Sorption and desorption kinetics of diuron,fluometuron, prometryn and pyrithiobac sodium in soils

Abstract

The sorption and desorption characteristics of four herbicides (diuron, fluometuron, prometryn and pyrithiobac‐sodium) in three different cotton growing soils of Australia was investigated. Kinetics and equilibrium sorption and desorption isotherms were determined using the batch equilibrium technique. Sorption was rapid (> 80% in 2 h) and sorption equilibrium was achieved within a short period of time (ca 4 h) for all herbicides. Sorption isotherms of the four herbicides were described by Freundlich equation with an r² value > 0.98. The herbicide sorption as measured by the distribution coefficient (K_d) values ranged from 3.24 to 5.71 L/kg for diuron, 0.44 to 1.13 L/kg for fluometuron, 1.78 to 6.04 L/kg for prometryn and 0.22 to 0.59 L/kg for pyrithiobac‐sodium. Sorption of herbicides was higher in the Moree soil than in Narrabri and Wee Waa soils. When the K_d values were normalised to organic carbon content of the soils (K_oC), it suggested that the affinity of the herbicides to the organic carbon increased in the order: pyrithiobac‐sodium < fluometuron < prometryn < diuron. The desorption isotherms were also adequately described by the Freundlich equation. For desorption, all herbicides exhibited hysteresis and the hysteresis was stronger for highly sorbed herbicides (diuron and prometryn) than the weakly sorbed herbicides (fluometuron and pyrithiobac‐sodium). Hysteresis was also quantified as the percentage of sorbed herbicides which is not released during the desorption step ω = [n_ad / n_de ‐1] x 100). Soil type and initial concentration had significant effect on ω. The effect of sorption and desorption properties of these four herbicides on the off‐site transport to contaminate surface and groundwater are also discussed in this paper.     

The effects of triclopyr on 2,4‐D mineralization in two soils

Abstract

The effects of the herbicide triclopyr (3,5,6‐trichloro‐2‐pyridinyloxyacetic acid) on the mineralization of 2,4‐D (2,4‐dichlorophenoyxacetic acid) in two soils which differed in their histories of prior exposure to the two herbicides were investigated. The relative effects of triclopyr on 2,4‐D mineralization and most probable numbers of 2,4‐D degraders were dependent upon the soil. Triclopyr was shown to increase 2,4‐D mineralization rates in a soil which had been exposed to both 2,4‐D and triclopyr, but decreased the mineralization rate of 2,4‐D and inhibited the increase of most probable numbers of 2,4‐D degraders in a soil that had not been directly exposed to either herbicide.     

Management Decentralization and Montane Forest Conditions in Tanzania

Abstract: We examined how differences in local forest‐management institutions relate to disparate anthropogenic forest disturbance and forest conditions among three neighboring montane forests in Tanzania under centralized, comanaged, or communal management. Institutional differences have been shaped by decentralization reforms. We conducted semistructured interviews with members of forest management committees, local government, and village households and measured anthropogenic disturbance, tree structure, and species composition in forest plots. We assessed differences in governance system components of local institutions, including land tenure, decision‐making autonomy by forest users, and official and de facto processes of rule formation, monitoring, and enforcement among the three management strategies. We also assessed differences in frequencies of prohibited logging and subsistence pole cutting, and measures of forest condition. An adjacent research forest served as an ecological reference for comparison of forest conditions. Governance was similar for comanaged and centralized management, whereas communal managers had greater tenure security and decision‐making autonomy over the use and management of their forest. There was significantly less illegal logging in the communal forest, but subsistence pole cutting was common across all management strategies. The comanaged forest was most disturbed by recent logging and pole cutting, as were peripheral areas of the larger centralized forest. This manifested in more degraded indicators of forest conditions (lower mean tree size, basal area, density of trees ≥ 90 cm dbh, and aboveground biomass and higher overall stem density). Greater tenure security and institutional autonomy of the communal strategy contributed to more effective management, less illegal logging, and maintenance of good forest conditions, but generating livelihood benefits was a challenge for both decentralized strategies. Our results underscore the importance of well‐designed institutional arrangements in forest management and illustrate mechanisms for improved forest governance and conservation in the context of Tanzanian decentralization reforms.     

Analytical philosophy and planning theory

This article examines the potential contribution of analytical philosophy to planning theory. In contrast to some recent discussions it takes as its starting point town planning as actually practised, and recognises the ideological framework within which, for the most part, twentieth century analytical philosophy has been conducted. It concludes that knowledge of philosophy may be of some limited use to the planning theorist.     

Territorial planning,environmental issues and social appraisal: some general implications of ‘new’ assessment methodologies

The paper attempts to conceptualise a range of problems arising from project appraisals. The author presents some general considerations concerning the role of social appraisal in territorial planning, the theoretical weaknesses of cost‐benefit analysis in assessing the effects of projects on territorial resources and some questions relating to assessment methodologies and the welfare foundations of social appraisal within planning practices. The author moves away from evaluation as a technical process towards one which also incorporates ‘practical’ knowledge in a process of argumentation.     

