were assessed by examining spatial patterns, including the distribution of cases per designated risk area. Chi-square analysis of expected vs observed values did not differ significantly at the p = 0.02 level, showing that the model was strikingly accurate in predicting the distribution of subjects with elevated blood lead. Results reveal that while point sources are significant, other sources of lead exposure are also important. The relative public health risk from exposure to lead in an urban setting may be assessed by distinguishing among sources of exposure and associating concentrations to blood lead levels. The results represent an iterative approach in environmental health research by linking environmental and human biomarker lead concentrations and using these results to validate an environmental model of risk to lead exposure.     

Combined use of GIS and environmental indicators for assessment of chemical, physical and biological soil degradation in a Spanish Mediterranean region

Soil is one of the main non-renewable natural resources in the world. In the Valencian Community (Mediterranean coast of Spain), it is especially important because agriculture and forest biomass exploitation are two of the main economic activities in the region. More than 44% of the total area is under agriculture and 52% is forested. The frequently arid or semi-arid climate with rainfall concentrated in few events, usually in the autumn and spring, scarcity of vegetation cover, and eroded and shallow soils in several areas lead to soil degradation processes. These processes, mainly water erosion and salinization, can be intense in many locations within the Valencian Community. Evaluation of soil degradation on a regional scale is important because degradation is incompatible with sustainable development. Policy makers involved in land use planning require tools to evaluate soil degradation so they can go on to develop measures aimed at protecting and conserving soils. In this study, a methodology to evaluate physical, chemical and biological soil degradation in a GIS-based approach was developed for the Valencian Community on a 1/200,000 scale. The information used in this study was obtained from two different sources: (i) a soil survey with more than 850 soil profiles sampled within the Valencian Community, and (ii) the environmental information implemented in the Geo-scientific map of the Valencian Community digitised on an Arc/Info GIS. Maps of physical, chemical and biological soil degradation in the Valencian Community on a 1/200,000 scale were obtained using the methodology devised. These maps can be used to make a cost-effective evaluation of soil degradation on a regional scale. Around 29% of the area corresponding to the Valencian Community is affected by high to very high physical soil degradation, 36% by high to very high biological degradation, and 6% by high to very high chemical degradation. It is, therefore, necessary to draw up legislation and to establish the policy framework for actions focused on preventing soil degradation and conserving its productive potential.     

Sustainability of farmers' soil fertility management practices: a case study in the North China Plain

To ensure regional self-sufficiency and adequate rural livelihoods in the North China Plain (NCP), tremendous efforts were made over the last two decades by the Chinese government to raise the productivity of crops, despite increasing pressure on the land caused by a growing population. Emphasis was placed on high external input use, especially for wheat, maize and cotton, ignoring the particularities and limitations of the natural resource base. This study assesses the sustainability of current soil fertility management practices on the basis of selected location-specific indicators, such as fertilizer use, soil pH, soil organic matter content, levels of nitrogen (N), phosphorus (P) and potassium (K) in the soil, and identifies determining factors of the yield and environmental impacts of inputs use. Data used for the analysis were gathered from soil tests, groundwater and chive plant tests, household surveys, and statistical yearbooks. Stepwise multiple regression analysis is applied to determine factors affecting the yields. The study revealed unbalanced use of nutrients. Organic fertilizers (manure, crop residues) and K are insufficiently applied, whereas N and P are considerably overused in comparison with recommended doses. The intensive cropping in the area using high-input technologies -particularly fertilizer- has resulted in a remarkable general enhancement of crop productivity and improvement of soil fertility over the years. The yield of wheat and maize has increased 173 and 180 kg ha(-1) annually from 1982 to 2000, respectively and soil fertility status also improved over the years and the values of the selected indicators are within the borderline for sustainability. Irrigation water, FYM application, and total labor used during the cultivation season (with the exception of cotton and chive) for production are the main factors determining the yields of four major crops under study, while popularly and overly used N did not appear to be a significant factor affecting the yield. Its overuse, however, leads to leaching of nitrate into groundwater and nitrate enrichment of vegetables. Of 20 groundwater samples, 16 showed nitrate levels between 55 and 180 mg l(-1), which exceeds recommendations for drinking water (相似文献