泄爆导管对球形容器内气体爆炸泄放过程影响的试验

设计了球形容器内气体爆炸通过导管泄爆的试验系统,选用体积分数为10%(特殊说明除外)的甲烷和空气预混气体开展试验,研究了泄爆导管长度、容器容积、点火位置、气体体积分数、破膜压力等因素的影响。结果表明:泄爆导管越长,容器内的正压力峰值和负压力峰值越大;密闭爆炸时,球形容器的容积对爆炸压力峰值几乎无影响;不同容积球形容器内气体爆炸通过相同导管泄爆时(导管长度均为6 m,直径均为0.06 m),容积大的容器内的压力锋值为小容器压力值的3.3倍,且大容器内的压力上升速率也明显高于密闭爆炸的情况;有泄爆导管存在时,尾部点火容器内的压力峰值高于中心点火;泄爆导管的存在使得容器内的压力峰值高于直接泄爆时的压力峰值;无论有、无泄爆导管,容器内的压力峰值均随破膜压力增加而增加,但差值越来越小,说明导管的存在对容器爆炸泄爆过程的影响趋向缓和,但导管的存在总是阻碍了泄爆过程,增加了爆炸的严重程度,因此,在泄爆设计时要充分考虑导管的影响,适当提高容器自身的耐压强度。     

催化裂解装置火灾爆炸危险性评价

道氏方法是对石化装置风险性进行量化评价的一种行之有效的方法,尤其是对装置的系统和单元的固有危险性及安全设施降低危险性的安全补偿作用进行认识和评价,采用道化学公司的火灾、爆炸危险指数法,对安庆石化炼油厂65×104t/a催化裂解装置的潜在火灾爆炸和反应危险性进行评价和分析,得到“严重”以上程度的单元有:加热炉、丙烷塔、丙烯塔、液化气储罐和汽油柴油储罐、反应器、瓦斯发生器、乙烷塔和稳定器,同时给出单元的危险等级和薄弱环节,为工厂的风险管理和安全管理决策提供了科学依据,并为降低装置风险提出了建议。     

评价爆炸超压作用的一个新指标及其在一次型FAE中的应用

利用单自由度体系在爆炸载荷作用下的动力响应的数值解,提出了一个近似关系式,进而得到一个新评价指标△P0.742m i0.258 .同时给出了一次型FAE的TNT比当量的计算方法,分别以超压峰值△Pm和△P0.742m i0.258 为评价指标计算了某一次型FAE的TNT比当量,并进行了比较.结果表明,单纯以超压峰值为评价指标的TNT比当量结果低估了一次型FAE的超压作用.鉴于爆炸超压场测试仪器与技术已能够容易地准确测量超压峰值与比冲量,建议以△P0.742m i0.258 为一次型FAE的TNT比当量的评价指标.     

气态硫闪爆事故原因分析及对策

对处理硫磺回收装置高温掺合阀故障时发生的硫闪爆事故进行了分析,提出了相应的对策.     

甲烷煤尘耦合爆炸传播特性及伤害研究

为探究煤尘质量浓度对甲烷煤尘耦合爆炸传播特性及伤害距离的影响,自制长15 m的爆炸管道系统,用体积分数为7％甲烷分别与质量浓度为0、50、100和200 g/m3的煤尘进行耦合爆炸试验,并根据质量、动量和能量守恒理论推导出最大压力计算公式.结果 表明:不同质量浓度煤尘与甲烷耦合爆炸时,最大压力均随与爆源距离的增加呈现出...     

