Characterization and prediction of highway runoff constituent event mean concentration

Highway stormwater runoff quality data were collected from throughout California during 2000-2003. Samples were analyzed for conventional pollutants (pH, conductivity, hardness, and temperature); aggregates (TSS, TDS, TOC, DOC); total and dissolved metals (As, Cd, Cr, Cu, Ni, Pb, and Zn); and nutrients (NO(3)-N, TKN, total P, and ortho-P). Storm event and site characteristics for each sampling site were recorded. A statistical summary for chemical characteristics of highway runoff is provided based on statewide urban and non-urban highways. Constituent event mean concentrations (EMCs) were generally higher in urban highways than in non-urban highways. The chemical characteristics of highway runoff in California were compared with national highway runoff chemical characterization data. The results obtained in California were generally similar to those found in other states. The median EMC for Pb measured in studies conducted in previous decades was much higher than the current median Pb EMC in California. The lower Pb EMC in California compared to previous highway runoff monitoring is believed to be due to the elimination of leaded gasoline. An attempt was also made to identify surrogate constituents within a general family of water quality categories using Spearman correlations and selected pairs with Spearman coefficients greater than 0.8. The strongest correlations were observed among parameters associated with dissolved minerals (EC, TDS, and chloride); organic carbon (TOC and DOC); petroleum hydrocarbons (TPH and O & G); and particulate matter (TSS and turbidity). Within the metals category, total iron concentration was highly correlated with most total metal concentrations. The correlations between total and dissolved concentrations were all less than 0.8, even between total and dissolved concentrations of the same metals. Multiple linear regression (MLR) analyses were performed to evaluate the impact of various site and storm event variables on highway runoff constituent EMCs. Parameters found to have significant impacts on highway runoff constituent EMCs include: total event rainfall (TER); cumulative seasonal rainfall (CSR); antecedent dry period (ADP); contributing drainage area (DA); and annual average daily traffic (AADT). Surrounding land use and geographic regions were also determined to have a significant impact on runoff quality. The MLR model was also used to predict constituent EMCs. Model performance determined by comparing predicted and measured values showed good agreement for most constituents.     

Channel and Perennial Flow Initiation in Headwater Streams: Management Implications of Variability in Source-Area Size

Despite increasing attention to management of headwater streams as sources of water, sediment, and wood to downstream rivers, the extent of headwater channels and perennial flow remain poorly known and inaccurately depicted on topographic maps and in digital hydrographic data. This study reports field mapping of channel head and perennial flow initiation locations in forested landscapes underlain by sandstone and basalt lithologies in Washington State, USA. Contributing source areas were delineated for each feature using a digital elevation model (DEM) as well as a Global Positioning System device in the field. Systematic source area–slope relationships described in other landscapes were not evident for channel heads in either lithology. In addition, substantial variability in DEM-derived source area sizes relative to field-delineated source areas indicates that in this area, identification of an area–slope relationship, should one even exist, would be difficult. However, channel heads and stream heads, here defined as the start of perennial flow, appear to be co-located within both of the lithologies, which together with lateral expansion and contraction of surface water around channel heads on a seasonal cycle in the basalt lithology, suggest a controlling influence of bedrock springs for that location. While management strategies for determining locations of channel heads and perennial flow initiation in comparable areas could assign standard source area sizes based on limited field data collection within that landscape, field-mapped source areas that support perennial flow are much smaller than recognized by current Washington State regulations.     

Recharge processes drive sulfate reduction in an alluvial aquifer contaminated with landfill leachate

Natural attenuation of contaminants in groundwater depends on an adequate supply of electron acceptors to stimulate biodegradation. In an alluvial aquifer contaminated with leachate from an unlined municipal landfill, the mechanism of recharge infiltration was investigated as a source of electron acceptors. Water samples were collected monthly at closely spaced intervals in the top 2 m of the saturated zone from a leachate-contaminated well and an uncontaminated well, and analyzed for delta(18)O, delta(2)H, non-volatile dissolved organic carbon (NVDOC), SO(4)(2-), NO(3)(-) and Cl(-). Monthly recharge amounts were quantified using the offset of the delta(18)O or delta(2)H from the local meteoric water line as a parameter to distinguish water types, as evaporation and methanogenesis caused isotopic enrichment in waters from different sources. Presence of dissolved SO(4)(2-) in the top 1 to 2 m of the saturated zone was associated with recharge; SO(4)(2-) averaged 2.2 mM, with maximum concentrations of 15 mM. Nitrate was observed near the water table at the contaminated site at concentrations up to 4.6 mM. Temporal monitoring of delta(2)H and SO(4)(2-) showed that vertical transport of recharge carried SO(4)(2-) to depths up to 1.75 m below the water table, supplying an additional electron acceptor to the predominantly methanogenic leachate plume. Measurements of delta(34)S in SO(4)(2-) indicated both SO(4)(2-) reduction and sulfide oxidation were occurring in the aquifer. Depth-integrated net SO(4)(2-) reduction rates, calculated using the natural Cl(-) gradient as a conservative tracer, ranged from 7.5x10(-3) to 0.61 mM.d(-1) (over various depth intervals from 0.45 to 1.75 m). Sulfate reduction occurred at both the contaminated and uncontaminated sites; however, median SO(4)(2-) reduction rates were higher at the contaminated site. Although estimated SO(4)(2-) reduction rates are relatively high, significant decreases in NVDOC were not observed at the contaminated site. Organic compounds more labile than the leachate NVDOC may be present in the root zone, and SO(4)(2-) reduction may be coupled to methane oxidation. The results show that sulfur (and possibly nitrogen) redox processes within the top 2 m of the aquifer are directly related to recharge timing and seasonal water level changes in the aquifer. The results suggest that SO(4)(2-) reduction associated with the infiltration of recharge may be a significant factor affecting natural attenuation of contaminants in alluvial aquifers.     

