燃气火焰中热力型NOx的生成与控制

燃气火焰中热力型ＮＯｘ以ＮＯ为主，以ＮＯ为主，燃烧温度对ＮＯ生成起决定作用，空气系数也主要通过改变燃烧温度影响ＮＯｘ生成。燃烧温度大于１８００Ｋ时，有较多ＮＯ生成。降低燃烧温度与保持高效燃烧相协调是控制ＮＯｘ生成的关键。     

堆肥式生态厕所处理人类排泄物变化规律研究

选用秸秆和木屑的混合物作为生态厕所反应基质,采用日本研制生产的s-15型生态厕所为实验装置,通过好氧微生物的氧化分解,将粪便转化为无臭味的水、二氧化碳和较干燥的有机肥.实验模拟实际生活,通过5～6人正常使用方式投加物料,旨在研究生态厕所在现实生活中处理人类排泄物的变化规律.通过分析实验过程中的物料投加量、使用周期、温度、含水率等指标的变化.发现生态厕所使用的第5～12周,温度在50℃左右,含水率稳定在50%～60%之间时生态厕所减量化效果最为理想.     

半干法烟气脱硫工艺中的近绝热饱和温度

介绍了近绝热饱和温度在半干法烟气脱硫工艺中的概念。根据半干法烟气脱硫中试试验的试验数据及工业试验装置的运行经验 ,论述了近绝热饱和温度对脱硫系统的性能及运行的影响。通过对影响近绝热饱和温度的因素的分析 ,提出了在设计和运行过程中 ,控制和选用近绝热饱和温度的可行方案     

DGGE/TGGE方法在土壤微生物群落研究中的应用

变性梯度凝胶电泳(DGGE)或温度梯度凝胶电泳(TGGE)已成为环境微生物学领城比较微生物群落多样性和检测种群动力学的重要分子手段,本文介绍了DGGE/TGGE方法在土壤微生物群落研究中的应用进展及存在的缺陷,并提出了改进建议.     

立井井壁破坏应力研究

应用利用弹性理论、温度应力场理论、热胀冷缩原理 ,对立井井壁破坏应力进行了较为精确的受力分析 ,给出了立井井壁应力分布规律的解析式。在整个理论的分析过程中 ,笔者着重分析了井壁应力中负摩擦力的影响 ,对负摩擦力引起的井壁应力进行了较为细致的计算 ,并通过具体算例进行了说明。笔者研究的结果 ,为井壁设计的理论提供了新的依据 ,同时对煤矿设计及煤矿工程应用有重要实用价值。     

Preparation of n-Octadecane@MF resin microPCMs and its application in temperature control of esterification reactions

Reaction thermal runaway accidents occur frequently and occupy a high proportion in chemical accidents. Reducing accidents by controlling reaction temperature is of great implication to enhance the safety level of chemical processes. Phase change materials (PCMs) have a good energy storage potential, which can rapidly convert the reaction exotherm in the reaction process into its own phase change latent heat, urgently control the reaction temperature, and enhance the process thermal safety level. In this study, using n-octadecane as the core and melamine-formaldehyde (MF) resin as the shell, microencapsulated phase change materials (microPCMs) was made, which has a smooth spherical shape, good thermal stability, and a phase change enthalpy up to 162.87 J/g. The homogeneous esterification reaction of 2-butanol (2 B) and propionic anhydride (PA) was selected as the target reaction, and then the reaction was scaled up equivalently to investigate the effect of amplification to the reaction system. The results indicated that the temperature control of the esterification reaction system by microPCMs is the synergy between physical inhibition and chemical inhibition. The reaction temperature could be controlled by adding microPCMs, and the temperature control effect improved with the increase of microPCMs addition. In large scale reactors, microPCMs still has certain temperature control ability after being added.     

基于BP神经网络的红外可燃气体探测器温度补偿研究

针对红外可燃气体探测器输出电压随温度变化,而又缺乏理论补偿公式的情况,提出采用BP神经网络对基于NDIR的可燃气体探测器进行温度补偿的方法,解决了以往温度补偿通过硬件补偿带来的探测器体积大、重量增加的弱点;与已有的软件补偿方法相比,BP神经网络方法通过对数据进行训练、学习获得温度补偿模型,得到了较好的结果,使得红外可燃气体探测器具有较宽的使用温度范围。     

受限透视角度下超声波CT温度场诊断技术

超声波CT一种热测量方法,具有不接触、对温度场不干扰的优点。本文发展一种新的超声波CT再现方法,用于解决受限透视角度所产生的信息量不足的问题。新的超声波CT再现算法建立在逆矩阵变换的基础上,它不同于通常的采用SL过滤器的所谓FBPCT再现方式。论文中描述了三种CT迭代再现算法,用计算机模拟结果和三维温度场测量实验数据验证了再现算法的可靠性。同时根据计算和实验结果,建议在受限的透视角度情况下,迭代方法采用修正的正则最小二乘法CGM是合适的。     

The potential effect of differential ambient and deployment chamber temperatures on PRC derived sampling rates with polyurethane foam (PUF) passive air samplers

Performance reference compound (PRC) derived sampling rates were determined for polyurethane foam (PUF) passive air samplers in both sub-tropical and temperate locations across Australia. These estimates were on average a factor of 2.7 times higher in summer than winter. The known effects of wind speed and temperature on mass transfer coefficients could not account for this observation. Sampling rates are often derived using ambient temperatures, not the actual temperatures within deployment chambers. If deployment chamber temperatures are in fact higher than ambient temperatures, estimated sampler-air partition coefficients would be greater than actual partition coefficients resulting in an overestimation of PRC derived sampling rates. Sampling rates determined under measured ambient temperatures and estimated deployment chamber temperatures in summer ranged from 7.1 to 10 m³ day⁻¹ and 2.2-6.8 m³ day⁻¹ respectively. These results suggest that potential differences between ambient and deployment chamber temperatures should be considered when deriving PRC-based sampling rates.     

Biodegradation kinetics of selected brominated flame retardants in aerobic and anaerobic soil

The purpose of the present study was to investigate the biodegradation kinetics in aerobic and anaerobic soil of the following brominated flame retardants: 2,4,4′-tribromodiphenyl ether (BDE 28), decabromodiphenyl ether (BDE 209), tetrabromobisphenol A (TBBPA), 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH), 2,4,6-tribromophenol (246BrPh), and hexabromobenzene (HxBrBz). For comparison, the biodegradation of the chlorinated compounds 2,4,4′-trichlorodiphenyl ether (CDE 28), 2,4,6-trichlorophenol (246ClPh), hexachlorobenzene (HxClBz), and 2,2′,4,4′,5,5′-hexachlorobiphenyl (PCB 153) was also assessed. In aerobic soil, BDE 209 showed no significant degradation during the test period, but concentrations of the other BFRs declined, with half-lives decreasing in the following order: BDE 28 > TBBPA > TBECH > HxBrBz > 246BrPh. Declines in almost the same order were observed in anaerobic soil: BDE 28, BDE 209 > TBBPA > HxBrBz > TBECH >246BrPh.