The grassroot development planning process: the role of physical planning in the rural environment

The concern of this paper is with the spatial consequences of development in a given rural setting and the way in which physical planning fits into the revival of a dying rural area, particularly in Third World Countries. It is based on experience derived from Dekinal in Benue State, Nigeria and endeavours to define a rural area by briefly discussing its characteristics and highlighting its problems. It proposes a comprehensive development planning process to induce development based on available resources.     

HYDROLOGIC MODELING OF A BIOINFILTRATION BEST MANAGEMENT PRACTICE1

ABSTRACT: The goal of this research was to develop a methodology for modeling a bioinfiltration best management practice (BMP) built in a dormitory area on the campus of Villanova University in Pennsylvania. The objectives were to quantify the behavior of the BMP through the different seasons and rainfall events; better understand the physical processes governing the system's behavior; and develop design criteria. The BMP was constructed in 2001 by excavating within an existing traffic island, backfilling with a sand/soil mixture, and planting with salt tolerant grasses and shrubs native to the Atlantic shore. It receives runoff from the asphalt (0.26 hectare) and turf (0.27 hectare) surfaces of the watershed. Monitoring supported by the hydrologic model shows that the facility infiltrates a significant fraction of the annual precipitation, substantially reducing the delivery of nonpoint source pollution and erosive surges downstream. A hydrologic model was developed using HEC‐HMS to represent the site and the BMP using Green‐Ampt and kinematic wave methods. Instruments allow comparison of the modeled and measured water budget parameters. The model, incorporating seasonally variable parameters, predicts the volumes infiltrated and bypassed by the BMP, confirming the applicability of the selected methods for the analysis of bioinfiltration BMPs.     

AN ECONOMIC ASSESSMENT OF GROUND WATER RECHARGE IN THE TUCSON BASIN1

ABSTRACT: Bringing water from Colorado River via the Central Arizona Project was perceived as the sole solution for Tucson Basin's water problem. Soon after Central Arizona Project's water arrived in Tucson in 1992, its quality provoked a quarrel over its use for potable purposes. A significant outcome of that quarrel was the enactment of the 1995 Proposition 200. The Proposition 200 precludes the use of Central Arizona Project's water for potable purposes, unless it is treated. Yet, it encourages using it for non‐potable purposes and for replenishing the Tucson aquifer through recharge. This paper examines the economic issues involved in utilizing Central Arizona Project's water for recharge. Four planning scenarios were designed to measure and compare the costs and benefits with and without Central Arizona Project's water recharge. Cost‐benefit analysis was utilized to measure recharge costs and benefits and to derive a rough estimate of cost savings from preventing land subsidence. The results indicate that the institutional requirements can be met with Central Arizona Project's water recharge. The economic benefits from reducing pumping cost and saving groundwater are not economically significant. Yet, when combining the use of Central Arizona Project's water for recharge and non‐potable purposes, it demonstrates positive net economic benefits.     

PRECIPITATION CHANGES FROM 1956 TO 1996 ON THE WALNUT GULCH EXPERIMENTAL WATERSHED1

ABSTRACT: The climate of Southern Arizona is dominated by summer precipitation, which accounts for over 60 percent of the annual total. Summer and non‐summer precipitation data from the USDA‐ARS Walnut Gulch Experimental Watershed are analyzed to identify trends in precipitation characteristics from 1956 to 1996. During this period, annual precipitation increased. The annual precipitation increase can be attributed to an increase in precipitation during non‐summer months, and is paralleled by an increase in the proportion of annual precipitation contributed during non‐summer months. This finding is consistent with previously reported increases in non‐summer precipitation in the southwestern United States. Detailed event data were analyzed to provide insight into the characteristics of precipitation events during this time period. Precipitation event data were characterized based on the number of events, event precipitation amount, 30‐minute event intensity, and event duration. The trend in non‐summer precipitation appears to be a result of increased event frequency since the number of events increased during nonsummer months, although the average amount per event, average event intensity, and average event duration did not. During the summer “monsoon” season, the frequency of recorded precipitation events increased but the average precipitation amount per event decreased. Knowledge of precipitation trends and the characteristics of events that make up a precipitation time series is a critical first step in understanding and managing water resources in semiarid ecosystems.     

Physical and Temporal Isolation of Mountain Headwater Streams in the Western Mojave Desert,Southern California1

Abstract: Streams draining mountain headwater areas of the western Mojave Desert are commonly physically isolated from downstream hydrologic systems such as springs, playa lakes, wetlands, or larger streams and rivers by stream reaches that are dry much of the time. The physical isolation of surface flow in these streams may be broken for brief periods after rainfall or snowmelt when runoff is sufficient to allow flow along the entire stream reach. Despite the physical isolation of surface flow in these streams, they are an integral part of the hydrologic cycle. Water infiltrated from headwater streams moves through the unsaturated zone to recharge the underlying ground‐water system and eventually discharges to support springs, streamflow, isolated wetlands, or native vegetation. Water movement through thick unsaturated zones may require several hundred years and subsequent movement through the underlying ground‐water systems may require many thousands of years – contributing to the temporal isolation of mountain headwater streams.