村镇小型生活垃圾热处理炉底渣的理化特性

小型垃圾热处理设备可实现就地处置,节约运输成本,目前在中国山区、丘陵地带的村镇得到广泛应用.为了解村镇小型生活垃圾热处理炉底渣的理化特性及其影响因素,对中国云南、贵州、安徽村镇实际运行的小型生活垃圾热处理设备产生的底渣进行取样,分析其热灼减率、物理组成、化学组成、晶相组成、重金属含量和浸出特性,探讨处理工艺、地域及季节...     

风险社会中突发事件的特征与处置理念探析

突发性事件由于其本身所具有突发性、紧急性、危重性、复杂性、关联性、广泛性、政治性和不确定性等特征，所以其负面性影响很大，往往可能成为激发社会矛盾、进而爆发政治、经济和社会危机的直接原因。而经济转轨、社会转型、利益群体多元化等许多不稳定的因素，对局部地区乃至全国的经济发展和社会稳定构成了潜在威胁。在这样一个具有诸多风险因素的社会，由此而引发的突发事件又有形式多元化、规模扩大化、形态群体化、影响辐射化、目标国际化等特点。所以，在现阶段，处置突发事件的理念必须适应这种风险社会的公共危机特点，做到危机缓和，未病先防；以人为本，取信于民；利益调和，治病求本。     

THROUGHFALL IN PLANTED STANDS OF FOUR SOUTHERN PINE SPECIES IN EAST TEXAS1

Throughfall was measured during 1978–79 beneath the canopies of adjacent stands of four major southern pine species, all on identical soil type and topography in the Stephen F. Austin Experimental Forest. Observations from 44 storms in a randomized network of 15, 5.08 cm PVC gages in a 0.4 ha plot of each species showed that throughfall expressed as percent of storm precipitation, is greatest under longleaf pine and least under loblolly pine; throughfall under shortleaf and slash pine did not differ significantly. Generally, through-fall decreased with storm size and intensity, with distance from the nearest tree stem, and is greater during summer half-year (May–October). Canopy drips, apparently accounting for the greater throughfall for the gage position closer to the stems, were more numerous than reported elsewhere. The 5.08 cm PVC gages proved to be acceptable substitutes for standard nonrecording gages in measuring throughfall. A network of 15 such gages was sufficient to sample throughfall data with 90 percent accuracy in each of the four southern pine plantations.     

WATER-BASED ACTIVITY INVOLVEMENT FOR RECREATION CONSUMERS AT STATE,FEDERAL, LOCAL,OR PRIVATE FACILITIES1

ABSTRACT: The water-based activity involvement of participants at state and federal and local and private facilities identified by using participation rate groups is examined. No differences between participant groups within activities based on socio-economic characteristics were found. However, groups of highly active individuals were identified at both types of properties. It is suggested that social action system variables be added to traditional social aggregate variables to assist the understanding of leisure involvement.     

家庭装修与选材

装修材料的正确选择是完善空间环境设计的主要要素,本文根据目前市场上一些流行的装修材料的特性进行全方位的分析,力求根据空间自身的特点,合理的运用材料本身的设计语言,创造出更加适用、丰富、绿色的可延展性的意境空间。     

南充市大气PM10污染水平的分布特征

本文对南充市环境监测站2002年城区5个监测点的PM10监测资料进行了分析。结果发现南充市大气污染物PM10污染严重，并存在明显的空间和季节差异。嘉陵环保局测点污染最严重，西南石油学院和炼油厂测点污染相对较轻；冬季污染最严重，夏季污染程度最小。最后，结合其他相关资料，对造成上述状况的原因作了探讨。     

江苏省环境系统特点及环境污染状况

江苏省自然特点为单一而脆弱,表面为平原为主,水域面积较大,山地少,森林覆盖率低,生物种类少,江苏省社会环境特点为人均资源少,经济基础好,交通发达,城市密集和人才优势明显;江苏省的废气,废水,固体,噪声污染日益严重。由于上述特点和原因,江苏省农业机械化,现代化程度较高,水产养殖业发达,但应进一步提高农业集约化程度和大力推广生态农业整治环境污染,利用天在河道进一步发展养殖业;江苏省工业轻,重并举以轻为