一起硫酸槽罐爆炸事故的直接原因分析

针对一起硫酸槽罐爆炸事故，在事故现场勘查资料以及其他有关资料分析的基础上，采用故障树定性分析了硫酸中间槽罐爆炸事故的直接原因，并对稀硫酸的成因进行了定性分析，得出了事故直接原因分析结论，总结了应该吸取的经验教训。     

Methodology for case studies of accidental gas explosions

This paper discusses a procedure for case studies of accidental gas explosions. The procedure for each case study can be subdivided into four steps, i.e., collection of proofs, analyses, confirmation, and inference about the processes of the accident, and the issues in each step are pointed out. Making a guess on the sequence of the accident to be investigated should be avoided during collection of proofs. Misunderstanding of the phenomena in analyses and confirmation is likely caused by inappropriate knowledge on the phenomena and/or use of unsuitable models. The sequence of the accidental gas explosion should be inferred on the basis of confirmed processes. If there are other possibilities, those should be described in the report. The reasonableness of the results of a case study depends on the rationality of the procedure and the quality or plausibility of knowledge to infer the probable sequence.     

浮顶油罐油气惰化防火防爆实验研究

对浮顶油罐的油气空间进行惰化,是一种新的油罐防火防爆方法。向浮顶油罐一、二次密封间的油气空间中加入氮气,可缩小浮顶油罐的一、二次密封之间环形空间油气的爆炸极限的范围。根据这一原理,通过模型实验对大型双重密封型浮顶油罐的油气空间进行了氮气惰化保护实验研究。实验结果表明油气空间内氮气的体积分数会随着氮气通入时间的增长而逐渐升高,油气的体积分数则逐渐降低。氮气通入开始一段时间,环形空间内氮气的体积分数会迅速上升,油气体积分数迅速下降。但随着氮气通入时间的增长,氮气体积分数的上升和油气体积分数的下降速度都会趋于平缓。另外当入口处氮气流量从27Nm3/h变化到54Nm3/h时,为使油气体积分数下降至油气爆炸下限1%所需氮气持续通入的时间也从300分钟左右下降至200分钟左右。     

URBAN INFLUENCE ON PHOSPHORUS AND SEDIMENT LOADING OF WEST POINT LAKE,GEORGIA1

ABSTRACT: West Point Lake is a 10,360 ha mainstream impoundment of the Chattahoochee River located 95 kilometers downstream of Atlanta, Georgia. Origins and magnitude of external total phosphorus (TP) and total suspended solids (TSS) loads from the West Point Lake basin were estimated over a one-year period. Partitioning the drainage basin allowed the sources of these loads to be determined. The upper subbasin area, from Franklin, Georgia, to the headwaters of the Chattahoochee River, contributed 96 percent of the discharge and 97 percent of the TP and TSS loads into West Point Lake. The lower subbasin area, from Franklin to West Point Lake dam, only contributed 3 percent of the TP and TSS loads. Ninety-one percent and 87 percent of the TP and TSS loads, respectively, from the upper subbasin originated from the Atlanta area. Point sources discharged 70 percent and 3 percent of the upper subbasin TP and TSS loads, respectively. A large portion (66 percent) of the TP from the upper subbasin was in the bioavailable form.     

SPRINGFLOW EFFECTS ON CHEMICAL LOADS IN THE SNAKE RWER,SOUTH-CENTRAL IDAHO1

ABSTRACT: The 150-kilometer middle reach of the Snake River (middle Snake) in south-central Idaho receives large quantities of water from springs discharging along the north side of the river from the regional Snake River Plain aquifer. Water-quality samples collected from nine north-side springs in April 1994 indicated that springs in the upstream part of the reach had larger concentrations of dissolved solids, dissolved nitrate, total nitrogen, tritium, and heavy isotopes of hydrogen and oxygen than to springs in the downstream part of the reach. Because the spring chemistry varies in the reach, discharge from the springs resulted in a degradation in water quality in some parts of the middle Snake and improvements in water quality in other parts. Depending on the annual discharge in the Snake River, the contribution from the north-side springs represented 33 to 66 percent of the discharge, 32 to 57 percent of the dissolved solids, 26 to 50 percent of the total nitrogen, and 7 to 14 percent of the total phosphorus transported annually from the middle Snake. Synoptic sampling showed that the north-side springs contributed 84 percent of the discharge and 35, 40, and 10 percent of the dissolved solids, total nitrogen, and total phosphorus load, respectively, to the Snake River during the peak of the irrigation season in 1994.